Thermochemistry of copper complex of 6-benzylaminopurine |
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| Authors: | Y Xu-Wu Z Hang-Guo S Wu-Juan W Xiao-Yan G Sheng-Li |
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| Institution: | (1) Shaanxi Key Laboratory of Phsico-Inorganic Chemistry, Department of Chemistry, Northwest University, Xi’an, 710069 Shaanxi, China;(2) College of Chemistry and Environment Science, Shaanxi University of Technology, Hanzhong, 723001 Shaanxi, China |
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| Abstract: | The copper(II) complex of 6-benzylaminopurine (6-BAP) has been prepared with dihydrated cupric chloride and 6-benzylaminopurine.
Infrared spectrum and thermal stabilities of the solid complex have been discussed. The constant-volume combustion energy,
Δc
U, has been determined as −12566.92±6.44 kJ mol−1 by a precise rotating-bomb calorimeter at 298.15 K. From the results and other auxiliary quantities, the standard molar enthalpy
of combustion, Δc
H
m
θ, and the standard molar of formation of the complex, Δf
H
m
θ, were calculated as −12558.24±6.44 and −842.50±6.47 kJ mol−1, respectively. |
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| Keywords: | combustion energy copper(II) complex of 6-benzylaminopurine rotating-bomb calorimeter standard enthalpy of formation |
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