超临界二氧化碳中甲基-β-环糊精与聚丙二醇的包合

探索了超临界二氧化碳介质中甲基-β-环糊精和两种线型聚丙二醇间的穿合(threadinginclusion);并和相同温度下空气中的固态包合反应进行了比较。在无溶剂状态下,原处于无定形态的甲基-β-环糊精可与聚丙二醇链作用形成具有圆筒状结构的结晶态包合物,引入适量二氧化碳可明显增大包合反应的程度;将聚丙二醇链两端的羟基换为丙烯酸酯基可使反应进一步加强。     

Flow Injection Chemiluminescence Determination of Phenol in Neutral Medium

A new flow injection chemiluminescence method for the determination of phenol was proposed, based upon the chemiluminescence reaction of phenol, N-bromosuccinimide, and hydrogen peroxide in neutral aqueous medium in the presence of cetyltrimethylammonium bromide surfactant micelles. The chemiluminescence signal was proportional to the concentration of phenol in the range of 1.0 × 10^?7?8.0 × 10^?6 g/mL with a detection limit of 3 × 10^?8 g/mL. The relative standard deviation for 1.0 × 10^?6 g/mL phenol solution was 2.0% (n = 11). The proposed method was successfully applied to the determination of phenol in phenol ear drops. A possible CL reaction mechanism was also discussed briefly.     

SmS phase transition in thin films prepared by reactive evaporation

Preparation and analysis of thin films containing samarium sulfide (SmS) is presented along with a review of relevant SmS properties. Films were deposited onto unheated substrates by the reactive evaporation of samarium in a backpressure of hydrogen sulfide. This technique yields films that contain significant quantities of impurities; however high-quality SmS crystals are also formed. A phase transition in the SmS crystals was observed both by spectrophotometry and x-ray diffraction. The film optical properties can be modeled with an effective medium calculation. The predicted spectra successfully reproduce the observed qualitative features over a wide range of wavelengths.     

Effective electrical and thermal conductivity of multifilament twisted superconductors

The effective electrical and thermal conductivity of composite wire with twisted superconducting filaments embedded into normal metal matrix is calculated using the extension of Bruggeman method. The resistive conductivity of superconducting filaments is described in terms of symmetric tensor, whereas the conductivity of a matrix is assumed to be isotropic and homogeneous. The dependence of the resistive electrical conductivity of superconducting filaments on temperature, magnetic field, and current density is implied to be parametric. The resulting effective conductivity tensor proved to be non-diagonal and symmetric. The non-diagonal transverse–longitudinal components of effective electrical conductivity tensor are responsible for the redistribution of current between filaments. In the limits of high and low electrical conductivity of filaments the transverse effective conductivity tends to that of obtained previously by Carr. The effective thermal conductivity of composite wires is non-diagonal and radius-dependent even for the isotropic and homogeneous thermal conductivities of matrix and filaments.     

Accuracy analysis of simplified and rigorous numerical methods applied to binary nanopatterning gratings in non-paraxial domain

A set of simplified and rigorous electromagnetic vector theories is used for analyzing the transmittance characteristics of diffraction phase gratings. The scalar diffraction theory and the effective medium theory are validated with the exact results obtained via the rigorous coupled-wave theory and the finite-difference time-domain method. The effects of surface profile parameters and also the angle of incidence is demonstrated to be a limiting factor in the accuracy of these theories. Therefore, the error of both simplified theories is also analyzed in non-paraxial domain with the intention of establishing a specific range of validity for both simplified theories.     

半导体光折变介质中光束传输的自囚禁及周期调制

推导了光束在半导体光折变介质的光子晶格中演化的二能级形式, 给出了光束在其中传播时二能级方程的经典正则形式. 解析计算出了经典正则方程的不动点并对其稳定性作了分析, 计算出了拓扑结构变化的临界值. 根据二能级方程的经典正则形式做出了空间相图, 进一步分析了半导体光折变介质中光束传输的自囚禁现象, 发现有两种形式的自囚禁: 1)能级中的布居数差和相对相位都在平衡点附近振动; 2)能级中的布居数差在平衡点附近振动, 而相对相位单调变化. 分别从高频、低频、中频三个方面研究了外加周期调制对自囚禁的影响, 发现在高频调制中发生自囚禁现象的相变参数能够被周期场非常有效的调制, 使得光束在半导体光折变介质中传输时, 在非线性效应影响较小时也能够发生自囚禁. 关键词： 半导体光折变介质 自囚禁 二能级形式 周期调制     

间接延迟耦合可激发介质中螺旋波的演化

采用Bär 模型研究了通过被动介质间接延迟耦合的两层可激发介质中螺旋波的相互作用. 数值模拟结果表明: 延迟耦合可以促进两个螺旋波的同步, 也可导致从螺旋波到集体振荡、各种靶波、时空混沌态或静息态的转变; 在这个耦合系统中还观察到周期 2和周期3螺旋波以及螺旋波漫游和漂移现象; 对产生这些现象的物理机制做了讨论. 关键词： 螺旋波 被动介质 时间延迟耦合 同步     

层状介质上时空展源瞬变电磁响应的计算方法研究

在瞬变电磁法的实际应用中,由于发射回线和发射波形的不规则性而导致其发射源成为时空展源. 展源效应的忽略会造成正反演和数据解释的差错,因此开展展源效应的研究对于瞬变电磁法的实际应用具有重要的意义. 对于空间展源,本文以磁偶极子的响应为基响应,应用有源空间的互易定理和第二类曲线积分,提出了一种可基于发射回线数值坐标求取任意形状发射回线响应的计算方法. 同时对于时间展源,以阶跃波形的响应为基响应,对阶跃响应的特性进行了分析,提出了一种对发射信号进行非均匀采样的高效时间域计算方法,解决了对数采样的基响应与高密度采样的发射波形之间进行常规卷积时所面临的时间与精度之间的矛盾. 通过对层状大地上展源响应的模拟仿真和对比验证显示了本文所提出方法的正确性. 最后本文考察了几种常见时空展源在常规近似前后响应的差别,并给出了相关结论. 关键词： 分层介质 展射电源 互易定理 非均匀采样