室温离子液体电解液中尖晶石LiMn_2O_4的电化学性质

应用循环伏安、恒电流充放电和电化学阻抗技术研究了尖晶石L iMn2O4于室温离子液体电解液中的电化学性质.实验表明,以室温离子液体作电解液,L iMn2O4的首次放电容量可达108.2 mAh/g、循环效率高于90%,温度和电流密度显著影响电极的电化学性能.交流阻抗测定了L i+在电极/电解液相界面迁移的活化能,为55 kJ/mol.根据界面反应的高活化能解释了L iMn2O4在该离子液体电解液中低温性能和倍率充放电性能不佳的原因.     

A novel ellipsoidal acoustic infinite element

A novel ellipsoidal acoustic infinite element is proposed. It is based a new pressure representation, which can describe and solve the eUipsoidal acoustic field more exactly. The shape functions of this novel acoustic infinite element are similar .to the Burnett‘s method, while the weight functions are defined as the product of the complex conjugates of the shaped functions and an additional weighting factor. The code of this method is cheap to generate as for 1-D element because only 1-D integral needs to be numerical. Coupling with the standard finite element, this method provides a capability for very efficiently modeling acoustic fields surrounding structures of virtually any practical shape. This novel method was deduced in brief and the conclusion was kept in detail. To test the feasibility of this novel method efficiently, in the examples the infinite elements were considered, excluding the finite elements relative. This novel eUipsoidal acoustic infinite element can deduce the analytic solution of an oscillating sphere. The example of a prolate spheroid shows that the novel infinite element is superior to the boundary element and other acoustic infinite elements. Analytical and numerical results of these examples show that this novel method is feasible.     

QCM和SAW传感器的原理及其在现场检测中的应用

压电化学传感器是一类重要的质量敏感型检测器,由于具有体积小、灵敏度高、响应时间快等优越性而具有极好的应用前景.本文介绍了体声波化学传感器(QCM)和表面声波化学传感器(SAW)的原理,概述了最近几年的应用情况及提高灵敏度的方法,并对其发展趋势进行了展望.     

定向多壁碳纳米管电化学储氢研究

利用恒流充放电、循环伏安曲线(CV)和电化学阻抗技术(EIS)等方法对定向多壁碳纳米管(AMWCNTs)储氢的电化学行为及其储氢机制进行了探讨.研究表明,定向AMWCNTs-Cu电极有较高的电化学储氢性能,其储氢容量在1500mA/g的电流密度下可以达到1162mA·h/g.定向AMWCNTs的电化学储氢能力强与其空间结构有关,而铜粉的加入有利于提高碳纳米管的电催化反应表面积和电极电化学反应活性,有利于氢在碳纳米管中扩散,从而提高了碳纳米管电极材料的储氢量.     

电化学双石英晶体阻抗分析新方法

电化学石英晶体微天平已被广泛应用于电分析化学与电化学领域[1] .电化学现场的石英晶体阻抗分析法能动态实时地提供电化学扰动下石英晶体谐振的多维信息 ,已用于研究电沉积与溶出[2 ,3] 、高聚物性质[4～ 6 ] 、耗尽层内溶液粘密度效应与金电极腐蚀[7,8] 等 .然而 ,以往的石英晶体阻抗分析均只涉及到一个石英晶体 ,同时对两个晶体 (分别作为工作电极和对电极 )谐振的阻抗分析未见报道 .本文以蔗糖溶液粘密度效应和氨性介质中铜沉积 /溶出过程为例 ,研究电化学双石英晶体阻抗分析新方法 .1　实验部分电化学双石英晶体阻抗分析系统由 HP43 9…     

Numerical method for the shape reconstruction of a hard target

IntroductionAninverseproblemofconsiderableimportanceinvariousfieldsofengineeringtechnology ,suchasnondestructivetesting ,medicalimaging ,remotesensingandseismicimaging ,istodeterminetheshapeofascatteringobjectfromitsfar_fieldeffectsontheacousticscatteringwaves.However,thiskindofproblemisparticularlydifficulttosolvesinceitisbothnonlinearandill_posed[1].Fortunately ,therehavebeenseveralmethodsdevelopedforsolvingnumericallytheinverseproblemduringthelastdecade .Ofparticularimportancearenonlinearop…     

Variation method for acoustic wave imaging of two dimensional targets

IntroductionAcousticwaveimaginghasagreatpotentialtobeappliedtonondestructivetesting ,medicalimaging ,geologicalprospectingandmaterialscienceetc.,andvariousimagingmethods,eachpossessingitsownpeculiarities,havebeenproposed .In 1 992 ,Moghaddam[1]putforwarda…     

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木材声发射信号与其内外部损伤情况存在一定的定量关系. 依据损伤理论和含有裂 纹以及缺陷的木材不同阶段的声发射特征,分别探讨并建立了受交变载荷和单向静载荷情况下以声发 射特征参数表示的木材损伤演变模型. 分析结果与木材的实际情况相一致,表明以声发射特 征参量建立的木材损伤演变模型对木材的损伤预测具有提前性与敏感性,而且木材的不均匀 性是其提前破坏的主要原因之一.     

Fractional coverage of defects in self-assembled thiol monolayers on gold

Au electrodes are alkylated by self-assembled organic monolayers of octadecanethiol from alcohol solution. The electron tunnelling resistance of a monolayer-coated gold electrode has been investigated by ac impedance. The relation between the fractional coverage of different defects and the corresponding film thickness at these ‘collapsed’ sites has been deduced from electron tunnelling theory. By using the concepts of average film thickness at defect (d_a) and average fractional coverage of defect (θ_a), we have obtained the θ_ad_a plot. The influence of the apparent standard rate constant on the shape of the θ_ad_a plot has been discussed. In our experiments, Fe(CN)₆^3−/4− is used as a redox probe to study the θ_ad_a plot of an octadecanethiol monolayer. The θ_a versus d_a plot indicates that the defects with d_a<6 methylene groups and θ_a<0.1 can increase the apparent standard rate constant from 1.9×10⁻¹⁰ cm s⁻¹, which is the theoretical value calculated from electron tunnelling theory, to 2.9×10⁻⁷ cm s⁻¹. The average thickness of the whole monolayer (ATWM), which is obtained from the θ_a versus d_a plot and which can indicate the blocking property of the monolayer, is 11 methylene groups.     

LY12铝合金表面稀土转化膜腐蚀行为的研究

通过金相观察和Ｘ射线射能谱分析研究了ＬＹ１２铝合金表面两种稀土转化膜的腐蚀行为,在ＮａＣｌ溶液中稀土转化膜的腐蚀以点腐蚀开始,点蚀处基体含Ｃｕ量高。根据Ｍａｎｓｆｅｌｄ点腐蚀模型等效电路提出了利用电化学阻抗谱研究稀土转化膜在ＮａＣｌ溶液中腐蚀程度的新方法,转化膜在ＮａＣｌ淀粉 中浸泡时间较短、腐蚀不太严重的情况下,等效电路中的Ｗａｒｂｕｒｇ阻抗Ｗ可以忽略,简化等效电路得出了计算转化膜表面点腐蚀百分