基于合成方法学研究的有机化学实验教学改革与实践——以苯甲酸乙酯制备为例

以苯甲酸乙酯的制备实验为例,将合成方法学研究引入有机化学实验教学。采取抽签方式确定每个学生的实验内容,通过考查加热方式(电热套或微波辐射加热)、溶剂(甲苯或环己烷)以及反应时间对实验结果的影响,使学生了解科学研究的方法,并通过文献查阅及实验结果分析讨论等教学实践环节提高学生的创新思维和科研能力。     

在基础无机化学实验教学中培养学生自主学习能力

自主学习能力的培养是开发学生创新思维、增强独立研究能力的基础,本文通过剖析基础无机化学实验教学中存在的问题,结合大一新生在学习过程中暴露出来的问题,探讨了如何在基础无机化学实验教学的不同阶段,在实验教学的各个环节中,采取不同的教学方式,运用不同的教学手段,帮助学生树立自主学习意识,提高自主学习能力,为新世纪高素质、创新性人才的培养奠定良好的基础。     

医用有机化学教学经验谈

就医用有机化学教学中的绪论课讲授、教学过程设计、教学内容组织、前沿知识补充谈了点滴经验,希望对培养和提高学生的学习兴趣和科学思维能力有所帮助。     

贯通中学和大学数学教与学 集成造就学生数学素养和创新实践能力

针对如何破解我国从应试教育向素质教育转变步履维艰的难题,本文详细介绍了如何贯通中学和大学数学教与学,集成培养学生数学素养和创新实践能力的具体做法和成效.     

Stochastic optimization of an urban rail timetable under time‐dependent and uncertain demand

Urban rail planning is extremely complex, mainly because it is a decision problem under different uncertainties. In practice, travel demand is generally uncertain, and therefore, the timetabling decisions must be based on accurate estimation. This research addresses the optimization of train timetable at public transit terminals of an urban rail in a stochastic setting. To cope with stochastic fluctuation of arrival rates, a two‐stage stochastic programming model is developed. The objective is to construct a daily train schedule that minimizes the expected waiting time of passengers. Due to the high computational cost of evaluating the expected value objective, the sample average approximation method is applied. The method provided statistical estimations of the optimality gap as well as lower and upper bounds and the associated confidence intervals. Numerical experiments are performed to evaluate the performance of the proposed model and the solution method.     

高速列车穿越有竖井隧道流场的特性研究

给出了高速列车穿越隧道压力波的三维粘性流场数值模拟过程,控制方程为三维粘性、可压缩、等熵和非定常流的Navier-Stokes方程,空间离散采用了中心有限体积法格式,时间采用预处理二阶精度多步后差分格式进行离散,对隧道壁面采用壁面函数处理。在模拟中考虑了竖井的位置、竖井的断面积、竖井的数目等因素对隧道内压力及压力梯度的影响。计算结果表明,竖井的存在改变了压缩波的波前形状,从而使得隧道内的压力变化的最大值降低,因而能够降低隧道内的压力梯度最大值,但它并不能延长压力上升的时间。     

Reflection and transmission of a compression wave at a tunnel portal

Analyses are made of the interaction of the nonlinearly steepened, compression wavefront generated by a high-speed train in a tunnel with the tunnel portal ahead of the train. The ‘micro-pressure’ pulse emitted from the portal can rattle structures in nearby buildings, and the expansion wave reflected back towards the train can cause discomfort to passengers. It is concluded that the usual simplified approximation of one-dimensional propagation within the tunnel provides an adequate representation of interactions of the wave with the portal, and also with ‘windows’ in the tunnel wall near the portal. It is shown how a discrete distribution of windows can be used to produce a reflected expansion wave that varies linearly across the wavefront, and how the thickness of that wavefront can be made many times larger than the thickness of the incident compression wave profile. A detailed analysis of the wave radiated from the portal reveals that cumulative nonlinear effects of propagation over long distances make little or no contribution to the free-space radiation of the micro-pressure wave.     

One‐step electrodeposition of amorphous carbon films containing WO3 with high conductivity and good wettability

Tungsten trioxide‐incorporated hydrogenated amorphous carbon (WO₃/a‐C:H) films have been fabricated on a single‐crystal silicon wafer by liquid phase electrodeposition using methanol as carbon source and tungsten carbonyl as incorporated reagent. The morphology, composition and structure of the films have been investigated by SEM, XPS, Raman scattering spectroscopy, Fourier transform infrared spectroscopy (FTIR) and Transmission electron microscope (TEM), respectively. The effects of WO₃ incorporation on the electrical and wetting properties were studied in detail. The characterization results showed that tungsten trioxide nanocrystalline particles with diameters in the range of 10–20 nm were homogenously embedded in the amorphous carbon films. Also, the electrical conductivity and wetting ability of the films were strongly improved due to the contribution of the tungsten trioxide. Copyright © 2010 John Wiley & Sons, Ltd.     

不同活性焦载体对V2O5/AC催化剂脱硫活性的影响

活性焦载体的选择是制备高活性烟气脱硫催化剂的关键.以四种煤制活性焦(AC)为载体,制得了系列V2O5/AC催化剂.通过脱硫活性评价、催化氧化能力测试和孔结构分析表明,AC表面的高活性氧化位较少,担载V2O5使AC表面产生了新的高活性氧化位,其脱硫活性显著提高;V2O5在具有高比表面积和较大孔容的载体上分散性较好,能够形...     

CeO2-WO3复合氧化物催化剂的NH3-SCR反应机理

采用共沉淀法制备了新型CeO2-WO3复合氧化物催化剂,并用于氨选择性催化还原(NH3-SCR)NOx反应中.活性测试表明,在200～450℃ NOx转化率接近100%.采用程序升温脱附和原位漫反射红外光谱研究了该催化剂上的NH3-SCR反应机理.结果表明,该催化剂的主要活性位是CeO2,而WO3的加入大大提高了其表面...