PHONONS IN POLYACENIC CHAINS

We have theoretically resolved phonon excitations in quasi-two-dimensional organic crystals of polyacenic semiconductor material which may be obtained by the pyrolytic treatment of phenol-formaldehyde resin. A model for studying the dynamical properties using three polyacene chains is proposed with the aim to present the vibrational properties of this structure. It employs the formalism of solid states in two dimensions which admit phonons. A simulation process of the two-dimensional lattice structure shows that elastic waves may explain the existence of vibrational modes in the frequency range 100-400 cm-1. The presence of acoustic and optical like phonons is discussed in terms of the elastic force constants. A hyperfine resonance structure is obtained. It allows the analysis of the dynamical evolution in thin films of polyacene. It is found that the behavior of the phonon density of states exhibits resonance between modes in the structure.     

Über die Phasenbreite von V2O5 im Temperaturbereich von 450°C bis 620°C

About the Homogeneity Range of V₂O₅ in the Temperature Range of 450°C to 620°C The influence of the deposition temperature T₁ on the homogeneity range of V₂O₅-crystalls was investigated by using a solid electrolyte cell. The deviation x in V₂O_5–x from the stoichiometric composition was obtained with: x = 0.0066 at T₁ = 450°C up to x = 0.0326 at T₁ = 620°C.     

A study on the kinetics of thermal decomposition of CaCO3

By means of TG, the thermal decomposition of the powdered CaCO₃ was tested with its various dispersities, range of size, and the different content of CO₂ in flowing nitrogen. Formulae for calculating the rate and time of decomposition were obtained.     

一种基于warping变换的浅海脉冲声源被动测距方法

针对浅海波导中脉冲声源被动测距问题, 提出了一种利用接收信号的能量密度函数进行warping变换的声源被动测距方法. 对于浅海波导, 接收信号的能量密度函数中不同号简正波相干部分, 经warping变换后输出结果的频谱中包含与声源和接收器位置无关的不变性频率特征. 这些特征频率在数值上等于理想波导中相干的两号简正波的截止频率差, 与海底参数无关, 因此仅需已知海水中的平均声速和海水深度便可计算出特征频率值. 当声源距离未知时, 利用特征频率的提取值与真实特征频率之间的关系可以实现快速测距, 极大地提高了计算速度. 为了验证方法的有效性, 对2011年11月黄海海域水声实验的接收脉冲数据进行了处理, 测距结果与实测距离符合良好, 平均测距误差在8%以内.     

复杂脉冲单发频域干涉测量

以傅里叶变换极限脉冲作参考脉冲,利用单次测量分析法对复杂的皮秒脉冲进行测量,用窗口傅里叶变换代替傅里叶变换对干涉条纹进行时间-频率分析,直接提取出复杂脉冲的啁啾特性或光谱成分,将光谱图中的功率密度S(ω,t)沿ω轴求和重建脉冲的时域包络.分别用该方法和传统频域干涉测量法测量一个线性啁啾脉冲和一个复杂脉冲.结果表明,该方法可实现复杂整形脉冲的实时测量,且时间分辨率为70 fs.     

非Kolmogorov大气湍流对径向部分相干阵列光束瑞利区间和湍流距离的影响

基于广义的Huygens-Fresnel原理和非Kolmogorov谱模型,推导了无线光通信系统中径向分布部分相干高斯-谢尔模型阵列光束在非Kolmogorov大气湍流中传输时瑞利区间z_R和湍流距离z_T的解析表达式,对瑞利区间和湍流距离随湍流参量和光束参量的变化情况进行了数值分析.结果表明:不论是相干还是非相干合成,径向分布部分相干高斯-谢尔模型阵列光束的z_R和z_T均随湍流广义指数α的增大非单调变化,当α=3.11时,z_R和z_T取最小值,此时阵列光束扩展最大;相干合成比非相干合成的光束扩展要小,但其受湍流的影响更大;对于相干合成而言,径向分布半径r0越大,合成光束的z_R和z_T就越大,而非相干合成的z_R和z_T不受r0的影响;不论是相干还是非相干合成,阵列子光束数目对合成光束的z_R和z_T没有影响;当光束相干参量β足够小或波长λ足够大时,大气湍流对阵列光束z_R的影响可以忽略.     

空间相机自适应曝光

为实现空间相机的自适应曝光,提出了一种根据场景高亮度信息设置曝光参量的测光、解算、成像工作模式.在空间相机前加装大尺度面阵测光相机,在空间相机推扫某一区域前,测光相机首先采用预设的曝光参量获取该区域图像,实测当前区域的高亮度信息;再将该高亮度设为空间相机的饱和亮度,解算空间相机的曝光参量;随着卫星的转动,空间相机采用该曝光参量完成位置区域拍摄成像,实现空间相机的自适应曝光.地面验证实验结果表明:与采用固定的较小的曝光参量相比,本文方法可以减小欠曝光图像数量;根据某次实验结果统计,图像的灰度范围由37提高到253,图像熵显著提高.该方法能够根据当前场景内容充分利用成像系统的动态范围并提高图像的灰度层次和图像质量.     

染料敏化太阳能电池Eu~(3+),Sm~(3+)掺杂TiO_2下转换光阳极的制备及性能

用溶胶-凝胶法制备了Eu,Sm共掺TiO_2粉体,将其与P25复合,制备了下转换光阳极,用于染料敏化太阳能电池,利用其下转换特性提高电池的光电性能.用荧光光谱对粉体的发光性能进行表征,荧光光谱显示:Eu,Sm共掺TiO_2粉体受463nm光激发可以发射550~700nm的可见光,具有下转换功能.当Eu~(3+)的摩尔掺杂含量为1%,Sm~(3+)的摩尔含量为0.5%时,制备的Eu~(3+),Sm~(3+)共掺下转换光阳极,短路电流达到14.08mA/cm2,与使用Eu~(3+)掺杂TiO_2的下转换光阳极电池相比,提高了32.08%,转换效率也达到5.29%.     

Guided filter and adaptive learning rate based non-uniformity correction algorithm for infrared focal plane array

Imaging non-uniformity of infrared focal plane array (IRFPA) behaves as fixed-pattern noise superimposed on the image, which affects the imaging quality of infrared system seriously. In scene-based non-uniformity correction methods, the drawbacks of ghosting artifacts and image blurring affect the sensitivity of the IRFPA imaging system seriously and decrease the image quality visibly. This paper proposes an improved neural network non-uniformity correction method with adaptive learning rate. On the one hand, using guided filter, the proposed algorithm decreases the effect of ghosting artifacts. On the other hand, due to the inappropriate learning rate is the main reason of image blurring, the proposed algorithm utilizes an adaptive learning rate with a temporal domain factor to eliminate the effect of image blurring. In short, the proposed algorithm combines the merits of the guided filter and the adaptive learning rate. Several real and simulated infrared image sequences are utilized to verify the performance of the proposed algorithm. The experiment results indicate that the proposed algorithm can not only reduce the non-uniformity with less ghosting artifacts but also overcome the problems of image blurring in static areas.