全文获取类型
收费全文 | 18106篇 |
免费 | 2704篇 |
国内免费 | 3147篇 |
专业分类
化学 | 14690篇 |
晶体学 | 172篇 |
力学 | 408篇 |
综合类 | 72篇 |
数学 | 4416篇 |
物理学 | 4199篇 |
出版年
2024年 | 47篇 |
2023年 | 254篇 |
2022年 | 478篇 |
2021年 | 604篇 |
2020年 | 835篇 |
2019年 | 667篇 |
2018年 | 621篇 |
2017年 | 689篇 |
2016年 | 854篇 |
2015年 | 803篇 |
2014年 | 915篇 |
2013年 | 1738篇 |
2012年 | 1156篇 |
2011年 | 1243篇 |
2010年 | 982篇 |
2009年 | 1214篇 |
2008年 | 1302篇 |
2007年 | 1297篇 |
2006年 | 1112篇 |
2005年 | 986篇 |
2004年 | 890篇 |
2003年 | 726篇 |
2002年 | 517篇 |
2001年 | 470篇 |
2000年 | 390篇 |
1999年 | 368篇 |
1998年 | 334篇 |
1997年 | 250篇 |
1996年 | 247篇 |
1995年 | 251篇 |
1994年 | 213篇 |
1993年 | 182篇 |
1992年 | 138篇 |
1991年 | 93篇 |
1990年 | 99篇 |
1989年 | 78篇 |
1988年 | 75篇 |
1987年 | 84篇 |
1986年 | 73篇 |
1985年 | 93篇 |
1984年 | 62篇 |
1983年 | 56篇 |
1982年 | 99篇 |
1981年 | 73篇 |
1980年 | 68篇 |
1979年 | 38篇 |
1978年 | 58篇 |
1977年 | 58篇 |
1976年 | 59篇 |
1975年 | 7篇 |
排序方式: 共有10000条查询结果,搜索用时 78 毫秒
71.
Rodrigo París José Luis de la Fuente 《Journal of polymer science. Part A, Polymer chemistry》2007,45(16):3538-3549
Different diblock copolymers constituted by one segment of a monomer supporting a reactive functional group, like allyl methacrylate (AMA), were synthesized by atom transfer radical polymerization (ATRP). Bromo‐terminated polymers, like polystyrene (PS), poly(methyl methacrylate) (PMMA), and poly(butyl acrylate) (PBA) were employed as macroinitiators to form the other blocks. Copolymerizations were carried out using copper chloride with N,N,N′,N″,N″‐pentamethyldiethylenetriamine (PMDETA) as the catalyst system in benzonitrile solution at 70 °C. At the early stage, the ATRP copolymerizations yielded well‐defined linear block copolymers. However, with the polymerization progress a change in the macromolecular architecture takes place due to the secondary reactions caused by the allylic groups, passing to a branched and/or star‐shaped structure until finally yielding gel at monomer conversion around 40% or higher. The block copolymers were characterized by means of size exclusion chromatography (SEC), 1H NMR spectroscopy, and differential scanning calorimetry (DSC). In addition, one of these copolymers, specifically P(BA‐b‐AMA), was satisfactorily modified through osmylation reaction to obtain the subsequent amphiphilic diblock copolymer of P(BA‐b‐DHPMA), where DHPMA is 2,3‐dihydroxypropyl methacrylate; demonstrating the feasibility of side‐chain modification of the functional obtained copolymers. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3538–3549, 2007 相似文献
72.
M. Frigon 《Journal of Fixed Point Theory and Applications》2007,1(2):189-194
We present results on the global existence of analytic solutions to the Cauchy problem in starshaped or convex complex domains.
No growth conditions are imposed. Our results rely on a notion of solution-tube that we introduce.
à la mémoire de Jean Leray 相似文献
73.
关于多线性振荡奇异积分在加权Hardy-型空间上的一致估计 总被引:1,自引:0,他引:1
本文对一类具有光滑位相函数的多线性振荡奇异积分算子建立了一致的加权(H^1(R^n),L^1(R^n))估计及一致的加权(HKp(R^n),Kp(R^n)估计。 相似文献
74.
Valery Agoshkov Paola Gervasio Alfio Quarteroni 《Mediterranean Journal of Mathematics》2006,3(2):147-176
New domain decomposition methods (DDM) based on optimal control approach are introduced for the coupling of first and second
order equations on overlapping subdomains. Several cost functionals and control functions are proposed. Uniqueness and existence
results are proved for the coupled problem, and the convergence of iterative processes is analyzed.
The work was supported by the Russian Foundation for Basic Research (04-01-00615) and it was partly carried out while the
first author was visiting the IACS at EPFL. 相似文献
75.
We introduce symmetric Boundary Value Methods for the solution of second order initial and boundary value problems (in particular
Hamiltonian problems). We study the conditioning of the methods and link it to the boundary loci of the roots of the associated
characteristic polynomial. Some numerical tests are provided to assess their reliability.
Dedicated to the memory of Professor Aldo Cossu 相似文献
76.
77.
The behavior of a two-level entangled atom in an optical field with circular polarization is studied in this paper. The interaction of an optical field and one of the entangled atoms is analyzed in detail. A general solution of the SchrAo¨Gdinger equation about the motion of the entangled atom is obtained. The properties of the action are dependent on the initial state of the atom. By detecting the entangled atom out of the field, we can obtain the state of the other atom moving in the field. It is shown that the state of the atom out of the field will influence the energies of the split-levels of the atom in the field. 相似文献
78.
导出了类Kerr介质中双模SU(1,1)相干态场与Λ型三能级原子相互作用系统的态函数,研究了Kerr效应对Λ型三能级原子布居概率、双模SU(1,1)相干态场的互关联函数、Cauchy-Schwartz不等式及二阶相干度的影响.结果表明:Kerr效应使原子与光场的耦合减弱,原子布居的崩塌与复苏的周期缩短;在初始光场较弱和较强两种情况下,类Kerr介质对双模SU(1,1)相干态场两模间的相关性、相关程度以及光子的聚束与反聚束效应产生的作用有明显的区别. 相似文献
79.
There are many advantages in being able to perform positron annihilation lifetime spectroscopy (PALS) using a variable energy positron beam, the most obvious being the easy identification of different defect types at different depths. The difficulty in conducting variable energy (VE) PALS studies lies in the fact that a “start” signal is required to signal the entry of the positron into the target. Two methods have been used to overcome this problem, namely the bunching technique, which employs radio frequency (RF) cavities and choppers, and secondly the use of secondary electrons emitted from the target. The latter technique is in terms of experimental complexity much simpler, but has in the past suffered from poor time resolution (typically ∼500 ps). In this work, we present a series of computer simulations of a design based on the secondary electron emission from thin C-foils in transmission mode which shows that significant improvements in time resolution can be made with resolutions ∼200 ps being in principle possible. 相似文献
80.
Fengfu Fu Liangjun Xu Wei Ye Yiquan Chen Mingyu Jiang Xueqin Xu 《中国颗粒学报》2006,4(6):323-326
Different-sized aerosols were collected by an Andersen air sampler to observe the detailed morphology of the black carbon (BC) aerosols which were separated chemically from the other accompanying aerosols, using a Scanning Electron Microscope equipped with an Energy Dispersive X-ray Spectrometer (SEM-EDX). The results indicate that most BC aerosols are spherical particles of about 50 nm in diameter and with a homogeneous surface. Results also show that these particles aggregate with other aerosols or with themselves to form larger agglomerates in the micrometer range. The shape of these 50-nm BC spherical particles was found to be very similar to that of BC particles released from petroleum-powered vehicular internal combustion engines. These spherical BC particles were shown to be different from the previously reported fullerenes found using Matrix-Assisted Laser Desorption/Ionization Time-Of-Flight Mass Spectrometry (MALDI-TOF-MS). 相似文献