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71.
Kazuhiko Taguchi 《Tetrahedron letters》2005,46(27):4539-4542
2-Aminobenzyl alcohol reacted with 2 equiv amount of ketones under the influence of [IrCl(cod)]2 or IrCl3 and KOH without any solvent, giving the corresponding quinoline derivatives in good yields. 相似文献
72.
Fengping Xiao 《Tetrahedron》2008,64(12):2755-2761
A sequential catalytic process has been developed based on gold-catalyzed nucleophilic addition of terminal alkynes to imines, and gold-catalyzed intramolecular reaction of aromatic ring to alkynes. This one-pot reaction of aldehydes, amines, and alkynes gives quinoline derivatives in good yields. 相似文献
73.
Jia Rong Li Li Jun Zhang Xi Quan Yang Qing Li Dong Wang Chun Xia Wang Da Xin Shi Qi Zhang 《中国化学快报》2008,19(1):15-18
Two different skeletons of heterocyclic compounds, quinoline and quinazolinone analogs could be obtained by a novel one-pot synthesis from substituted 3-amino- 1H-benzo[f]chromene-2-carbonitrile derivatives and cyclohexanone in DMF in the catalyst of anhydrous Zinc chloride under reflux. A plausible mechanism was proposed. 2007 Jia Rong Li. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved. 相似文献
74.
XIA Dao-cheng LI Wan-cheng WANG Xu YU Shu-kun FAN Cui-xiang MA Chun-yu CHENG Chuan-hui FAN Zhao-qi DU Guo-tong CONG Fang-di DU Xi-guang 《高等学校化学研究》2008,24(4):407-410
A novel solvothermal synthesis method for the direct growth of B-form crystals of copper phthalocyanine(CuPc) is presented in this article. With quinoline as solvent, crystals were grown after cooling the reaction mixture of 1,3-diiminoisoindoline and copper oxide, heated for 9 h at 270 ℃, to room temperature in an autoclave. These high quality crystals were suitable for characterization measurements. The single-crystal diffraction data show a monoclinic system unit cell: a=1.4668(3) nm, b=0.48109(10) nm, c=1.9515(7) nm, a=90°, B=121.04(2)°, r=90°, where the corresponding cell volume is 1.17991 nm^3. Needle-like single crystals of CuPc up to 10.5 mm in length were obtained. The influences of different temperatures, reaction time and solvent volume on the crystal yields were also discussed. Optimum reaction conditions were 10 mL of quinoline, at 270 ℃ for 8 h. 相似文献
75.
Melinda Fekete Mercedesz Töröncsi Lajos Novak 《Central European Journal of Chemistry》2008,6(1):33-37
Palladium-catalyzed amination reactions of quinoline triflate and the effect of a Pd catalyst, its ligands, solvents, bases,
and temperature were studied. This method facilitated an easier pathway for the preparation of aminoquinoline derivatives
as potential precursors of new serotoninerg agents.
相似文献
76.
In recent years, ionic liquids have attracted much attention as useful synthetic solvents. Compared with classical molecular solvents, the ionic liquids are environmentally benign reaction media. A variety of quinoline derivatives have been synthesized under ionic liquid conditions using Amberlyst‐15 as catalyst. 相似文献
77.
《印度化学会志》2021,98(6):100079
A new novel organic corrosion inhibitor N-[4-(1,3-benzo[d]thiazol-2-ylcarbamoyl)phenyl]quinoline-6-carboxamide (NBCPQC) has been synthesized. The synthesized novel organic inhibitor NBCPQC used to be carried out on mild steel corrosion in 1N HCl for the first time. The studied inhibitor was once evaluated as corrosion inhibitor for mild steel in 1N of HCl solution using electrochemical research which advocated that a protective film is form by the process of inhibitor absorption on the surface of mild steel. Inhibitor shows a better inhibiton efficiency of maximum above 90% in 1N HCl medium. Inhibitors show a better efficiency by way of reducing and sluggish down the corrosion process however on growing the temperature it is weakened on controlling corrosion. In addition to this adsorption isothermal models had been interpreted to fit the adsorption behaviour of the inhibitor compound on mild steel surface. Thus the result reveals that the compound shows a Langmuir adsorption isotherm. 相似文献
78.
Mian Cui Jing-Hui Liu Xiao-Yu Lu Xi Lu Zhen-Qi Zhang Bin Xiao Yao Fu 《Tetrahedron letters》2017,58(20):1912-1916
An efficient and convenient method for C5-benzylation of quinoline frameworks is developed with the using of inexpensive FeCl3 catalyst. A range of N-bisbenzylic and N-monobenzylic sulfonamides smoothly react with aliphatic amides and aromatic amides, giving the corresponding products in moderate to excellent yields. 相似文献
79.
-5-Sulfono-7-(4-x phenyl azo)-8-hydroxy quinoline (SAHQ)-x ligands, x = NO2 or CH3 or Cl have polycrystalline structure in as synthesized condition. Thermally evaporated thin films of SAHQ-x have crystal structure depending on the substitution group; SAHQ-NO2 and SAHQ-Cl films have nano-crystalline structure with different degree of crystallinity and SAHQ-CH3 film has amorphous structure. The changes in optical functions and therefore optical constants with substitution group variation have been calculated by using spectrophotometer measurements of the transmittance and reflectance at nearly normal incidence of light in the wavelength range 200–2500 nm. Substitution group variation influences the refractive index, dispersion parameters, optical functions and bond length of SAHQ. It has no influence on mobility, relaxation time and plasma frequency of charge carriers. The obtained optical energy gaps for SAHQ-x ligands, x = NO2 or CH3 or Cl are 1.89, 2 and 2eV, respectively. 相似文献
80.
An efficient base-free one-pot synthesis of 1,2-dihydrobenzo[b][1,8]naphthyridines from BH acetates of 2-chloro-3-formylquinolines and activated alkenes followed by their acetylation, with different amines have been reported. These reactions are completed in very short time and provided the products in good to excellent yields. We further explored the scope of BH acetate with carbon nucleophile providing a new route to the synthesis of acridine derivative in excellent yield under mild condition. 相似文献