一种全可见光敏感的光致聚合物全息特性研究

制备了一种对整个可见光波段都敏感的光全息存储材料,并研究了该材料的透过率、衍射效率、灵敏度等全息特性.用He-Ne激光器633 nm和Ar+ 激光器514 nm,488 nm,476 nm四种波长的光曝光,材料的饱和衍射效率最大为66%,最小为48%;最高灵敏度为8.06×10－3 cm2/mJ.最高折射率调制度为4.22×10－4.用多波长存储时,不同波长的光可存储多幅全息图,且再现图像清晰.结果表明,该材料是较好的高密度数字全息存储材料.     

基于光子晶体光纤的全光波长变换研究

选用具有高非线性系数和非常灵活色散特性的光子晶体光纤(PCF)作为波长变换的媒质,对基于光子晶体光纤四波混频效应的波长变换进行了理论分析,设计实验系统,并进行了实验.实现了中心波长在1 550 nm附近、基于PCF四波混频效应的全光波长变换,最大转换效率－22 dB,转换带宽28 nm.     

波长转换器和光纤延迟线在WDM光分组交换中的结构设计和性能研究

介绍了两种新颖的光分组交换结构——MOD1和MOD2,用于解决分组冲突问题.其特点在于,MOD1共享了一组非简并的延迟线,而MOD2则是共享了一组简并的延迟线和波长转换器.研究表明,对于非突发业务,两种结构都只需要少量的延迟线即可获得理想的性能.此时,MOD1比MOD2更加能降低系统体积和成本.而对于突发业务,如果MOD1所共享的延迟线数量和MOD2所共享的延迟线和转换器的总数量相等,MOD2的分组丢弃率要远远低于MOD1.随着业务突发程度的增加,MOD2中的转换器数量也需要增加才能维持给定的分组丢弃率,但即使业务突发程度很高,MOD2在体积、成本和性能等三方面均可取得较理想的折衷.     

飞秒受激拉曼光谱线形:基于泵浦及探测脉冲光的共振条件研究

Resonance enhancement has been increasingly employed in the emergent femtosecond stimulated Raman spectroscopy (FSRS) to selectively monitor molecular structure and dynamics with improved spectral and temporal resolutions and signal-to-noise ratios. Such joint efforts by the technique-and application-oriented scientists and engineers have laid the foundation for exploiting the tunable FSRS methodology to investigate a great variety of photosensitive systems and elucidate the underlying functional mechanisms on molecular time scales. During spectral analysis, peak line shapes remain a major concern with an intricate dependence on resonance conditions. Here, we present a comprehensive study of line shapes by tuning the Raman pump wavelength from red to blue side of the ground-state absorption band of the fluorescent dye rhodamine 6G in solution. Distinct line shape patterns in Stokes and anti-Stokes FSRS as well as from the low to high-frequency modes highlight the competition between multiple third-order and higher-order nonlinear pathways, governed by different resonance conditions achieved by Raman pump and probe pulses. In particular, the resonance condition of probe wavelength is revealed to play an important role in generating circular line shape changes through oppositely phased dispersion via hot luminescence (HL) pathways. Meanwhile, on-resonance conditions of the Raman pump could promote excited-state vibrational modes which are broadened and red-shifted from the coincident ground-state vibrational modes, posing challenges for spectral analysis. Certain strategies in tuning the Raman pump and probe to characteristic regions across an electronic transition band are discussed to improve the FSRS usability and versatility as a powerful structural dynamics toolset to advance chemical, physical, materials, and biological sciences.     

波长扫描极值解调法实现光纤光栅应变和温度传感的测量

本文用可编程调谐光纤光栅环行腔激光器作扫描光源,采用波长扫描极值传感解调法对光纤光栅应变及温度进行了测量。应变测量范围为±2440με,灵敏度为0.016step/με;温度测量范围达608℃,灵敏度为0.13step/℃。     

基于半导体光放大器的交叉增益调制效应实现2.5Gb/s归零码的全光波长变换

采用半导体光放大器的交叉增益调制进杆了2.SGb/s的归零码光脉冲的波长变换。向下波长变换间距大于20nm,向上波长变换间距大于10nm.对变换信号测量了接收机入纤功率和误码率的关系。对实验结果进行了分析,实验表明采用半导体光放大器的交叉增益调制效应对归者吗进行波长变换时存在着一些问题。     

X射线荧光光谱结合CARS变量筛选选择方法用于土壤中铅砷含量的测定

X射线荧光光谱分析作为一种以化学计量学为基础的定量分析技术,所建立模型优劣对结果的预测准确性显得十分重要.竞争性自适应重加权算法(CARS)采用自适应重加权采样技术,利用交互验证选出互验证均方根误差(RMSECV)值最低原则,寻出最优变量组合.为了进一步提高PLS模型的解释和预测能力,将竞争性自适应重加权算法(CARS...     

Preparation of carbon-aerogel polypyrrole composite for desalination by hybrid capacitive desalination method

Capacitive Deionization (CDI) is an emerging technology with great potential applications. Most researchers view it as a viable water treatment alternative to reverse osmosis. This research reports the preparation and application of a carbon aerogel polypyrrole (CA-PPy) composite for the desalination of NaCl solution by the hybrid CDI method. The carbon aerogel (CA) was prepared from a Resorcinol / Formaldehyde precursor by the sol–gel method. The aerogel obtained from the sol–gel was then pyrolysed in a tube furnace to form CA. Polypyrrole (PPy) was prepared by the Oxidative chemical polymerisation of pyrrole, ferric chloride hexahydrate (oxidant), and sodium dodecyl sulfate (dopant). A composite of CA and PPy was then prepared and used to modify carbon electrodes. The CA-PPy composite was characterised to verify its composition, morphology, thermal properties, and functional groups. The electrochemical properties of the material were determined by Cyclic voltammetry (CV) and Electrochemical impedance spectroscopy (EIS) tests. The electrochemical tests were done using a GAMRY potentiostat electrochemical workstation, a 1.0 M KCl was used as the electrolyte, and the applied potential window was (-0.2 to + 0.6) V for the CV test. The EIS test was done with the same concentration of KCl electrolyte at an applied potential of 0.22 V and at a frequency range of (0.1 – 100, 000) Hz. The optimal specific capacitance of the CA is 115F/g, and that of the composite is 360.1F/g, they were both obtained at a scan rate of 5 mV/s. The CDI desalination study of the CA-PPy composite showed a salt adsorption capacity (SAC) of 10.10 mg/g (300 mg/L NaCl solution) – 15.7 mg/g (800 mg/L NaCl solution) at 1.2 V applied voltage. The salt recovery efficiency of the electrode material in the 300 mg/L solution is 27 %, in the 500 mg/L solution, it is 20.12 %, and in the 800 mg/L solution, it is 15.41 %. The electrode material also showed good electrochemical stability after nine cycles of ion adsorption/desorption study.