Process,mechanism and impacts of scale formation in alkaline flooding by a variable porosity and permeability model

In spite of the role of alkali in enhancing oil recovery (EOR), the formation of precipitation during alkaline-surfactant-polymer (ASP) flooding can severely do harm to the stratum of oil reservoirs, which has been observed in situ tests of oil fields such as scale deposits found in oil stratum and at the bottom of oil wells. On the other hand, remarkable variation of stratum parameters, e.g., pore radius, porosity, and permeability due to scale formation consider-ably affects seepage flow and alkaline flooding process in return. The objective of this study is to firstly examine these mutual influential phenomena and corresponding mecha-nisms along with EOR during alkaline flooding when the effects of precipitation are no longer negligible. The chem-ical kinetic theory is applied for the specific fundamental reactions to describe the process of rock dissolution in silica-based reservoirs. The solubility product principle is used to analyze the mechanism of alkali scale formation in flooding. Then a 3D alkaline flooding coupling model accounting for the variation of porosity and permeability is established to quantitatively estimate the impact of alkali scales on reser-voir stratum. The reliability of the present model is verified in comparison with indoor experiments and field tests of the Daqing oil field. Then, the numerical simulations on a 1/4 well group in a 5-spot pattern show that the precipitation grows with alkali concentration, temperature, and injection pressure and, thus, reduces reservoir permeability and oil recovery correspondingly. As a result, the selection of alkali with a weak base is preferable in ASP flooding by tradeoff strategy.     

A characterization of the coupled evolution of grain fabric and pore space using complex networks: Pore connectivity and optimized flows in the presence of shear bands

A framework for the multiscale characterization of the coupled evolution of the solid grain fabric and its associated pore space in dense granular media is developed. In this framework, a pseudo-dual graph transformation of the grain contact network produces a graph of pores which can be readily interpreted as a pore space network. Survivability, a new metric succinctly summarizing the connectivity of the solid grain and pore space networks, measures material robustness. The size distribution and the connectivity of pores can be characterized quantitatively through various network properties. Assortativity characterizes the pore space with respect to the parity of the number of particles enclosing the pore. Multiscale clusters of odd parity versus even parity contact cycles alternate spatially along the shear band: these represent, respectively, local jamming and unjamming regions that continually switch positions in time throughout the failure regime. Optimal paths, established using network shortest paths in favor of large pores, provide clues on preferential paths for interstitial matter transport. In systems with higher rolling resistance at contacts, less tortuous shortest paths thread through larger pores in shear bands. Notably the structural patterns uncovered in the pore space suggest that more robust models of interstitial pore flow through deforming granular systems require a proper consideration of the evolution of in situ shear band and fracture patterns – not just globally, but also inside these localized failure zones.     

Porous alumina-based fluorous liquid membranes: Dependence of transport on fluorous solvent

We report here the properties of supported fluorous liquid membranes based on porous alumina. The alumina is first rendered compatible with fluorous solvents by surface modification with an oligomeric perfluoropropylene oxide-based carboxylic acid, Krytox 157FSH. After modification, simply dipping the porous alumina membrane into a perfluorinated solvent results in a supported liquid membrane with high selectivity for fluorous compounds. Two homologous series of compounds differing in the number of -CF₂- groups were investigated, namely esters of cinnamyl alcohol and the analogous naphthyl derivative with 2H,2H,3H,3H-perfluoroalkanoic acids (HOOC-(CH₂)₂-(CF₂)_m−1CF₃, m = 2, 4, 6 and 8). Four perfluorinated membrane solvents (FC-77, PF-5080, FC-3283 and FC-43) were investigated. In FC-3283, the permeabilities, which are the products of a diffusion coefficient and a partition coefficient in the solution-diffusion model, of cinnamyl alcohol derivatives are 3.62 ± 0.36 times greater than those of the analogous naphthyl compounds for the solutes containing the same perfluorinated chain. Permeability, P, increases as the perfluorinated chain length increases in all of the perfluorinated solvents. Values of log(P) vs m are linear with a slope of 0.147 ± 0.002 but with different intercepts for the various solvents. Independent measurements of the partition coefficients of the solutes between the source/receiving phase solvent, ethanol, and the fluorous solvents reveal that the selectivity behavior is dominated by partitioning rather than diffusion. The free energy of transfer of a -CF₂- group (ethanol to perfluorinated solvents) is −1.1 kJ/mol. Despite the fact that the solvents are mixtures, not pure liquids, the partition coefficients are well correlated with values calculated based on group contributions with ‘mobile order and disorder’ theory. The diffusion coefficients of four solutes in four membrane solvents were also determined based on the solution-diffusion model. The Stoke-Einstein equation shows satisfactory estimation of experimental results.     

Size-dependent magnetic properties of FeGaB/Al2O3 multilayer micro-islands

Recently, micrometer-size patterned magnetic materials have been widely used in MEMS devices. However, the self-demagnetizing action is significantly influencing the performance of the magnetic materials in many MEMS devices. Here, we report an experimental study on the magnetic properties of the patterned micro-scale FeGaB/Al₂O₃ multilayers. Ferromagnetic hysteresis loop, ferromagnetic resonance (FMR), permeability and domain behavior have been demonstrated by complementary techniques. Magnetic annealing was used to enhance the performance of magnetic multilayers. The comparisons among micro-islands with different sizes in the range of $200\mathrm{\mu }\text{m}～500\mathrm{\mu }\text{m}$ as well as full film show a marked influence of size-effect, the exchange coupling effect, and the different domain structures inside the islands.     

含磁芯线圈动态电感计算

 从电感的基本定义出发，推导了一个新的递推公式，可准确地对含磁芯线圈动态电感进行数值计算，并在纯电感、含有5匝磁芯线圈和含有17块铁氧体大环磁芯的感应腔在双脉冲励磁情况下分别计算了动态电感量，验证了该方法的可行性。通过电感值可反推出磁芯在各种情况下磁导率的变化曲线，从而确定磁芯的磁特性及其适用范围。     

Novel sepiolite reinforced emerging composite polymer electrolyte membranes for high-performance direct methanol fuel cells

Methanol permeation is the main issue of Nafion membranes when they are used as a polymer electrolyte membrane (PEM) in direct methanol fuel cells (DMFCs). In the current study, novel nanocomposite polymer membranes are prepared by the integration of surface-modified sepiolite (MS) in polyvinylidene fluoride grafted polystyrene (PVDF-g-PS) copolymer as PEM in DMFCs. Sepiolite (SP) surface is chemically modified using vinyltriethoxysilane and analyzed by Fourier-transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), and scanning electron microscopy (SEM). Nanocomposite PVDF-g-PS/MS membranes are prepared by phase inversion technique and subsequently treated with chlorosulfonic acid to induce sulfonic acid (SO₃H) active sites at the membrane surface. The prepared nanocomposite membranes (S-PPMS) are analyzed for their physicochemical characteristics in terms of water uptake percentage, cation exchange capacity, proton conductivity (σ), and methanol permeability. MS dispersion in the copolymer matrix is proved through morphological SEM examination. The S-PPMS membranes exhibit increased proton conductivity due to the presence of well-dispersed MS and surface functional –SO₃H groups. A peak power density of 210 mWcm^?2 is recorded for S-PPMS10 at 110 °C, which is higher than the output obtained from Nafion-117. These promising results indicate the potential utilization of prepared nanocomposite PEMs for DMFC application.     

Permeability of periodic arrays of spheres

For periodic arrays of spheres the permeability is obtained numerically as a function of the dimensionless wave number kD in the flow direction, where D is the sphere diameter, k = 2π/λ is the wave number, and λ is the distance between the spheres in the flow direction. Our numerical results for the solids fraction of 0.45 show that for kD < 6.5 the permeability increases with increasing kD. But, it decreases for 6.5 < kD < 8.5 and reaches a local minimum at kD  8.5, and then increases again with increasing kD. Since the Fourier spectrum of the area fraction is zero for kD = 8.98, this result suggests that the area fraction plays an important role in determining the dependence of permeability on the distance between the spheres in the flow direction. For smaller solids fractions, the positions of the local maximum and minimum of permeability shift to slightly smaller kD’s.     

A new simulation framework for predicting the onset and effects of fines mobilization

Fines release and migration is a universal problem in the production of oil from poorly consolidated sandstone reservoirs. This problem can result in the changes of porosity and permeability. It may not only damage a production facility, but it can also have a profound effect on oil recovery, resulting from the change in heterogeneity of the oil formation. Based on the macroscopic continuous porous media, continuity equations for multiphase flow in oil formations, and the theories of fines release and migration, a three-dimensional (3D) field scale mathematical model describing migration of fines in porous media is developed. The model is solved by a finite-difference method and the line successive over relaxation (LSOR) technique. A numerical simulator is written in Fortran 90 and it can be used to predict (1) the ratio of fines to production liquid volume, (2) the permeability change caused by colloidal and hydrodynamic forces resulting from fines release and migration, and (3) production performance. The numerical results of the one-dimensional model were verified by the data obtained by core displacement experiments. The sensitivity of numerical results with grid block size was studied by coarse grids, moderate grids, and fine grids. In addition, an oil field example with five-spot patterns was made on the numerical simulator. The results show that fines migration in an oil formation can accelerate the development of heterogeneity of the reservoir rock, and has an obvious influence on production performance, i.e., water drive front, water-cut trends, and oil recovery.     

Stress-induced fluid flow anisotropy in fractured rock

Anisotropic stress states are common in the upper crust and result in fracture apertures being dependent on fracture orientation. Fractured rocks should therefore display an anisotropic permeability determined by the aperture, length, and orientation of those fractures remaining open. In this paper, a numerical study of this effect is made for a rock containing two orthogonal fracture sets subject to a uniaxial compressive stress applied perpendicular to one of the sets. With increasing compressive stress, the decreasing aperture of fractures orientated perpendicular to the stress axis leads to a decrease in permeability both parallel and perpendicular to the stress. For flow parallel to the stress direction, this is a consequence of the finite length of the fractures, flow in fractures perpendicular to the stress being required to connect fractures orientated parallel to the stress direction. As the number of fractures is decreased towards the percolation threshold, the average permeability tensor is found to become increasingly isotropic. This behaviour results from the highly tortuous nature of the flow paths just at the percolation threshold.