An investigation of lipase catalysed sonochemical synthesis: A review

Ultrasonic irradiation has recently gained attention of researchers for its process intensification in numerous reactions. Earlier ultrasound was known for its application either to deactivate enzyme activity or to disrupt the cell. However, in recent years, practice of ultrasonic irradiation began to emerge as a tool for the activation of the enzymes under mild frequency conditions. The incorporation of ultrasound in any of enzymatic reactions not only increases yield but also accelerates the rate of reaction in the presence of mild conditions with better yield and less side-products. To attain maximum yield, it is crucial to understand the mechanism and effect of sonication on reaction especially for the lipase enzyme. Thus, the influence of ultrasound irradiation on reaction yield for different parameters including temperature, enzyme concentration, mole ratio of substrates, solvents ultrasonic frequency and power was reviewed and discussed. The physical effect of cavitation determined by bubble dynamics and rate of reaction through kinetic modelling also needs to be assessed for complete investigation and scale up of synthesis. Thus, prudish utilisation of ultrasound for enzymatic synthesis can serve better future for sustainable and green chemistry.     

Using developed creep constitutive model for optimum design of HDPE pipes

Unlike metal pipes, high density polyethylene (HDPE) pipes are not susceptible to erosion and corrosion. However, the most important mechanical feature of the HDPE pipes is that this material creeps even at room temperature. Therefore, it is essential to study the creep behavior of this material in order to develop a model. In this paper, creep behavior of HDPE at different temperature and stress levels has been experimentally studied to obtain the creep constitutive parameters of the material. These parameters are used to predict the creep behavior of different structures such as HDPE pipes. For this purpose, a number of specimens have been machined from industrial manufactured pipe walls. Uniaxial creep tests have been carried out and creep strain curves with time for each test were recorded. Then, a constitutive model is proposed for HDPE based on the experimental data and optimization methods. The results of this model have been compared with the test data and good agreement is observed. The developed constitutive model and reference stress method (RSM) were used to produce graphs which provide optimum creep lifetime and design conditions for HDPE pipes that are subjected to combined internal pressure and rotation. These graphs can facilitate the design process of HDPE pipes.     

Removal of methylene blue by two zeolites prepared from naturally occurring Egyptian kaolin as cost effective technique

The optimum condition as well as adsorption behavior of two zeolite types prepared from Egyptian kaolin (namely, zeolite A and zeolite X) with methylene blue (MB) are demonstrated in this study. This will be a step to remove such dyes from textile as well as dying industries.MB removal was investigated using synthetic solutions at initial concentrations 15 mg/L of MB at constant temperature and pH (25 ± 0.1 °C and 7.5 ± 0.2) respectively. The removal efficiency was determined at different contact times and different zeolite doses.The optimum contact times for the removal of MB were 60 min and 75 min for zeolite X and zeolite A, respectively. 0.6 g was the optimum dose for removal of MB with both zeolite types.The batch method has been employed, using MB concentration in solution ranging from 2 to 25 mg/L. The percentage removal and distribution coefficients (K_d) were determined for the adsorption system as a function of sorbate concentration. The isothermal models investigated in this study show that adsorption ratios of MB on both zeolites match to Langmuir and Freundlich equation adding to that every equation constant has been calculated. According to the equilibrium studies, adsorption of zeolite X in higher concentrations is much better than that of zeolite A. Dublin–Kaganer–Radushkevich (DKR) shows physisorption endothermic adsorption process for both zeolites and also linear correlation of Redlich–Peterson and Tekman isothermal models were proved.These results show that zeolites prepared from naturally abundant Egyptian kaolin hold great potential to remove dying materials such as MB from wastewater. This will encourage using such low cost technique in removal of dyes from industrial wastewater.     

螺栓紧固型纵振换能器设计考虑

本文采用网络传输法分析了螺栓紧固型纵振换能器的设计方法，并考虑了换能器结构件的内部机械损耗和压电元件的电损耗，数值计算了换能器谐振特性及书面位置，结果与实验情况一致。     

锚杆桩优化设计理论

本文提出了一道锚杆桩优化设计理论。实例分析表明, 优化设计方法比传统设计方法能大大降低工程造价。     

掺Er3+飞秒光纤放大器的特性研究

依据二能级速率方程和光传输方程,理论计算了Er3+光纤放大器中Er3+光纤的最佳长度Lc. 以全光纤飞秒激光器输出的孤子脉冲作为种子源,以理论值Lc作为实际采用的光纤长度,实验测量了Er3+光纤放大器在同向泵浦和反向泵浦下信号光的输出功率,得到同向泵浦的增益为20.0dB, 反向泵浦的增益为20.2 dB.同时测量了脉冲宽度随泵浦功率的变化,实验结果表明,随着泵浦功率的增大,输出光脉冲的宽度的压缩效应经历逐渐增强后逐渐减弱的过程.在同向泵浦方式下,可以得到更短的输出脉宽,其最短脉冲宽度为260 fs.     

Extraction of polyunsaturated fatty acid ethyl esters from sardine oil using Ag-containing o/w/o emulsion liquid membranes

Using silver ion as a carrier in o/w/o type emulsion liquid membranes, batch-wise extraction experiments were performed to separate polyunsaturated fatty acid ethyl esters originating in sardine oil. It was possible to separate polyunsaturated fatty acid (PUFA) esters from the mixture of PUFA and saturated fatty acid esters. The operating conditions for stable liquid membranes were experimentally determined. A new membrane breakage model that successfully describes the membrane stability behavior is proposed.     

Multi-wheel drive vehicle energy/fuel efficiency and traction performance: Objective function analysis

This paper presents the results of a mathematical analysis, computational results, and experimental data related to the multi-wheel drive vehicle energy/fuel efficiency and vehicle tractive and velocity operational properties evaluation.Power distributions to the drive wheels provided by vehicle driveline systems are the major factors in pre-determining the vehicle energy/fuel efficiency. The objective function mathematical analysis has led to some important practical recommendations for designing better driveline systems. Generally, the maximum efficiency of a vehicle is provided by wheel power distributions that are under unequal slips of the vehicle tires. However, optimum driveline systems are expected to be designed in a way that leads to the same slips for all the tires.The mathematical analysis, computational results, and experimental data are presented in a combination with the results of a century-long scientific discussion on the problem under consideration. Details are in the paper.     

Optimum phase matching and effective nonlinear coefficients of LBO and KTP for continuously changing wavelength

In this paper, the optimum phase matching and the effective nonlinear coefficient of KTP and LBO type I and type II were calculated in continuously changing wavelength by the method using Miller rule and Sellmeier equation. The difference of the effective nonlinear coefficients calculated by the proposed method and the approximate method was discussed. The results show that the approximate calculations using the value of 1.064 μm wavelength will yield greater errors in frequency conversion. The results presented in the paper are in accordance with the experiment results.     

A new frequency domain based approach for a nonlinear aeroelasticity analysis

In this paper, a new frequency-domain based approach for the investigation of aeroelasticity problems is introduced that is capable of handling both linear and nonlinear problems. This approach is based on coupling a conceptual method used in a structural dynamic analysis and an optimum equivalent linear frequency response function (OELF). Additionally, a new criterion for determining the flutter speed and the instability of nonlinear systems is introduced that is based on the condition number of the aeroelastic matrices. Due to the global nature of the condition number, the new criterion proves to be efficient and simple to use. To examine the efficiency of the new technique, a two-dimensional nonlinear airfoil with an unsteady aerodynamic model is considered.