全文获取类型
收费全文 | 3308篇 |
免费 | 288篇 |
国内免费 | 178篇 |
专业分类
化学 | 1541篇 |
晶体学 | 22篇 |
力学 | 344篇 |
综合类 | 6篇 |
数学 | 528篇 |
物理学 | 1333篇 |
出版年
2024年 | 2篇 |
2023年 | 80篇 |
2022年 | 66篇 |
2021年 | 80篇 |
2020年 | 99篇 |
2019年 | 63篇 |
2018年 | 75篇 |
2017年 | 120篇 |
2016年 | 136篇 |
2015年 | 111篇 |
2014年 | 189篇 |
2013年 | 240篇 |
2012年 | 162篇 |
2011年 | 223篇 |
2010年 | 186篇 |
2009年 | 243篇 |
2008年 | 255篇 |
2007年 | 236篇 |
2006年 | 201篇 |
2005年 | 166篇 |
2004年 | 128篇 |
2003年 | 107篇 |
2002年 | 82篇 |
2001年 | 73篇 |
2000年 | 52篇 |
1999年 | 51篇 |
1998年 | 61篇 |
1997年 | 45篇 |
1996年 | 28篇 |
1995年 | 24篇 |
1994年 | 24篇 |
1993年 | 22篇 |
1992年 | 16篇 |
1991年 | 15篇 |
1990年 | 10篇 |
1989年 | 19篇 |
1988年 | 13篇 |
1987年 | 8篇 |
1986年 | 10篇 |
1985年 | 8篇 |
1983年 | 4篇 |
1982年 | 11篇 |
1981年 | 6篇 |
1980年 | 8篇 |
1979年 | 2篇 |
1978年 | 2篇 |
1977年 | 5篇 |
1970年 | 2篇 |
1969年 | 1篇 |
1957年 | 2篇 |
排序方式: 共有3774条查询结果,搜索用时 0 毫秒
101.
一维导电材料例如纳米线,大量应用于柔性压力传感器中. 但是一维材料和基底之间接触时相互作用力较弱,使得传感器灵敏度、响应时间、和循环寿命等性能指标有待进一步提高. 针对这些问题,设计了石墨烯/石墨烯卷轴多分子层复合薄膜作为传感器导电层. 石墨烯卷轴具有一维结构,而石墨烯的二维结构可以牢固地固定卷轴,以确保高导电性复合薄膜与基底之间的粘附性,同时整体结构的导电通道得到了增加. 由于一维和二维结构的协同效应,实现了应变灵敏度系数3.5 kPa-1、 响应时间小于50 ms、能够稳定工作1000次以上的压阻传感器. 相似文献
102.
Natural fibers are inexpensive, biodegradable, and have similar specific properties to some synthetic fibers. Hardly any previous investigations exist of a composite made of multiple layers of pure Kevlar fiber fabric and pure Flax fiber fabric in a “sandwich structure”, but it only measured impact properties. The composite was made of 12 Flax/epoxy layers at the core in 3 possible configurations (i.e. [0]12F, [0/90]6F, or [±45]6F) that were sandwiched by 2 Kevlar/epoxy layers (i.e. plain weave) on each side. This study showed maximum change in the mechanical properties with respect to Flax/Epoxy for tension (+137.85% in ET, and +171.22% in σUT), compression (+171.22% in Ec, and −10.6% in σUC), 3-point bending (−11.54% in EB, and +2.19 in σUB), torsion (−5.31% in G, and 395.82% in τ), and water absorption (60.04%). This novel hybrid composite may be useful for research and industry applications. 相似文献
103.
《中国化学快报》2020,31(6):1415-1421
Electrocatalytic CO_2 reduction(CO_2 ER) into formate is a desirable route to achieve efficient transformation of CO_2 to value-added chemicals,however,it still suffers from limited catalytic activity and poor selectivity.Herein,we develop a hybrid electrocatalyst composed of bismuth and bismuth oxide nanoparticles(NPs) supported on nitrogen-doped reduced graphene oxide(Bi/Bi_2 O_3/NrGO) nanosheets prepared by a combined hydrothermal with calcination treatment.Thanks to the combination of undercoordinated sites and strong synergistic effect between Bi and Bi_2 O_3,Bi/Bi_2 O_3/NrGO-700 hybrid displays a promoted CO2 ER catalytic performance and selectivity for formate production,as featured by a small onset potential of-0.5 V,a high current density of-18 mA/cm~2,the maximum Faradaic efficiency of85% at-0.9 V,and a low Tafel slope of 166 mV/dec.Experimental results reveal that the higher CO_2 ER performance of Bi/Bi_2 O_3/NrGO-700 than that of Bi NPs supported on NrGO(Bi/NrGO) can be due to the partial reduction of Bi_2 O_3 NPs into Bi,which significantly increases undercoordinated active sites on Bi NPs surface,thus boosting its CO_2 ER performance.Furthermore,a two-electrode device with Ir/C anode and Bi/Bi_2 O_3/NrGO-700 cathode could be integrated with two alkaline batteries or a planar solar cell to achieve highly active water splitting and CO_2 ER. 相似文献
104.
105.
Well-known as a hazardous compound, nitrite constitute a real threat to the public health. So, there is a pressing need to detect and quantify them in different matrix. Even though conventional analytical methods can be used to address this issue, electrochemistry allows a fast, sensitive, and efficient analysis. Conducting polymers continue to raise great interest among scientific communities due to their properties. Moreover, their combination with carbon nanomaterials, or metallic nanoparticles improves their properties, and provides great results. In this paper, we will focus on some revealing works devoted to the electrochemical detection of nitrite using this kind of materials. 相似文献
106.
The effectiveness of hybrid drying based on convective drying with application of ultrasound and microwave enhancement is the main subject of the studies. The drying kinetics, energy consumption as well as the quality aspect of green pepper is analysed. It was shown that hybrid drying methods shorten significantly the drying time, reduce the energy consumption and affect positively the quality factors. Each of the analysed aspects depend on combination of the convective-ultrasound-microwave drying programs. Besides, based on the drying model elaborated earlier by one of the authors, the effects of ultrasound on convective drying assessed by such phenomena as “heating effect”, “vibration effect” and “synergistic effect” are presented. 相似文献
107.
Sayyeda M. Hasan Landon D. Nash Duncan J. Maitland 《Journal of polymer science. Part A, Polymer chemistry》2016,54(14):1300-1318
Porous shape memory polymers (SMPs) exhibit geometric and volumetric shape change when actuated by an external stimulus and can be fabricated as foams, scaffolds, meshes, and other polymeric substrates that possess porous three-dimensional macrostructures. These materials have applications in multiple industries such as textiles, biomedical devices, tissue engineering, and aerospace. This review article examines recent developments in porous SMPs, with a focus on fabrication methods, methods of characterization, modes of actuation, and applications. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2016 , 54, 1300–1318 相似文献
108.
In this Letter, we construct the quasi-normal modes of three-dimensional extremal black holes in an algebraic way. We show that the infinite towers of the quasi-normal modes of scalar, vector and tensor could be constructed as the descendents of the highest weight modes. Our investigation shows that the hidden conformal symmetry suggested in Chen et al. (2010) [5] is an intrinsic property of the extremal black hole. Moreover, we notice that we need to fix the freedom in defining the local vector fields and find the right hidden conformal symmetry to obtain the physical quasi-normal modes. 相似文献
109.
N.J. Balmforth 《Communications in Nonlinear Science & Numerical Simulation》2012,17(5):1989-1997
Numerical computations are presented of the BGK-like states that emerge beyond the saturation of the bump-on-tail instability in the Vlasov-Poisson system. The stability of these states towards subharmonic perturbations is explored in order to gauge whether the primary bump-on-tail instability always suffers a secondary instability that precipitates wave mergers and coarsening of the BGK pattern. Because the onset of the bump-on-tail instability occurs at finite wavenumber, and the spatially homogeneous state is not itself unstable to spatial subharmonics, it is demonstrated that mergers and coarsening do not always occur, and the dynamics displays a richer spatio-temporal complexity. 相似文献
110.
We investigate the stability and phase transition of localized modes in Bose–Einstein Condensates (BECs) in an optical lattice with the discrete nonlinear Schrödinger model by considering both two- and three-body interactions. We find that there are three types of localized modes, bright discrete breather (DB), discrete kink (DK), and multi-breather (MUB). Moreover, both two- and three-body on-site repulsive interactions can stabilize DB, while on-site attractive three-body interactions destabilize it. There is a critical value for the three-body interaction with which both DK and MUB become the most stable ones. We give analytically the energy thresholds for the destabilization of localized states and find that they are unstable (stable) when the total energy of the system is higher (lower) than the thresholds. The stability and dynamics characters of DB and MUB are general for extended lattice systems. Our result is useful for the blocking, filtering, and transfer of the norm in nonlinear lattices for BECs with both two- and three-body interactions. 相似文献