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31.
Most adhesives and binders, including bitumen for asphalt mixture production, are presently produced from petrochemicals after
the refining of crude oil. The fact that crude oil reserves are a finite resource means that in the future, it may become
necessary to produce these materials from alternative and probably renewable sources. Suitable resources of this kind may
include polysaccharides, plant oils and proteins. This paper deals with the synthesis of polymer binders from monomers that
could, in future, be derived from renewable resources. These binders consist of polyethyl acrylate (PEA) of different molecular
weight, polymethyl acrylate (PMA) and polybutyl acrylate (PBA), which were synthesised from ethyl acrylate, methyl acrylate
and butyl acrylate, respectively, by atom transfer radical polymerisation. The rheological properties of these binders were
determined by means of oscillatory testing using a dynamic shear rheometer and combinations of stress/strain, temperature
and frequency sweeps. The results indicate that PEA can be produced to have rheological properties similar to that of ‘soft’
100/150 penetration grade bitumen, PMA with similar rheological properties to that of ‘hard’ 10/20 penetration grade bitumen,
while PBA, due to its highly viscous nature and low dynamic moduli, cannot be used on its own as a binder. The synthetic polymers
were found to be thermo-rheologically simple, and the shift factors, used to produce the dynamic moduli master curves, were
found to fit an Arrhenius function. 相似文献
32.
33.
Faison P. Gibson 《Computational & Mathematical Organization Theory》2007,13(1):39-61
An important aspect of learning is the ability to transfer knowledge to new contexts. However, in dynamic decision tasks, such as bargaining, firefighting, and process control, where decision makers must make repeated decisions under time pressure and outcome feedback may relate to any of a number of decisions, such transfer has proven elusive. This paper proposes a two-stage connectionist model which hypothesizes that decision makers learn to identify categories of evidence requiring similar decisions as they perform in dynamic environments. The model suggests conditions under which decision makers will be able to use this ability to help them in novel situations. These predictions are compared against those of a one-stage decision model that does not learn evidence categories, as is common in many current theories of repeated decision making. Both models' predictions are then tested against the performance of decision makers in an Internet bargaining task. Both models correctly predict aspects of decision makers' learning under different interventions. The two-stage model provides closer fits to decision maker performance in a new, related bargaining task and accounts for important features of higher-performing decision makers' learning. Although frequently omitted in recent accounts of repeated decision making, the processes of evidence category formation described by the two-stage model appear critical in understanding the extent to which decision makers learn from feedback in dynamic tasks.
Faison (Bud) Gibson is an Assistant Professor at College of Business, Eastern Michigan University. He has extensive experience developing and empirically testing models of decision behavior in dynamic decision environments. 相似文献
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35.
Smooth Solutions to Optimal Investment Models with Stochastic Volatilities and Portfolio Constraints
Pham 《Applied Mathematics and Optimization》2002,46(1):55-78
Abstract. This paper deals with an extension of Merton's optimal investment problem to a multidimensional model with stochastic volatility
and portfolio constraints. The classical dynamic programming approach leads to a characterization of the value function as
a viscosity solution of the highly nonlinear associated Bellman equation. A logarithmic transformation expresses the value
function in terms of the solution to a semilinear parabolic equation with quadratic growth on the derivative term. Using a
stochastic control representation and some approximations, we prove the existence of a smooth solution to this semilinear
equation. An optimal portfolio is shown to exist, and is expressed in terms of the classical solution to this semilinear equation.
This reduction is useful for studying numerical schemes for both the value function and the optimal portfolio. We illustrate
our results with several examples of stochastic volatility models popular in the financial literature. 相似文献
36.
In this paper, we propose the treatment of complex reservoir operation problems via our newly developed tool of fuzzy criterion
decision processes. This novel approach has been shown to be a more flexible and useful analysis tool especially when it is
desirable to incorporate an expert’s knowledge into the decision models. Additionally, it has been demonstrated that this
form of decision models will usually result in an optimal solution, which guarantees the highest satisfactory degree. We provide
a practical exemplification procedure for the models presented as well as an application example. 相似文献
37.
We examine a sequential selection problem in which a single option must be selected. Each option's value is a function of its attributes, whose precise values can be ascertained at a given cost. We prove the optimality of a threshold stopping rule for a general class of objective functions. 相似文献
38.
Two-component thermo-responsive hydrogels poly(N-isopropylacrylamide)-co-vinylbenzyltrimethylammonium chloride (NIPA-co-VBT) and poly(N-isopropylacrylamide)-co-p-sodium styrene sulphonate (NIPA-co-SSS) were prepared by using high energy gamma radiation. The gels were characterized by Fourier transformed infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and sol-gel analysis. The presence of ionic monomers in NIPA leads to lower gel content. Introduction of ionic components in the matrix enhanced swelling extent but caused slower volume transition. The swelling studies in alcohol indicated that swelling extent was function of polarity of the swelling medium and all gels followed the order water > methanol > ethanol > iso-propanol. In mixed co-solvents (water-alcohol), they exhibit complex reentrant behavior. The co-polymer gels containing VBT swelled faster and to higher extent than those containing SSS. The dynamic swelling studies indicated that diffusion of water in PNIPA gel shifts from Fickian for PNIPA to anomalous for NIPA-co-ionic gels also the mean swelling time (MST) decreases for gels containing ionic monomers. 相似文献
39.
The new research reactor FRM-II near Munich has a strong positron source, which delivers an intense, nearly monoenergetic positron beam. Our positron systems, the pulsed low energy positron source (PLEPS) and the scanning positron microscope (SPM) will be operated at this beam. Some aspects of matching these systems to the new positron source will be discussed.Considerable improvements are expected, e.g. more than 105 s−1 recorded events at PLEPS and sub-micrometre resolution at SPM. They will enable investigations in so far inaccessible problems like the evaluation of annihilation characteristics and trapping constants of individual defects or studies of fast dynamical processes. In applied materials science complex defect structures will be studied which demand a resolution into many differing lifetimes, e.g. fractured specimens, wear, corrosion, etc. Also large series of measurements at small systematic modifications are planned. There is also the opportunity to analyse in addition the chemical microstructure of the specimens by means of a hydrogen microprobe and other ion beam techniques available close to FRM-II at the Technical University of Munich. 相似文献
40.