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131.
132.
Almstetter MF Appel IJ Dettmer K Gruber MA Oefner PJ 《Journal of chromatography. A》2011,1218(39):7031-7038
The alignment algorithm Statistical Compare (SC) developed by LECO Corporation for the processing of comprehensive two-dimensional gas chromatography-time-of-flight mass spectrometry (GC×GC-TOFMS) data was validated and compared to the in-house developed retention time correction and data alignment tool INCA (Integrative Normalization and Comparative Analysis) by a spike-in experiment and the comparative metabolic fingerprinting of a wild type versus a double mutant strain of Escherichia coli (E. coli). Starting with the same peak lists generated by LECO's ChromaTOF software, the accuracy of peak alignment and detection of 1.1- to 4-fold changes in metabolite concentration was assessed by spiking 20 standard compounds into an aqueous methanol extract of E. coli. To provide the same quality input signals for both alignment routines, the universal m/z 73 trace of the trimethylsilyl (TMS) group was used as a quantitative measure for all features. The performance of data processing and alignment was evaluated and illustrated by ROC curves. Statistical Compare performed marginally better at the lower fold changes, while INCA did so at the higher fold changes. Using SC, quantitative precision could be improved substantially by exploiting the signal intensities of metabolite-specific unique (U) m/z ion traces rather than the universal m/z 73 trace. A list of 56 features that distinguished the two E. coli strains was obtained by the SC alignment using m/z U with an estimated false discovery rate (FDR) of <0.05. Ultimately, 23 metabolites could be identified, one additional and five less than with INCA due to the failure of SC to extract unitized m/z U's across all fingerprints with suitable spectral intensities for the latter metabolites. 相似文献
133.
134.
We consider the cost of general orthogonal range queries in random quadtrees. The cost of a given query is encoded into a (random) function of four variables which characterize the coordinates of two opposite corners of the query rectangle. We prove that, when suitably shifted and rescaled, the random cost function converges uniformly in probability towards a random field that is characterized as the unique solution to a distributional fixed-point equation. We also state similar results for 2-d trees. Our results imply for instance that the worst case query satisfies the same asymptotic estimates as a typical query, and thereby resolve an open question of Chanzy et al. (2001). 相似文献
135.
万升联 《数学物理学报(A辑)》2021,(1):237-244
该文研究一种新的解变分不等式的二次投影算法.通过构造一类新的严格分离当前迭代和变分不等式解集的超平面,进而建立了解决伪单调变分不等式投影算法的一种新的框架.通过改进已有结果的证明方法,证明了该算法生成的无穷序列是全局收敛的,并且在局部误差和Lipschitz条件下给出了收敛率分析. 相似文献
136.
The self-alignment of some 1P1- level of alkaline-earth elements in a hollow cathode discharge is investigated. The radiative lifetimes and the signal broadening constants are determined from the Hanle signals. 相似文献
137.
V. A. Tolkachev 《光谱学快报》2013,46(4):293-294
During plasma spectrum investigation in a discharge tube with hollow cathode, the conventional flat bottom of which is replaced with a conical one(1), an increase of the line intensity of the cathode material, as well as of the introduced sample, is observed (2,3,4); at the same time, the lines of the buffer gas change weakly (mostly decrease) their intensity. 相似文献
138.
Mario Villalobos-Arias Carlos A. Coello Coello Onésimo Hernández-Lerma 《Mathematical Methods of Operations Research》2006,64(2):353-362
In this paper we consider a simulated annealing algorithm for multiobjective optimization problems. With a suitable choice of the acceptance probabilities, the algorithm is shown to converge asymptotically, that is, the Markov chain that describes the algorithm converges with probability one to the Pareto optimal set. 相似文献
139.
A simple technique for the alignment of a dispersive ring cavity consisting of a reflection-grating and two mirrors is described. Lasing on different rotational–vibrational transitions of CO2 molecule is achieved in the ring configuration. 相似文献
140.
本文考察了一类非线性Kundu方程的周期初值问题,提出了一种弱守恒的差分格式,对其差分解作了先验估计,证明了格式的收敛性与稳定性,最后,通过数值计算检验了格式的可信性. 相似文献