Fabrication and electrochemistry study of multi-thiol coronary molecule monolayers

Single-component monolayer of novel multi-thiol coronary molecule and two-component mixed monolayer composed of coronary molecule and n-alkanethiol on gold substrates are described. The assembly of monolayers is characterized by ellipsometry, infrared spectroscopy and X-ray photoelectron spectroscope. The electrochemical properties of the single- and two-component monolayers are evaluated by cyclic voltammetry and electrochemical impedance spectroscopy experiments. Coronary molecule with multi-thiol groups has the ability to form stable monolayer via the interaction of mercapto groups and Au surface. Electrochemical impedance measurements indicate that 89.9% of the gold surface is blocked by the coronary molecule, which is attributed to the special spatial structure of the coronary molecule. The uncovered site on gold surface in coronary molecule monolayer could be occupied by the second suitable molecule. The mixed monolayer prepared by stepwise assembly of coronary molecule and n-alkanethiol has complete compact packing and few defects.     

LOM and HOM damping study in a superconducting deflecting cavity for ALS at LBNL

Superconducting deflecting cavities can be used in synchrotron light source to generate subpicosecond X-ray pulses while the impedance of the lower order modes (LOM) and higher order modes (HOM) in the cavity should be kept below an accepted level to avoid beam instability. These modes can be damped by adding waveguide on beam pipe. Detailed simulation of Q in CST Microwave Studio is introduced and experiment results on an aluminum model cavity with damping waveguide are reported to make a comparison.     

Trivalent Cation Substitution Effect into Layered Double Hydroxides Co2Fey Al1−y(OH)6Cl·nH2O: Study of the Local Order: Ionic Conductivity and Magnetic Properties

A series of layered double hydroxide materials of composition Co₂Fe_yAl_1−y(OH)₆Cl·nH₂O (0≤y≤1) was prepared via chimie douce. The crystalline parameter related to the cation to cation distance obeys the expected variation, showing that the substitution is effective over the entire range. Local order around Co and Fe cations is studied by X-ray absorption spectroscopy. Moduli of the Fourier transform at the Fe K-edge are superimposable, in agreement with an ordered model, although present in small domains since no superlattice is depicted. The ionic resistivity of the samples is highly dependent on the water molecule content. The conductivity is found to be thermally assisted, and the variation of the slope in the Arrhenius diagram is explained by a Vogel-Tamman-Fulcher-type behavior. Magnetic susceptibility measurements support the proposed cation composition and indicate the onset of local magnetic order at low temperature (below 10 K). The inter-sheet distance influences the magnetic response at low temperature, showing the presence of weak interactions between lamellae.     

Origin of cathodic degradation and new phase formation at the La0.9Sr0.1MnO3/YSZ interface

New phase formation at the La_0.9Sr_0.1MnO₃/YSZ interface and its effects on the cathodic performances were studied at 900 °C in air. The resistance caused by the interfacial product layer kept increasing with time to reach up to 40% of the total resistance after 500 h. The interfacial product was identified as La₂Zr₂O₇ by XRD measurement. The electrical conductivity of La₂Zr₂O₇ (2.4 × 10⁻⁵ S cm⁻¹ at 1000 °C), measured by AC impedance and current interruption methods, was 4 to 7 orders of magnitude smaller than those of La_0.9Sr_0.1MnO₃ electrode or YSZ electrolyte. Either the electronic conductivity or the electrochemical O₂ reduction activity of La₂Zr₂O₇ was negligible. Combining these results, a conclusion was made that the cathodic degradation comes mainly from the growth of interfacial product layer and its contribution to the cell resistance increment is ohmic in nature.     

HL—1M装置ICRH天线设计及最佳耦合研究

本文对HL-1M装置离子回旋共振加热(ICRH)天线设计及最佳耦合研究所采用的数值计算公式进行了推导。对天线耦合有重要作用的特征电阻R、特征电感L和特征电容C进行了数值计算。讨论了天线几何尺寸,等离子体参数对ICRH的影响,比较了3维和2维数值计算的结果,从中得到了HL-1M条件下最佳功率耦合的天线几何参数和设计的指导原则。     

Influence of electrolyte characteristics on the electrochemical parameters of electrical double layer capacitors

Electrical double layer capacitors based on ideally polarizable nanoporous carbon electrodes in propylene carbonate with the addition of different 1 M Me₃EtNBF₄, Me₂Et₂NBF₄, MeEt₃NBF₄, Et₄NBF₄, Et₃PrNBF₄ and Et₃BuNBF₄ electrolytes have been tested by cyclic voltammetry, chronoamperometry and electrochemical impedance methods. The limits of ideal polarizability, low-frequency limiting capacitance and series resistance, time constant, Ragone plots (energy density vs. power density dependencies) and other characteristics have been discussed. The influence of the electrolyte molar mass on the electrochemical characteristics of the nanoporous carbon electrode cells has been established. The applicability limits of the Srinivasan and Weidner model have been tested.     

Electrodynamics of the vortex lattice in untwinned YBaCuO by complex impedance measurements

We report complex impedance measurements in an untwinned YBaCuO crystal. Our broad frequency range covers both the quasi static response and the resistive response of the vortex lattice. It allow us to characterize the irreversibility line without the need of any frequency dependent pinning parameters. We confirm the validity of the two modes model of vortex dynamic, and extract both the surface critical current and the flux flow resistivity around the first order transition T_m. This latter is identified by the abrupt loss of pinning and by an unexpected step of (T) at T_m. Received 22 November 2002 / Received in final form 17 February 2003 Published online 20 June 2003 RID="a" ID="a"e-mail: alain.pautrat@ismra.fr RID="b" ID="b"UMR 6508 associée au CNRS     

用传递矩阵法预测单层或多层微孔板的吸声性能

提出用实验测得含不同孔径孔的微孔板声阻抗率来预测由其形成的单层或多层微孔板的吸声特性，并用传递矩阵法来预测该微孔板的各种组合结构的整体吸声性能。采用该方法获得的微孔板吸声性能曲线与实测结果相当接近，能较好地预测各种组合微孔板的吸声性能。表明传递矩阵法是预测较复杂形式微孔板结构吸声性能的一种有效的方法。     

Rod-pinch 二极管理论及数值模拟

 介绍了Rod-pinch二极管的基本结构和工作原理，采用Laminar模型分析了Rod-pinch二极管中的粒子运动过程及其阻抗特性。考虑背景空间离子电荷的影响，用1维Laminar方程分析Rod-pinch二极管中电子的自箍缩过程，并且利用Magic程序对其中的粒子运动进行数值模拟，求解二极管中的电压和电流，最终得出二极管的阻抗特性，在较低电压下，负极性RPD的性能明显不如正极性RPD。根据临界电流经验公式，初步验证Laminar理论模型的可行性。     

1.2 MV大功率直流高压电源研制

 采用等边三角形结构的铁芯，次级线圈分成40级，分别进行三相全波整流，每级输出直流30 kV，串联后获得1.2 MV/A的直流高电压大功率输出。电源的能量转换效率大于95%，漏抗高达21.7%。采用无滤波电容结构，次级线圈星型/三角型接法交替使用，纹波系数小于±4%。整个电源密封在压力钢筒中，充0.8 MPa高纯度SF6气体作为绝缘介质，最大工作场强小于130 kV/cm。设计了专门的SF6气体冷却系统，气体温度控制在60 ℃以内，高电压由充气同轴传输线输出。在小负载条件下，电源各项指标满足技术要求，已经安装在1.2 MW，1.2 MeV大功率直流电子加速器上进行整机联调。