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71.
The structure of the title adduct comprises a phenanthroline derivative 2-phenyl-imidazo[4,5-f]1,10-phenanthroline and a methanol.The composition of the crystalline adduct was characterized as C19H12N4.CH3OH.It belongs to orthorhombic system,space group Pna21 with a=1.3693(4)nm,b=2.2988(7)nm,c=0.51338(15)nm,V=1.6160(8)nm^3.Z=4,and final R1=0.0423.wR2=0.1012 .Crystal structure shows that all the 19 carbon atoms and 4 nitrogen atoms are coplanar.The bond length data indicated that a very extensive conjugation system was formed.This conjugation makes the compound being a potentially excellent energy transformer used for luminescent materials. 相似文献
72.
By making use of a light gas gun, a specially designed target is impacted by the LY12 flyer, and the pressure is taken in the range of 0.6-3 GPa. Based on the stress profiles measured in the buffer materials by manganese gauges, the Hugoniot curve and release curves of LY12 aluminium alloy are obtained. Meanwhile, the release curves from different initial shocked states are described in both the pressure-particle velocity plane and the pressure-specific volume plane. 相似文献
73.
74.
结果表明,LixNi0.3Co0.7O2具有六方晶系R3^-m空间群结构。当X-1,0.315时,其晶胞参数分别为a=2.826nm,c=14.130nm和a=0.2808nm,c=1.4253nm;MO6(M=Ni,Co)八面体中M-O平均距离分别为0。1941nm和0.1933nm。XPS分析结果表明LIxNi0.3CO0.7O2表面存在Li2O,同时探讨了其中过渡金属离子的3d电子结构变化。 相似文献
75.
《中国物理快报》2003,20(10):1871-1874
76.
The current-voltage characteristics of Ti/n-GaAs Schottky diodes measured over a temperature range of 78-299K have been interpreted on the basis of thermionic emission across an inhomogeneous Schottky contact.The experiment shows that the apparent barrier height (φap) increases from 0.437eV at 78K to 0.698eV at room temperature.the plot of φap versus 1/T does not exhibit a simple linear relationship over the whole temperature range,indicating that the barrier height distribution is more complicated than the frequently observed single Gaussian distribution.A new multi-Gaussian distribution model is developed.Our experimental results can be explained by a double Gaussian distribution of the barrier heights.The weight,the mean barrier height,and the standard deviation of the two Gaussian functions are 0.00001 and 0.99999,0.721 and 0.696,0.069 and 0.012eV,respectively. 相似文献
77.
We show theoretically that it is possible to modify absorption of a bulk absorbing material by inserting another non-absorbing dielectric slab periodically to form one-dimensional photonic crystals.It is found that,for frequencies within photonic bandgaps,absorption is always suppressed.For frequencies located at photonic bands,absorption can be suppressed or enhanced,which depends on the relative values of the real refractive index of the absorbing and non-absorbing dielectric layers. 相似文献
78.
A europium complex Eu (DBM)3 TPPO (Eu tris(benzoylmethide)-(triphenylphosphine oxide)) and silicon nanoparticles have been hybridized.The hybridization can evidently change the photoluminescence (PL) characteristics of the Eu complex in the following aspects:under an excitation of 390nm,the intensity of the PL peak at 611nm due to the ^5Du-^7F2 transition of the Eu^3 ions has been increased by 30%,and thc integrated PL intensity in the visible range has been increased by nearly 3 times;the PL excitation efficiency beyond 440nm has been improved cvidently;the peak in the PL excitation spectrum shifts from 408nm to 388nm,and the PL decay time decreases from 2.07 to 0.96μs,The experimental results indicatde that in the PL process,the photoexcited energy may transfer from the silicon nanoparticlcs to the Eu^3 ions. 相似文献
79.
80.
The experimental conditions for photoactivated intermittent fluorescence from nanoscale silver oxide were studied with fluorescence microscopy.Strong fluorescence was observed from the Ag2O particles with size of 10-20nm excited with both blue and green light .We observed the saturation of Photoexcitation with blue light and explained the experimental results using the model of agglomeration of silver atoms to form small clusters and the fluorescence of Ag2 and Ag3 clusters. 相似文献