Janus 粒子在环境检测领域中的应用

Janus 粒子,也称为阴阳结构粒子或两面性非对称粒子,是指表面上具有两种或两种以上不同化学组成或性质的不对称粒子。目前,Janus 粒子因其独特的结构和功能已经逐渐成为生物医药、催化、材料以及防污等领域中的新型功能材料。在环境检测领域,Janus材料亦因其特殊的光学、磁学及电学性能,为提高检测灵敏度、选择性和稳定性等提供了新的研究方向。基于此,本文主要讨论了Janus材料在环境检测方面的特点、优势和相关应用。最后,本文基于本课题组的研究经验以及工作中所面临的问题,对本领域的发展和未来的研究方向提出了展望,以期对本领域的未来发展提供指导。     

激光等离子体中电子热流变化的数值模拟

利用二维相对论电磁粒子模拟程序研究了激光等离子体中电子热流在各向异性等离子体中的发展演化过程,提出了单位时间内等离子体临界表面上输运的能量与电子自由路程之间的函数关系,得到了用经典Spitzer-Harm理论来描述的电子热传导公式,探讨了经典电子热传导模型与被限制的自由热流随时间的变化情形。数值结果表明,强激光照射等离子体薄靶时的初始时刻电子热流迅速增大,但由于周边的自生磁场对电子的运动有限制作用,因此热流随时间缓慢地减少。对这些过程的研究对于电子热流的衰减和热输运等过程有重要意义。     

多孔有机盐单晶的合成及各向异性质子导电性能

以cis,cis-1,3,5-三氨基环己烷·3HBr和均苯四甲酸在室温下通过离子键构筑了具有规整形貌和大尺寸的晶态多孔有机盐CPOS-10, 其具有较好的热稳定性和永久多孔性. 得益于规整形貌及大尺寸单晶, 首次实现了对多孔有机盐单晶各向异性质子导电性能的研究, 并结合晶体结构探索了各向异性质子导电的机理. 结果表明, 水分子浓度对CPOS-10质子电导率的大小具有重要作用, 骨架内水分子浓度高的晶面更易于与极性基团构成氢键网络, 促进质子传导, 利用此网络的质子传导具有更高的质子电导率. 因此, 骨架内水分子的不均匀分布是导致单晶各向异性质子导电的主要原因. 对CPOS-10单晶各向异性质子导电性能的探索可为研究多孔有机盐的质子导电机理提供重要的依据.     

含各向异性左手材料的一维Thue-Mores准周期结构的反射带隙

采用传输矩阵法,研究了由各向同性右手材料和各向异性左手材料组成的Thue-Morse准周期结构的反射带隙,分析了入射角、偏振和晶格比例缩放因子对反射带隙的影响.结果表明该结构存在一个全方向反射带隙,该带隙的宽度由TE模的低频带边缘和TM模的高频带边缘决定.当在该结构中插入一层缺陷时,在全方向带隙中出现一条缺陷模.对TE模,缺陷模的位置受入射角的影响很弱,而对TM模,缺陷模的位置随入射角的增大,向高频方向移动.     

CO2-水-页岩相互作用的研究现状及展望

简要综述了CO2、水和页岩间矿物的相互作用,分析了CO2注入到地下进入页岩层后,地下含水层pH值的变化,并根据页岩层的矿物学组成分为黏土矿物和脆性矿物,较为详细地描述了CO2与黏土矿物和脆性矿物之间发生的地球化学反应,概述了此反应对页岩层孔隙度和渗透率的影响。同时,也讨论了CO2增强页岩气开采的现实问题及发展趋势,为今后的研究提供了参考。     

Rayleigh Scattering for An Electromagnetic Anisotropic Medium Sphere

Based on the scales theory of electromagnetic waves, the analytical expression of electrical fields inside an anisotropic medium sphere is studied. Differential scattering cross section and radar cross section （RCS） for an anisotropic spherical target are presented. The correctness of the obtained results is tested. The simulation results show that the scattering of an anisotropic sphere has the property of a dipole radiation under the condition of Rayleigh scattering. The larger the dielectric constant is, the stronger the dipole scattering is. Anisotropy in magnetism only has an effect on differential RCS. These results provide a theoretical base for the identification of anisotropic targets.     

Thermal Entanglement of an XY Two-Qutrit Spin Chain with Dzialoshinski-Moriya Interaction

The effect of Dzialoshinski-Moriya （DM） interaction on thermal entanglement of an XY two-qutrit spin chain is investigated. We find that DM interaction and the anisotropy parameter can enhance quantum thermal entanglement to a maximal value individually. However, when both of them take large values, the entanglement is not enhanced, but is destroyed. Our analysis will shed some light on the understanding of the effect of the DM interaction on thermal entanglement of an XY two-qutrit spin chain.     

Application of Equivalent Air Gap Method in Uniaxial Crystal Plate

The equivalent air gap method is a simple way to trace the ray propagation in an isotropic medium, but it cannot be applied to an anisotropic medium. We present the exact general expressions of the equivalent air gap thicknesses and the displacements for the plane-parallel uniaxial crystal plates. They are also suitable for the isotropie medium. This method is useful when one determines whether certain size plane-parallel plates can be fitted into the available air of an optical system, and also in the prism system design.     

Photonic band gap from periodic structures containing anisotropic nonmagnetic left-handed metamaterial

<正>We demonstrate a photonic band gap(PBG) from one-dimensional(1D) periodic structures created by a double-layer unit cell with an air layer and an anisotropic nonmagnetic left-handed metamaterial(LHM) layer whose permittivity elements are partially negative.The requirements imposed on the materials and structures to realize a PBG are derived when the frequency is above or below the cutoff frequency,and the transmission properties of the PBG are discussed by utilizing 4×4 transfer-matrix method with dispersive semiconductor metamaterial.