腰椎间盘纤维环膨隆症站立位动态脊髓造影的临床意义

目的:在MRI或CT检查的腰腿痛病人中,通过站立位动态脊髓造影,了解椎间盘纤维环在腰椎中立、过屈、过伸三位置下的变化,并探讨其临床意义,筛选出具有手术指征的LDH病人,决定手术方式.方法:对86例LDH患者,行站立或平卧中立、过屈、过伸脊髓造影,对比分析两组动态变化.鉴别出LDB,选择性行有限椎板减压,或保留其椎间盘.结果:脊髓造影侧位像“拿破仑帽”状影,站立三位置均明显大于平卧位,差异非常显著(P＜0.01),在动态变化中平卧位者改成由中至屈曲位时,硬膜囊受压影较站立位者明显缩小,差异非常显著(P＜0.01),站立由中至伸时,压迫影较平卧位增大,差异显著(P＜0.05).其中28例,行有限椎板切除或保留其椎间盘,效果优良.结论:站立位会使LDB加重、临床症状加重,因站立过伸位使腰椎管狭窄病人症状加重.而平卧位造影时因重力负荷减轻,(拿破仑帽)影像不明显或消失,而出现假阴性.     

基于经验模式分解的拖曳式声纳拖船噪声抵消研究

拖曳式线列阵声纳的拖船噪声具有多途角扩展等特点，并且是一个非平稳过程，使得对该噪声的消除或抑制是一大难点。经验模式分解是一种用于分析非线性非平稳信号的新方法，该方法自适应地将嵌于数据内部的多个固有模式函数逐一分解开来。本文尝试利用经验模式分解方法分离出水听器接收信号中的拖船干扰噪声，从而达到消除干扰的目的。海上试验数据的处理结果充分验证了这种方法的可行性。     

外光注入半导体激光器实现时钟分频

从理论和实验上研究了利用光注入半导体激光器对高重复速率光脉冲产生的周期振荡和时钟分频现象.结果表明，光注入半导体激光器引起的二倍周期振荡是使注入脉冲重复频率分频的直接原因.通过耦合速率方程，数值模拟了半导体激光器在外光注入时输出光的时间序列和功率谱，并且分析了激光腔内各种周期振荡的特征.研究表明，当注入光使半导体激光器出现稳定的二倍周期振荡，且注入光的重复频率为此振荡频率的二倍时，时钟分频即可产生实验中，采用重复频率为6.32GHz的光脉冲注入Fabry-Perot激光器，实现了3.16GHz时钟分频信号 关键词： 周期振荡 时钟分频 光谱侧带 光注入     

2×n阶网络侧端等效电阻的另一种公式

再次研究了2×n阶梯形网络的侧端等效电阻,通过网络分析构建差分方程模型,给出了2×n阶梯形网络侧端等效电阻的另外一个普适规律,并通过具体的特例进行了比较与验证.     

侧链基团对聚合物薄膜瞬态发光性能的影响

采用飞秒激光光谱技术比较研究了两种卟啉侧链聚合物:卟啉丙烯酸酯-苯乙烯共聚物P[(por)A-S]和卟啉铁(Ⅲ)丙烯酸酯-苯乙烯共聚物P[(por)FeA-S]的瞬态发光性能。并采用纳秒激光光谱技术测量了小分子卟啉(TPP)的荧光动力学过程。结果表明:P[(por)FeA-S]具有比P[(por)A-S]快得多的荧光弛豫过程,而P[(por)A-S]的荧光寿命远小于小分子卟啉的荧光寿命。对上述过程进行了分析,P[(por)A-S]的荧光衰变主要来源于聚合物分子链间的相互作用;而P[(por)FeA-S]的荧光衰变除了来源于聚合物分子链间的相互作用外,中央金属离子与配位体之间的电荷转移也对卟啉发色基团的激发态超快无辐射弛豫具有重要的影响,对上述过程的产生机理进行了讨论。     

关于电阻率测井中视电阻率概念的合理性

对视电阻率这一电阻率测井中常用的概念进行深入分析,通过理论上的考虑及有关数值算例,探讨视电阻率应该具有的性质及相应概念的合理性.     

Synthesis and mesomorphic properties of novel tolane-type liquid crystals

Two series of novel tolane-type liquid crystals(LCs) comprising of hydrogen-bonded organic acids were synthesized.The formation of dimerized H-bond LCs was confirmed by IR spectroscopy,and mesomorphic properties of the LCs were investigated by differential scanning calorimetry(DSC) and polarizing optical microscopy(POM).It was found that the end groups of the liquid crystals as well as the unsaturated rigid core had effect on the mesomorphic properties.     

Two novel fluorescent calix[4]arene derivatives with benzoazole units in 1,3-alternate conformation for selective recognition to Fe~(3+) and Cr~(3+)

Two novel fluorescent calix[4]arene derivatives 1a and 1b with benzoxazole or benzothiazole units in 1,3-alternate conformation have been synthesized and characterized by IR,~1H NMR,~(13)C NMR and MS.Their complexation properties to different heavy and transition metal ions have been studied by UV-vis spectroscopy and fluorescence spectrometer.Compounds 1a and 1b show selective recognition to Fe~(3+) and Cr~(3+).     

Homogeneous modification of carbon nanotubes with cellulose acetate

An efficient strategy that comprised shorten,chain extension,active groups introducing and homogeneous reaction tactics,was adopted to modify multiwalled carbon nanotubes(MWNTs) with cellulose acetate(CA).Specially,by utilizing 2,4,6-trichloro- 1,3,5-triazine,a reactive intermediate of the MWNTs(MWNT-triazine) was obtained.Suitable solubility of the MWNT-triazine helps make the homogeneous modification become reality.Detailed characterizations further verified that reaction between chloride atoms in the ...     

Synthesis of new chiral 1,2,3,4-tertrahydroisoquinoline β-amino alcohol for asymmetric diethylzinc addition to aryl aldehydes(Ⅰ)

Four new chiral 1,2,3,4-tetrahydroisoquinoline-derived β-amino alcohols were synthesized from commercially available L-DOPA. These ligands were evaluated in the asymmetric addition of diethylzinc to benzaldehydes and showed different catalytic activities(up to 86%ee).The solvent played an important role in the enantioselective process.The transition state models were proposed to explain the reversion of the product configuration.