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91.
一类新的多功能构筑基块-多吡唑化合物的设计合成 总被引:3,自引:0,他引:3
The design and synthesis of novel polypyrazolyl aromatic bridging ligands 1,3,5-tris(3,5-dimethyl-1-pyrazol-4-yl)benzene and 2,4,6-tris(4-(3,5-dimethyl-^1H-pyrazol-4-yl)phenyl)-1,3,5-triazine from simple starting materials mesitylene and p-tolunitrile were reported. 相似文献
92.
A New Efficient Synthesis of p-Nitrocalix[4]arene 总被引:1,自引:0,他引:1
YongLI JiaSongWANG QiWANG DeShanLI 《中国化学快报》2004,15(4):400-403
A new efficient synthesis of p-nitrocalix[4]arene from calix[4]arene by using nitrogen dioxide is described.The compound is an useful intermediates for the introduction of other functional groups to obtain N containing substituted calix[4]arene.The reaction mechanism is briefly discussed. 相似文献
93.
Shi-jun Zheng Kazuo Akagi Qun Xu Shao-kui Cao Qi-feng Zhou 《高分子科学》2006,(4):353-361
Novel shish-kebab type liquid crystalline poly(p-phenylenevinylene) derivatives were synthesized by Stille coupling reaction from 2,5-bis[(4-n-alkoxyl)benzoyloxy]1,4-dibromobenzene (monomer l) and 1,2-bis(tributylstannyl) ethylene (monomer 2). The polymers with alkoxy groups are soluble in common organic solvents and exhibit blue fluorescence. Both the cast film and the annealed film have large red-shifts in fluorescence spectra and show yellow fluorescence. The polymers with CN and NO2 groups show poor solubility and green fluorescence. All the polymers possess liquid crystalline smectic phases. The melting point (Tm) of the polymers decreases when the length of the alkoxy tails of the mesogenic units increases. The polymers are easily aligned under a magnetic field of 10 Tesla. It is found that the conjugated backbone and LC side chain are aligned perpendicular and parallel to the magnetic field, respectively. The polymers show optical dichroism in fluorescence spectra, suggesting that they are available for advance materials with linear optical polarization. 相似文献
94.
A vinyl monomer having an electron-donating moiety, p-(N,N-dimethylamino)styrenc (DMAS),was synthesized. It was combined with benzoyl peroxide (BPO) to form a redox initiation system to initiatethe polymerization of methyl methacrylate (MMA). UV spectra measurements show that DMAS enters thePMMA chain as well. Both DMAS and its polymer P(DMAS) display strong fluorescence, and thefluorescence can be quenched by electron-deficient compounds such as methacrylonitrile, fumaronitrile andmethyl methacrylate etc. Moreover, DMAS can also form charge transfer complex (CTC) with strongelectron acceptors such as tetracyanoethylene (TCNE). The difference between the photochemical propertiesof DMAS and P(DMAS) were explained in terms of molecular structure change and polymer conformationeffect in solution. In addition, the CTC and exciplex formation of DMAS or P(DMAS) with C_(60) were alsostudied. 相似文献
95.
JianGouHUANG ManCaiXU HaiTaoLI ZuoQingSHI 《中国化学快报》2003,14(9):914-916
Two polymeric adsorbents, poly(methyl p-vinylbenzvl ether) and oolv(ohenvl p-vinylbenzyl ether), were synthesized from chloromethylated polystyrene, Their adsorptionproperty for phenol in hexane solution was investigated. The results showed that the twoadsorbents adsorb phenol from hexane solution through hydrogen-bonding and π-π stacking interaction. 相似文献
96.
本文研究了集值映射的(C,ε)-超次微分.首先,引进了集合的(C,ε)-超有效点,呈现了(C,ε)-超有效点的一些性质和等价刻画,在(C,ε)-超有效性意义下,获得了集值优化问题的标量化定理.其次,定义了集值映射的(C,ε)-超次微分,研究了(C,ε)-超次微分的存在条件,建立了用(C,ε)-超次微分刻画的Moreau-Rockafellar定理.最后,作为应用,建立了涉及(C,ε)-超次微分的集值优化问题的最优性条件.本文获得的结果统一和推广了一些文献中用超次微分或ε-超次微分刻画的结果. 相似文献
97.
作为对半连续函数的推广,Yamazaki在[Topology Appl.,2017,231:386-399]中引入半连续偏序集值映射的概念.本文证明多数广义度量空间和度量空间均可用偏序集值映射来刻画,所得结果推广了[Topol ogyAppl.,2018,238:76-89]中的某些相应结论. 相似文献
98.
CHAOS FOR MIXING TRANSFORMATIONS 总被引:3,自引:0,他引:3
Liao Gongfu 《数学年刊B辑(英文版)》1994,15(4):501-506
CHAOSFORMIXINGTRANSFORMATIONS¥LIAOGONGFU(DepartmentofMathematics,JilinUniversity,Changchun130023,China.)Abstract:Foraclassofm... 相似文献
99.
As a continuation of part I of the paper under the same title, we developgeneral monotonic enclosure methods for the couple systems of the splitting equations {x=G([x]a,[x]b,[y]c) y=G([y]a,[y]b,[x]c),which models the system of equations associated with hybrid and aaynchronotts monotonicity as well as convexity. The resulting algorithms and convergence theorems generalize and unify various known methods and monotonic enclosure theorents established by other authors. 相似文献
100.
XILIFENG 《高校应用数学学报(英文版)》1996,11(2):209-216
Abstract. In this paper, for any continuous function 相似文献