Quantum Mutual Entropy for a Multilevel Atom Interacting with a Cavity Field

We derive an explicit formula for the quantum mutual entropy as a measure of the total correlations in a multi-level atom interacting with a cavity field. We describe its theoretical basis and discuss its practical relevance. The effect of the number of levels involved on the quantum mutual entropy is demonstrated via examples of three-, four- and five-level atom. Numerical calculations under current experimental conditions are performed and it is found that the number of levels present changes the general features of the correlations dramatically. PACS numbers: 32.80.−t, 42.50.Ct, 03.65.Ud, 03.65.Yz.     

Determination of Diffusion Coefficients for Binary Nonelectrolyte Mixtures. A Free-Volume Predictive Approach

A diaphragm cell has been used to measure mutual diffusion coefficients at 25°C for four binary nonelectrolyte mixtures: ethylbenzene + n-hexane, carbon tetrachloride + ethylbenzene, cyclohexane + p-xylene, and 1,2-dichloroethane + cyclohexane. A free-volume predictive approach for binary mutual diffusion coefficients was developed and tested. Only infinite dilution diffusion coefficients, some readily available pure substance data, and UNIFAC group contribution parameters are used in the model. No binary equilibrium thermodynamic information is required. For 73 binary systems with an overall average absolute deviation of 5.2%, it has been shown that the developed method is better than two commonly available reference methods for the prediction of liquid diffusion coefficients.     

药物相互作用及其临床意义

介绍了药物相互作用的概况和药物在药物动力学方面、药效学及在体外相互作用的一些临床表现.特别是因药物相互作用而引起的药物不良反应问题应引起注意。     

Dipole moments of some substituted benzaldehydes. Conformational preference of substituents ortho to the aldehyde group

The dipole moments of a number of substituted benzaldehydes are measured in benzene solution. The angle which the dipole axis of the CHO group makes with the axis of rotation of the group is determined. The observed moments of the ortho-substituted benzaldehydes are compared with the moments calculated for free rotation as well as fors-trans ands-cis orientations of the -CHO group.o-Fluorobenzaldehyde exists mostly in thes-trans conformation.o-Chloro-,o-bromo-ando-nitro-benzaldehydcs also exist in thes-trans conformation; their observed dipole moments are even lower than the values calculated fors-trans forms, indicating mutual induction of the ortho substituents. Though 2,5-dichlorobenzaldehyde is expected to have the same dipole moment as benzaldehyde, the observed moment is significantly lower due to mutual induction of the ortho substituents. 2,5-Dimethylbcnzaldehyde has, however, almost the same moment as benzaldehyde. The dipole moment ofo-methoxybcnzaldchyde is considerably higher than the values calculated for boths-cis ands-trans conformations. An explanation is given for this.o-Hydroxybenzaldehyde exists exclusively in thes-cis form due to internal H-bonding.     

Statistical inference and modelling of momentum in stock prices

The following results are obtained, (i) It is possible to obtain a time series of market data {y(t)} in which the fluctuations in fundamental value have been compensated for. An objective test of the efficient market hypothesis (EMH), which would predict random correlations about a constant value, is thereby possible, (ii) A time series procedure can be used to determine the extent to which the differences in the data and the moving averages are significant. This provides a model of the form y(t)-y(t-l)=0.5{y(t- l)-y(t-2)}+ε(t)+0.8ε(r-1) where ε(t) is the error at time t, and the coefficients 0.5 and 0.8 are determined from the data. One concludes that today's price is not a random perturbation from yesterday's; rather, yesterday's rate of change is a significant predictor of today's rate of change. This confirms the concept of momentum that is crucial to market participants. (iii) The model provides out-of-sample predictions that can be tested statistically. (iv) The model and coefficients obtained in this way can be used to make predictions on laboratory experiments to establish an objective and quantitative link between the experiments and the market data. These methods circumvent the central difficulty in testing market data, namely, that changes in fundamentals obscure intrinsic trends and autocorrelations. This procedure is implemented by considering the ratio of two similar funds (Germany and Future Germany) with the same manager and performing a set of statistical tests that have excluded fluctuations in fundamental factors. For the entire data of the first 1149 days beginning with the introduction of the latter fund, a standard runs test indicates that the data is 29 standard deviations away from that which would be expected under a hypothesis of random fluctuations about the fundamental value. This and other tests provide strong evidence against the efficient market hypothesis and in favour of autocorrelations in the data. An ARIMA time series finds strong evidence (9.6 and 21.6 standard deviations in the two coefficients) that the data is described by a model that involves the first difference, indicating that momentum is the significant factor. The first quarter's data is used to make out-of-sample predictions for the second quarter with results that are significant to 3 standard deviations. Finally, the ARIMA model and coefficients are used to make predictions on laboratory experiments of Porter and Smith in which the intrinsic value is clear. The model's forecasts are decidedly more accurate than that of the null hypothesis of random fluctuations about the fundamental value.     

Review on the thickness measurement of ultrathin oxide films by mutual calibration method

Mutual calibration was suggested as a method to determine the absolute thickness of ultrathin oxide films. It was motivated from the large offset values in the reported thicknesses in the Consultative Committee for Amount of Substance (CCQM) pilot study P-38 for the thickness measurement of SiO₂ films on Si(100) and Si(111) substrates in 2004. Large offset values from 0.5 to 1.0 nm were reported in the thicknesses by ellipsometry, X-ray reflectometry (XRR), medium-energy ion scattering spectrometry (MEIS), Rutherford backscattering spectroscopy (RBS), nuclear reaction analysis (NRA), and transmission electron microscopy (TEM). However, the offset value for the thicknesses by X-ray photoelectron spectroscopy (XPS) was close to zero (−0.013 nm). From these results, the mutual calibration method was reported for the thickness measurement of SiO₂ films on Si(100) by combination of TEM and XPS. The mutual calibration method has been applied for the thickness measurements of hetero oxide films such as Al₂O₃ and HfO₂. Recently, the effect of surface contamination was reported to be critical to the thickness measurement of HfO₂ films by XPS. On the other hand, MEIS was proved to be a powerful zero offset method which is not affected by the surface contamination. As a result, the reference thicknesses in the CCQM pilot study P-190 for the thickness measurement of HfO₂ films on Si(100) substrate were determined by mutual calibration method from the average XRR data and MEIS analysis. Conclusively, the thicknesses of ultrathin oxide films can be traceably certified by mutual calibration method and most thickness measurement methods can be calibrated from the certified thicknesses.     

Two-frequency mutual coherence function and its applications to pulse scattering by random rough surface

An analytic expression of the two-frequency mutual coherence function (MCF) was derived for a two-dimensional random rough surface. The scattered field was calculated by the Kirchhoff approximation, which is valid in the case that the radius of curvature of the surface is much larger than the incident wave length. The scattering problem of narrowband pulse was investigated to simplify the analytic expression of the two-frequency MCF. Numerical simulations show that the two-frequency MCF is greatly dependent on the root-mean-square (RMS) height, while less dependent on the correlation length. The analytic solutions were compared with the results of Monte Carlo simulation to assess the accuracy and computational efficiency. Supported by the National Natural Science Foundation of China (Grant No. 60571058) and the National Defense Foundation of China (Grant No. 51403020505DZ0111)     

非线性时间序列互信息与Lempel-Ziv复杂度的相关性研究

为探究非线性动力学系统的互信息和复杂度的相关性，用Logistic映射、Lorenz模型和心电RR间期的非线性时间序列作为实验数据，计算多分段延时互信息和多分段Lempel-Ziv复杂度以及它们之间的相关系数.结果表明这些序列的互信息和复杂度呈强负相关，对Logistic方程生成的201个序列的不同段互信息和不同段复杂度之间的相关系数绝对值都大于0.9162，最大达0.9923；对94个心电RR间期序列都大于0.8555，最大达0.9860.研究还发现互信息比复杂度能更敏感地表现出非线性动力系统的特征. 关键词： 相关系数 互信息 Lempel-Ziv 复杂度 心电RR间期     

开放式基金流动性指标研究

本文主要介绍了开放式投资基金的流动性概念和指标体系设计，并运用指标进行实证检验，分析基金的流动性及其实际意义。