A strategy for a national metrology institute to create a cost effective distributed metrology infrastructure for chemical measurements

A sound strategy for a national metrology institute (NMI) is proposed, describing how to set up an metrology infrastructure for chemical measurements. A national measurement infrastructure is defined as a collection of various measurement services (testing, calibration and reference laboratories) and the communication between these services. For clarity, in this paper the distributed metrology infrastructure covers those organisations that are involved in disseminating measurement traceability (i.e. the national metrology institute and the reference laboratories acting as national reference standard holders).The strategy aims at a proper support of sectoral field laboratories. It is based on a distributed metrology system. Such a system is composed of clearly identified national reference standard holders for particular measurement services (e.g. for a particular analyte in a particular matrix) co-ordinated via an NMI. Such national reference standard holders, appointed by the NMI, represent the best measurement capability inside the country, and their appointment is based on demonstrated measurement competence. They receive support (e.g. under contract) from the NMI to fulfil this role. They have the obligation to demonstrate their measurement capabilities on a regular basis and in a publicly open and transparent way.In particular and carefully selected cases, the NMI itself can and should act as national reference standard holder. The NMI should particularly devote a large part of its resources to cross-sectoral knowledge transfer, to advice and co-ordination. This can be achieved by participating in teaching/training, by supporting the accreditation, by being involved in advising governmental bodies in authorisation of laboratories and by assisting in the implementation of legislation.As a consequence, only when values produced at the NMI (or one of its designated national reference standard holders) are disseminated to field laboratories (e.g. for CRMs or as a calibration service) will it be necessary to have the NMI measurement capability recognised under the CIPM-MRA system.Such a distributed system requires an efficient communication tool between the three stakeholders concerned: the NMI, the national reference standard holder and the end users. The latter not only include the field laboratories, but also governmental bodies and the national accreditation body.Presented at the XVIIIth IMEKO Congress in Dubrovnik-Cavtat, June 22–27, 2003Further contributors to this paper: M. Buzoianu (National Institute of Metrology, Bucharest), W.Kozlowski (Central Office of Measures, Warsaw), P. Klenovsky, Frantisek Jelinek (CMI, Prague), C. Michael (State General Laboratory, Nicosia), Zsofia Nagyné Szilágyi, (National Office of Measures, Budapest), V. Patoprsty (Slovak Institute of Metrology, Bratislava), A. Todorova (SAMTS Sofia)     

Calibration of ultrasonic hydrophone probes up to 100 MHz using time gating frequency analysis and finite amplitude waves

A number of ultrasound imaging systems employs harmonic imaging to optimize the trade off between resolution and penetration depth and center frequencies as high as 15 MHz are now used in clinical practice. However, currently available measurement tools are not fully adequate to characterize the acoustic output of such nonlinear systems primarily due to the limited knowledge of the frequency responses beyond 20 MHz of the available piezoelectric hydrophone probes. In addition, ultrasound hydrophone probes need to be calibrated to eight times the center frequency of the imaging transducer. Time delay spectrometry (TDS) is capable of providing transduction factor of the probes beyond 20 MHz, however its use is in practice limited to 40 MHz. This paper describes a novel approach termed time gating frequency analysis (TGFA) that provides the transduction factor of the hydrophone probes in the frequency domain and significantly extends the quasi-continuous calibration of the probes up to 60 MHz. The verification of the TGFA data was performed using TDS calibration technique (up to 40 MHz) and a nonlinear calibration method (up to 100 MHz). The nonlinear technique was based on a novel wave propagation model capable of predicting the true pressure-time waveforms at virtually any point in the field. The spatial averaging effects introduced by the finite aperture hydrophones were also accounted for. TGFA calibration results were obtained for different PVDF probes, including needle and membrane designs with nominal diameters from 50 to 500 micro m. The results were compared with discrete calibration data obtained from an independent national laboratory and the overall uncertainty was determined to be +/-1.5 dB in the frequency range 40-60 MHz and less than +/-1 dB below 40 MHz.     

From Rényi Entropy Power to Information Scan of Quantum States

In this paper, we generalize the notion of Shannon’s entropy power to the Rényi-entropy setting. With this, we propose generalizations of the de Bruijn identity, isoperimetric inequality, or Stam inequality. This framework not only allows for finding new estimation inequalities, but it also provides a convenient technical framework for the derivation of a one-parameter family of Rényi-entropy-power-based quantum-mechanical uncertainty relations. To illustrate the usefulness of the Rényi entropy power obtained, we show how the information probability distribution associated with a quantum state can be reconstructed in a process that is akin to quantum-state tomography. We illustrate the inner workings of this with the so-called “cat states”, which are of fundamental interest and practical use in schemes such as quantum metrology. Salient issues, including the extension of the notion of entropy power to Tsallis entropy and ensuing implications in estimation theory, are also briefly discussed.     

肽的检测方法及化妆品中肽检测的计量需求

肽因具有良好的生物活性而在化妆品中得到越来越广泛的应用。介绍了化妆品中肽的类型及其作用,肽对改善皱纹、抗衰老和美白祛斑等方面有明显功效。当前社会对化妆品中肽的检测方法及计量学研究存在迫切需求,综述了目前检测肽常见的方法:凯氏定氮法、荧光检测技术、化学发光检测法、电泳法、比色法、酶联免疫吸附剂测定法、色谱法等。     

Super-sensitivity measurement of tiny Doppler frequency shifts based on parametric amplification and squeezed vacuum state

The precision measurement of Doppler frequency shifts is of great significance for improving the precision of speed measurement. This paper proposes a precision measurement scheme of tiny Doppler shifts by a parametric amplification process and squeezed vacuum state. This scheme takes a parametric amplification process and squeezed vacuum state into a detection system, so that the measurement precision of tiny Doppler shifts can exceed the Cram′er–Rao bound of coherent light. Simultaneously, a simulation study is carried out on the theoretical basis, and the following results are obtained: for the signal light of Gaussian mode, when the amplification factor g = 1 and the squeezed factor r = 0.5, the measurement error of Doppler frequency shifts is 14.4% of the Cramer–Rao bound of the coherent light in our system. At the same time,when the local light mode and squeezed vacuum state mode are optimized, the measurement precision of this scheme can be further improved by ■ times, where n is the mode-order of the signal light.     

The dynamical optimal acquisition of automation

The acquisition of automation occurs in response to a variety of organizational goals. It follows that different mathematical models are required to capture an organization's specific incentives. In addition, formulations must differ to reflect the characteristics of the automation being considered. Here, a survey of three models developed by the author is presented that considers the optimal dynamic mix of labor and automation. These models differ with respect to (i) the organizational motivations identified for acquiring the automation, (ii) the purpose and use of the automation under consideration, and (iii) the manner in which the automation is acquired over time.     

Refractive index matched liquid crystal cell for laser metrology application

There exists a problem in advanced numerically controlled automatic laser metrology. Reported study is related to minimising the system generating three or more coherent laser measuring beams. These rays, generated in a proper rangefinder, are necessary to determine the spatial coordinates and spatial orientation of the measured details. The simplest solution is to generate laser coherent light beams of wavelength λ = 0.6328 µm with a given light polarisation plane and then to direct them along three or more independent optical paths. To form these optical paths, a special refractive index matched liquid crystal cell (MLCC) might be applied. To ensure a stable laser operation during the measurement process, the back reflection of the laser beam from MLCC should not exceed 0.7%. The main task of this work is developing such a MLCC transducer. To reach the critical back reflection low enough, the MLCC is constructed as multilayer structure. MLCC operates in positive twisted nematic (TN) mode. Owing to the high-birefringence nematic liquid crystal mixture used and rather big cell gap, the elaborated low reflective MLCC (with R < 0.7%) works at TN mode above the sixth interference maximum of transmitting linearly polarised light.     

The 14th Australian Symposium on Analytical Chemistry. Adelaide, 5–9 July 1997

 The Analytical Division of the Royal Australian Chemical Institute (RACI) held its 14th biennial symposium on analytical chemistry (14AC) in Adelaide, South Australia on 5–9 July 1997 [1]. The theme, "A broader view of the world" was an explicit invitation from the organisers to analysts to "take time away from their laboratories and consider how their work affects the world . . . A major challenge to chemists is to redefine their role in industry, education and the community and face, head-on, the demands brought about by free trade, economic rationalism and the environment." Part of this challenge, as reflected in invited plenary and keynote speakers as well as the cut and thrust of debate on the conference floor, is to address the important role of chemical measurement and confidence in the domestic and international systems of measurement.     

基于径向基函数模型的工程工料消耗的估算方法

将径向基函数网络方法应用于工程工料消耗估算 ,讨论了网络结构的设计、学习算法等问题 ;建立了基于径向基函数网络的工程工料消耗估算模型 ,计算实例表明 ,借助该模型可实现工程工料消耗的快速估算 .     

前置放大器在高频信号检测系统中的作用

利用约瑟夫森效应获取电磁信号的频谱信息是超导电子学的重要应用之一.我们在实验室已搭建的高频信号频谱检测系统基础上,研究了前置放大器的噪声参数对整个高频信号检测系统性能产生的影响.通过实验,我们将两个不同输入电压噪声密度的低噪声放大器应用于检测系统,并对所得的结果进行了比较.讨论了在前置放大器方面对基于约瑟夫森效应的液氮温区的小型高频信号检测系统进行改进的可能性.