Study on thermal degradation mechanisms of comb polyacrylates containing long fluorocarbon side chains by TG/FTIR

Thermal degradation of two series of polyacrylates containing long fluorocarbon chains [abbr.: PF_nA {HCF₂(CF₂)_n−1  CH₂ O C(O) , n = 4, 6, 8, 10} and abbr.: PFF_nEA {CF₃(CF₂)_n−1  CH₂CH₂ O C(O) , n = 6, 8, 10}] was investigated by TG /FTIR. Thermal degradation behavior of polymers changed depending on the type of tie groups, which link the fluorocarbon chains to the main chain, and also on the length of fluorocarbon chains. It was clarified that the apparent activation energies (ΔE_a ) of PF_nA series obtained by Ozawa's method varied in the order of PF₄A > PF₆A > PF₈A > PF₁₀A, while those of PFF_nEA series having tie group of  CH₂ CH₂ O C(O) were almost constant. The results for PF_nA series (tie group:  CH₂ O C(O) ) are attributable to the shield effect of long fluorocarbon chains on the back‐biting reaction in the thermal degradation of comb polymers rather than the change of C C bond dissociation energy in the main chain. It was found that TG curves of PFF_nEA series were shifted to the lower temperature region than those of PF_nA. This result can be attributable to the scission of side groups followed by the evaporation of fluorocarbon compounds and carbon dioxide. © 2000 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 38: 2794–2803, 2000     

Polymers of carbonic acid. XXVII. Macrocyclic polymerization of trimethylene carbonate

2,2-Dibutyl-2-stanna-1,3-dioxepane (DSDOP) was used as cyclic initiator for the polymerization of trimethylene carbonate (TMC). The polymerizations were either conducted in concentrated chlorobenzene solution at 50 and 80°C or in bulk at 60 and 120°C. With monomer/initiator ratios ≤100 the conversion was complete within 2 h at 80°C and within 12 h at 50°C. Variation of the reaction time revealed that the rapid polymerization is followed by a relatively rapid (backbiting) degradation even at 80°C. The polymerizations in bulk at 60°C were somewhat slower than those at 80°C in solution, but the influence of degradation reactions was less pronounced. With optimized reaction time the number average molecular weight (M_n) roughly parallels the monomer/initiator ratio and M_n's up to 100,000 were obtained. In contrast to a classical living polymerization broader polydispersities (1.5–1.7) were found. In the case of 5,5-dimethyltrimethylene carbonate rapid degradation and chain transfer reactions prevented the formation of high molecular weight polymers. © 1999 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 37: 2179–2189, 1999     

北京谱仪Ⅲ中触发数据并串结合传送方法的研究

 北京谱仪中各探测器电子学系统向触发系统传输大量并行信号,需要采用并串结合型光纤传输方法,以达到断开地回路,提高系统及线路抗干扰能力,延长传输距离的目的。对此种传输方法的误码率、报错与恢复、延时一致性和相位稳定性等关键问题进行了深入研究,得到确切参数,并提出了单路出错自恢复同步的解决方法,增强了系统的耐用性。同时发现各线路间传输延迟有半个周期的不一致,因此在接收端应把采样时钟上升沿调整在所有解出数据都稳定的时刻。此方法可满足北京谱仪工程的实际需要。     

代数重建技术在板壳结构断层重建中的应用

针对板壳结构用锥束射线倾斜扫描时数据缺失等问题,利用代数重建技术(ART)进行了断层重建。计算机模拟结果表明,由ART重建出的切片图像质量远好于先前用滤波反投影(FBP)重建出的切片图像质量。对影响ART算法的各种因素进行了调整,即选取适当的初始图像和收敛因子就可获得最佳的图像质量。