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91.
Rodrigo París José Luis de la Fuente 《Journal of polymer science. Part A, Polymer chemistry》2007,45(16):3538-3549
Different diblock copolymers constituted by one segment of a monomer supporting a reactive functional group, like allyl methacrylate (AMA), were synthesized by atom transfer radical polymerization (ATRP). Bromo‐terminated polymers, like polystyrene (PS), poly(methyl methacrylate) (PMMA), and poly(butyl acrylate) (PBA) were employed as macroinitiators to form the other blocks. Copolymerizations were carried out using copper chloride with N,N,N′,N″,N″‐pentamethyldiethylenetriamine (PMDETA) as the catalyst system in benzonitrile solution at 70 °C. At the early stage, the ATRP copolymerizations yielded well‐defined linear block copolymers. However, with the polymerization progress a change in the macromolecular architecture takes place due to the secondary reactions caused by the allylic groups, passing to a branched and/or star‐shaped structure until finally yielding gel at monomer conversion around 40% or higher. The block copolymers were characterized by means of size exclusion chromatography (SEC), 1H NMR spectroscopy, and differential scanning calorimetry (DSC). In addition, one of these copolymers, specifically P(BA‐b‐AMA), was satisfactorily modified through osmylation reaction to obtain the subsequent amphiphilic diblock copolymer of P(BA‐b‐DHPMA), where DHPMA is 2,3‐dihydroxypropyl methacrylate; demonstrating the feasibility of side‐chain modification of the functional obtained copolymers. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3538–3549, 2007 相似文献
92.
Bart M. J. M. Suijkerbuijk Duncan M. Tooke Anthony L. Spek Gerard van Koten Robertus J. M. Klein Gebbink Prof. Dr. 《无机化学与普通化学杂志》2007,633(15):2649-2653
A tin(IV) porphyrin was combined with two axial NCN‐pincer platinum(II) fragments by utilizing the oxophilicity of the apical positions on the tin atom and the acidic nature of the NCN‐pincer platinum derived benzoic acid. The solid‐state structure determined by X‐ray crystallography revealed some close contacts between the pincer complexes and the meso‐p‐tolyl subsitutents of the porphyrin. It was shown by 1H NMR spectroscopy that these close contacts were not present in solution and that this compound can potentially act as a novel building block for supramolecular architectures. 相似文献
93.
In this paper, we consider questions related to the structure of inverse matrices of linear bounded operators acting in infinite-dimensional complex Banach spaces. We obtain specific estimates of elements of inverse matrices for bounded operators whose matrices have a special structure. Matrices are introduced as special operator-valued functions on an index set. The matrix structure is described by the behavior of the given function on elements of a special partition of the index set. The method used for deriving the estimates is based on an analysis of Fourier series of strongly continuous periodic functions. 相似文献
94.
Jiang Tongsong Liu Yonghui Wei Musheng 《高校应用数学学报(英文版)》2006,21(1):113-118
This paper derives a theorem of generalized singular value decomposition of quaternion matrices (QGSVD),studies the solution of general quaternion matrix equation AXB -CYD= E,and obtains quaternionic Roth's theorem. This paper also suggests sufficient and necessary conditions for the existence and uniqueness of solutions and explicit forms of the solutions of the equation. 相似文献
95.
运输网络中最小饱和流的求解 总被引:4,自引:0,他引:4
运输网络中常常由于流量的不可控易发生堵塞现象.网络发生堵塞时的饱和流值达不到最大流值.最小饱和流是运输网络,尤其是紧急疏散网络设计中很重要的一个参数.通过建立网络的割集矩阵来确定网络的堵塞截面,基于此提出了求解最小饱和流的线性规划模型及算法.举例分析表明,利用该算法计算网络最小饱和流更加简便、更加实用. 相似文献
96.
97.
A set of new multi-component matrix Lie algebra is constructed, which is devoted to obtaining a new loop algebra A-2M. It follows that an isospectral problem is established. By making use of Tu scheme, a Liouville integrable multi-component hierarchy of soliton equations is generated, which possesses the multi-component Hamiltonian structures. As its reduction cases, the multi-component C-KdV hierarchy is given. Finally, the multi-component integrable coupling system of C-KdV hierarchy is presented through enlarging matrix spectral problem. 相似文献
98.
王筑娟 《数学的实践与认识》2006,36(11):217-222
讨论Dx广义正定阵的问题,给出了Dx广义正定阵的一些等价性的刻划,同时还讨论了Dx广义正定阵的若干性质. 相似文献
99.
Let G be a graph and let Pm(G) denote the number of perfect matchings of G.We denote the path with m vertices by Pm and the Cartesian product of graphs G and H by G×H. In this paper, as the continuance of our paper [W. Yan, F. Zhang, Enumeration of perfect matchings of graphs with reflective symmetry by Pfaffians, Adv. Appl. Math. 32 (2004) 175-188], we enumerate perfect matchings in a type of Cartesian products of graphs by the Pfaffian method, which was discovered by Kasteleyn. Here are some of our results:1. Let T be a tree and let Cn denote the cycle with n vertices. Then Pm(C4×T)=∏(2+α2), where the product ranges over all eigenvalues α of T. Moreover, we prove that Pm(C4×T) is always a square or double a square.2. Let T be a tree. Then Pm(P4×T)=∏(1+3α2+α4), where the product ranges over all non-negative eigenvalues α of T.3. Let T be a tree with a perfect matching. Then Pm(P3×T)=∏(2+α2), where the product ranges over all positive eigenvalues α of T. Moreover, we prove that Pm(C4×T)=[Pm(P3×T)]2. 相似文献
100.
R. Thomas conjectured, 20 years ago, that the presence of a positive circuit in the interaction graph of a dynamical system is a necessary condition for the presence of several stable states. Recently, E. Remy et al. stated and proved the conjecture for Boolean dynamical systems. Using a similar approach, we generalize the result to discrete dynamical systems, and by focusing on the asynchronous dynamics that R. Thomas used in the course of his analysis of genetic networks, we obtain a more general variant of R. Thomas’ conjecture. In this way, we get a necessary condition for genetic networks to lead to differentiation. 相似文献