Heterocyclization of thioamides containing an active methylene group (review)

Data from the last six years on the heterocyclization of thioamides containing an active methylene group are analyzed and classified. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1763–1800, November, 2008.     

Finite-time consensus for switching network topologies with disturbances

In this paper we investigate the properties of a decentralized consensus algorithm for a network of continuous-time integrators subject to unknown-but-bounded time-varying disturbances. The proposed consensus algorithm is based on a discontinuous local interaction rule. Under certain restrictions on the switching topology, it is proven that after a finite transient time the agents achieve an approximated consensus condition by attenuating the destabilizing effect of the disturbances. This main result is complemented by an additional result establishing the achievement of consensus under different requirements on the switching communication topology. In particular, we provide a convergence result that encompasses situations in which the time varying graph is always disconnected. Lyapunov analyses are carried out to support the suggested algorithms and results. Simulative tests considering, as case study, the synchronization problem for a network of clocks are illustrated and commented on to validate the developed analysis.     

Stochastic control of helicopter suspended load position

Modelling of the motion of a helicopter with a suspended load is described. The mathematical model takes into account stochastic disturbances acting on the load suspension point. The proposed approach allows solution of the problem of optimal control with minimization of oscillation and control power expenditure. The evolution of the system solution with time is investigated for various disturbance intensities. Computer calculation results are presented as a function of the suspension length and the intensity of stochastic disturbances.     

Optimal control of self-organized dynamics in cellular signal transduction

We demonstrate how model-based optimal control can be exploited in biological and biochemical modelling applications in several ways. In the first part, we apply optimal control to a detailed kinetic model of a glycolysis oscillator, which plays a central role in immune cells, in order to analyse potential regulatory mechanisms in the dynamics of associated signalling pathways. We demonstrate that the formulation of inverse problems with the aim to determine specific time-dependent input stimuli can provide important insight into dynamic regulations of self-organized cellular signal transduction. In the second part, we present an optimal control study aimed at target-oriented manipulation of a biological rhythm, an internal clock mechanism related to the circadian oscillator. This oscillator is responsible for the approximate endogenous 24 h (latin: circa dies) day-night rhythm in many organisms. On the basis of a kinetic model for the fruit fly Drosophila, we compute switching light stimuli via mixed-integer optimal control that annihilate the oscillations for a fixed time interval. Insight gained from such model-based specific manipulation may be promising in biomedical applications.     

Dispersion Stability and Particle Characterization by Sedimentation Kinetics in a Centrifugal Field

ABSTRACT

The analysis of sedimentation or flotation (creaming) by detecting the transmission profile over the entire sample height in an analytical centrifuge (using a Stability Analyzer) is described and illustrated for a diverse range of practical dispersions and emulsions. It is also illustrated how to use extrapolated results to estimate dispersion shelf life stability for samples in a gravitational field. Formulation optimization, such as choosing appropriate surfactant levels, is also shown to be a practical application of such methods.     

假设检验中p值的灵活运用

给出假设检验中p值的定义以及双边检验p值与单边检验p值的关系,介绍了利用p值将三种检验同时进行的方法及意义,最后给出应用实例.     

Achievement of chaotic synchronization trajectories of master-slave manipulators with feedback control strategy

This paper addresses a master-slave synchronization strategy for complex dynamic systems based on feedback control.This strategy is applied to 3-DOF planar manipulators in order to obtain synchronization in such complicated as chaotic motions of end-effectors.A chaotic curve is selected from Duffing equation as the trajectory of master end-effector and a piecewise approximation method is proposed to accurately represent this chaotic trajectory of end-effectors.The dynamical equations of master-slave mani...     

Heterogeneous polycondensation for composition control of poly(p‐mercaptobenzoyl‐co‐p‐benzamide) by shearing

Composition control of aromatic poly(thioester‐amide) was examined by the reaction‐induced phase separation during polymerization of S‐acetyl‐4‐mercaptobenzoic acid (AMBA) and p‐acetylaminobenzoic acid (AABA) in aromatic solvent. The poly(thioester‐amide)s were obtained as precipitates and their yields became lower at the middle range of the content of AMBA in feed (χ_f). The contents of p‐mercaptobenzoyl (MB) moiety (χ_p) in the precipitates prepared without shearing were in good agreement with the χ_f values. In contrast to this, the χ_p values of the precipitates prepared at χ_f of 50–70 mol % under shearing were much lower than the χ_f values. The reaction rate of AMBA increased with shearing, whereas that of AABA was unchanged by shearing. This shearing effect on the reaction rates accelerated to form the homo‐oligomers. The solubility of MB oligomers enhanced by shearing, whereas that of p‐benzamide oligomers did not enhance owing to the strong interaction through hydrogen bonding. The MB oligomers were inhibited to be precipitated, resulting in the lower χ_p values than the χ_f values. The composition could be controlled by the application of the shearing to the heterogeneous polymerization. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 4301–4308     

Electromechanical control of vibration on a plate submitted to a non-ideal excitation

This paper deals with the enhancement of electromechanical control of vibration on a thin plate submitted to non-ideal excitation. Modelling of the systems displays the non-ideal source used as external excitation above the structure on a particular surface and control force acting at specific points under the structure. The electromechanical device is composed by a RL circuit with a saturated inductance and stings connected to the plate is used as connection between the structure and the controller. Routh–Hurwitz criteria are used to obtain the stability condition of the controlled system and some dynamics exploration leads us to the condition for which the amplitude of vibration is reduced in the mechanical structure.