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61.
Wei‐Ling Wang Jian‐Wei Xu Yee‐Hing Lai 《Journal of polymer science. Part A, Polymer chemistry》2006,44(13):4154-4164
Bipyridinophane–fluorene conjugated copolymers have been synthesized via Suzuki and Heck coupling reactions from 5,8‐dibromo‐2,11‐dithia[3]paracyclo[3](4,4′)‐2,2′‐bipyridinophane and suitable fluorene precursors. Poly[2,7‐(9,9‐dihexylfluorene)‐co‐alt‐5,8‐(2,11‐dithia[3]paracyclo[3](4,4′)‐2,2′‐bipyridinophane)] ( P7 ) exhibits large absorption and emission redshifts of 20 and 34 nm, respectively, with respect to its planar reference polymer Poly[2,7‐(9,9‐dihexylfluorene)‐co‐alt‐1,4‐(2,5‐dimethylbenzene)] ( P11 ), which bears the same polymer backbone as P7 . These spectral shifts originate from intramolecular aromatic C? H/π interactions, which are evidenced by ultraviolet–visible and 1H NMR spectra as well as X‐ray single‐crystal structural analysis. However, the effect of the intramolecular aromatic C? H/π interactions on the spectral shift in poly[9,9‐dihexylfluorene‐2,7‐yleneethynylene‐co‐alt‐5,8‐(2,11‐dithia[3]paracyclo[3](4,4′)‐2,2′‐bipyridinophane)] ( P10 ) is much weaker. Most interestingly, the quenching behaviors of these two conjugated polymers are largely dependent on the polymer backbone. For example, the fluorescence of P7 is efficiently quenched by Cu2+, Co2+, Ni2+, Zn2+, Mn2+, and Ag+ ions. In contrast, only Cu2+, Co2+, and Ni2+ ions can partially quench the fluorescence of P10 , but much less efficiently than the fluorescence of P7 . The static Stern–Volmer quenching constants of Cu2+, Co2+, and Ni2+ ions toward P7 are of the order of 106 M?1, being 1300, 2500, and 37,300 times larger than those of P10 , respectively. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 4154–4164, 2006 相似文献
62.
Cyrille Ospel 《Journal of Pure and Applied Algebra》2002,173(3):315-337
For a commutative algebra the shuffle product is a morphism of complexes. We generalize this result to the quantum shuffle product, associated to a class of non-commutative algebras (for example all the Hopf algebras). As a first application we show that the Hochschild-Serre identity is the dual statement of our result. In particular, we extend this identity to Hopf algebras. Secondly, we clarify the construction of a class of quasi-Hopf algebras. 相似文献
63.
Multiderivations of Coxeter arrangements 总被引:3,自引:0,他引:3
Hiroaki Terao 《Inventiones Mathematicae》2002,148(3):659-674
Let V be an ℓ-dimensional Euclidean space. Let G⊂O(V) be a finite irreducible orthogonal reflection group. Let ? be the corresponding Coxeter arrangement. Let S be the algebra of polynomial functions on V. For H∈? choose α
H
∈V
* such that H=ker(α
H
). For each nonnegative integer m, define the derivation module D
(m)
(?)={θ∈Der
S
|θ(α
H
)∈Sα
m
H
}. The module is known to be a free S-module of rank ℓ by K. Saito (1975) for m=1 and L. Solomon-H. Terao (1998) for m=2. The main result of this paper is that this is the case for all m. Moreover we explicitly construct a basis for D
(m)
(?). Their degrees are all equal to mh/2 (when m is even) or are equal to ((m−1)h/2)+m
i
(1≤i≤ℓ) (when m is odd). Here m
1≤···≤m
ℓ are the exponents of G and h=m
ℓ+1 is the Coxeter number. The construction heavily uses the primitive derivation D which plays a central role in the theory of flat generators by K. Saito (or equivalently the Frobenius manifold structure
for the orbit space of G). Some new results concerning the primitive derivation D are obtained in the course of proof of the main result.
Oblatum 27-XI-2001 & 4-XII-2001?Published online: 18 February 2002 相似文献
64.
65.
We consider the semilinear Cauchy problem for a class of pseudo-differential operators generating sub-Markovian semigroups.
Solutions of such problems with negative definite nonlinearity play an important role in constructing branching measure-valued
processes. We establish local existence and uniqueness of solutions in the context of the Dirichlet space associated to the
problem. Comparison and global properties of solutions are also studied.
Accepted 29 August 2001. Online publication 17 December 2001. 相似文献
66.
Bruno Zimmermann 《Monatshefte für Mathematik》2002,135(3):253-258
We give a list including all finite groups G which admit smooth orientation preserving actions on homology 3-spheres (arbitrary actions, i.e. possibly with fixed points;
if the action is free then the group G has periodic cohomology and the classification of such groups is well known). The main work in this direction is due to M.
Reni. In the present paper, we complete and extend his results for the case of nonsolvable groups G.
Received 19 March 2001; in revised form 15 September 2001 相似文献
67.
Yuval Z. Flicker 《Mathematische Annalen》1993,297(1):199-219
68.
In this paper,we research general Defective Cion Problem under the model S,i.e,the number d of Defective cions is not fixed. For d=O,1,or 2. we get some good results. 相似文献
69.
Vahid Karimipour 《Letters in Mathematical Physics》1994,30(2):87-98
Quantum de Rham complexes on the quantum plane and the quantum group itself are constructed for the nonstandard deformation of Fun(SL(2)). It is shown that in contrast to the standardq-deformation of SL(2), the above complexes are unique for SL
h
(2). Also, as a byproduct, a new deformation of the two-dimensional Heisenberg algebra is obtained which can be used to construct models ofh-deformed quantum mechanics. 相似文献
70.
本文用ab initio计算方法,采用STO-3G基组,对二硝基卤代甲烷CH_2(NO_2)_3(1),CF_2(NO_2)_2(2);CCl_2(NO_2)_2(3)等分子作了单点计算,研究其旋转势能.全构型优化研究了五个具有对称性构型的结构和稳定性,并作了理论分析和探讨. 相似文献