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51.
The paper describes the quantized Hamilton dynamics (QHD) approach that extends classical Hamiltonian dynamics and captures quantum effects, such as zero point energy, tunneling, decoherence, branching, and state-specific dynamics. The approximations are made by closures of the hierarchy of Heisenberg equations for quantum observables with the higher order observables decomposed into products of the lower order ones. The technique is applied to the vibrational energy exchange in a water molecule, the tunneling escape from a metastable state, the double-slit interference, the population transfer, dephasing and vibrational coherence transfer in a two-level system coupled to a phonon, and the scattering of a light particle off a surface phonon, where QHD is coupled to quantum mechanics in the Schrödinger representation. Generation of thermal ensembles in the extended space of QHD variables is discussed. QHD reduces to classical mechanics at the first order, closely resembles classical mechanics at the higher orders, and requires little computational effort, providing an efficient tool for treatment of the quantum effects in large systems.  相似文献   
52.
In this article, we apply a novel time‐dependent discrete variable representation (TDDVR) method proposed by Barkakaty and Adhikari to investigate tunneling through an Eckart barrier. This semi‐classical method is theoretically rigorous and straightforward to implement. Among the TDDVR formulations, this report presents the first derivation of a rigorous form of quantum force (QF) for the present perspective. The validity of this semi‐classical approach is demanded based on the excellent agreement of the tunneling probability with the corresponding quantum results. © 2004 Wiley Periodicals, Inc. Int J Quantum Chem, 2004  相似文献   
53.
A weakly continuous, equicontinuous representation of a semitopological semigroup on a locally convex topological vector space gives rise to a family of operator semigroup compactifications of , one for each invariant subspace of . We consider those invariant subspaces which are maximal with respect to the associated compactification possessing a given property of semigroup compactifications and show that under suitable hypotheses this maximality is preserved under the formation of projective limits, strict inductive limits and tensor products.

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54.
We consider the covariance matrix,G mm =q 2<(x,m);(y,m)>, of thed-dimensionalq-states Potts model, rewriting it in the random cluster representation of Fortuin and Kasteleyn. In any of theq ordered phases, we identify the eigenvalues of this matrix both in terms of representations of the unbroken symmetry group of the model and in terms of random cluster connectivities and covariances, thereby attributing algebraic significance to these stochastic geometric quantities. We also show that the correlation length corresponding to the decay rate of one of the eigenvalues is the same as the inverse decay rate of the diameter of finite clusers. For dimensiond=2, we show that this correlation length and the correlation length of the two-point function with free boundary conditions at the corresponding dual temperature are equal up to a factor of two. For systems with first-order transitions, this relation helps to resolve certain inconsistencies between recent exact and numerical work on correlation lengths at the self-dual point o. For systems with second order transitions, this relation implies the equality of the correlation length exponents from above and below threshold, as well as an amplitude ratio of two. In the course of proving the above results, we establish several properties of independent interest, including left continuity of the inverse correlation length with free boundary conditions and upper semicontinuity of the decay rate for finite clusters in all dimensions, and left continuity of the two-dimensional free boundary condition percolation probability at o. We also introduce DLR equations for the random cluster model and use them to establish ergodicity of the free measure. In order to prove these results, we introduce a new class of events which we call decoupling events and two inequalities for these events. The first is similar to the FKG inequality, but holds for events which are neither increasing nor decreasing; the second is similar to the van den Berg-Kesten inequality in standard percolation. Both inequalities hold for an arbitrary FKG measure.  相似文献   
55.
Following the progression towards weaker logics, a number of authors have considered the notion of a sheaf over a quantale or, equivalently, a quantale valued set. In this paper, we use ideas from enriched category theory to motivate the definition of a quantic sheaf. Given a localic subquantale of Q, a quantic sheaf over Q gives a sheaf in the usual sense. As an application, we derive a series of sheaf representations for commutative rings including the familiar Pierce representation.  相似文献   
56.
We study super-Brownian motion inR d starting from a nontrivial finite measure and conditioned to nonextinction as defined by Evans. If (Y t ) t0 denotes this process, we provide a new approach to the immortal particle representation of (Y t ) t0 . We then show that the measureZ onR d defined byZ(B)= o 1 Y t (B) dt is almost surely finite on compact sets whend5 and almost surely infinite on every ball whend4.  相似文献   
57.
If the centered and normalized partial sums of an i.i.d. sequence of random variables converge in distribution to a nondegenerate limit then we say that this sequence belongs to the domain of attraction of the necessarily stable limit. If we consider only the partial sums which terminate atk n wherek n+1 ck n then the sequence belongs to the domain of semistable attraction of the necessarily semistable limit. In this paper, we consider the case where the limiting distribution is nonnormal. We obtain a series representation for the partial sums which converges almost surely. This representation is based on the order statistics, and utilizes the Poisson process. Almost sure convergence is a useful technical device, as we illustrate with a number of applications.This research was supported by a research scholarship from the Deutsche Forschungsgemeinschaft (DFG).  相似文献   
58.
Let (W, S) be a Coxeter group associated to a Coxeter graph which has no multiple bonds. Let H be the corresponding Hecke Algebra. We define a certain quotient \-H of H and show that it has a basis parametrized by a certain subset W cof the Coxeter group W. Specifically, W cconsists of those elements of W all of whose reduced expressions avoid substrings of the form sts where s and t are noncommuting generators in S. We determine which Coxeter groups have finite W cand compute the cardinality of W cwhen W is a Weyl group. Finally, we give a combinatorial application (which is related to the number of reduced expressions for w W cof an exponential formula of Lusztig which utilizes a specialization of a subalgebra of \-H.  相似文献   
59.
We demonstrate a one to one correspondence between the irreducible projective representations of an affine Kac-Moody group and those of the related loop group, which leads to the results that every non-trivial representation of an affine Kac-Moody group must have its degree greater than or equal to the rank of the group and that the equivalence appears if and only if the group is of type for some . Moreover the characteristics of the base fields for the non-trivial representations are found being always zero.

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60.
We obtain a resolution of the identity operator, for functions on a latticeZ d, which is derived from the block renormalization group. We use eigenfunctions of the terms of the decomposition to form a basis forl 2(Zd) and show how the basis is generated from lattice wavelets. The lattice spacing is taken to zero and continuum wavelets are obtained.  相似文献   
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