Kinetic theory of adsorption and desorption

In this paper we use stochastic methods to discuss adsorption and desorption. The paper derives generalized coefficients of sticking and accomodation depending on surface temperatureT _s and gas temperatureT _g and shows, that for additive Markov processes, these kinetic coefficients are identical. Furthermore, exact solutions of the kinetic equations for certain simple transition probabilitiesP(, ) are found and an approximation method for more complicatedP(, ) is given. The comparison of the theory with experimental results for noble gas-metal systems indicate a quadratic relationship between the first moment of the transition probabilityP(, ) and the well depth of the physisorption system.     

P-polarized nonlinear surface polaritons near the surface of a saturable self-defocusing medium: Threshold case

We have obtained the solution of the stationary problem for P-polarized nonlinear surface polaritons (NLSP) near the interface of two media, one of which is optically linear and the other having an optical nonlinearity with saturation and a dielectric function of the form: =_xx=_zz=₀+a|E|²/(1+b|E|²), where E is the amplitude of the electric field. On this basis the NLSP energy and propagation properties, the polarization structure and the localization depth of the NLSP field as well as the physically allowed region in the parameter space have been investigated for the case in which the parameter ₀ is positive, b is non-negative, and a and ₁ are negative (₁ is the dielectric function of the linear medium); ₀>|₁|.     

Static and dynamic properties of XY systems with extended defects in cubic anisotropic crystallines

Static and dynamic critical behavior ofXY systems in cubic anisotropic crystallines, with extended defects (or quenched nonmagnetic impurities) strongly correlated along _d -dimensional space and randomly distributed ind – _d dimensions, were studied. These extended defects make the systems coordinate anisotropic, resulting in unique critical behavior due to competition between the cubic anisotropy and the coordinate anisotropy. The systems were analyzed by an ^1/2 (4 – d) type of expansion with double expansion parameters based on a renormalization-group (RG) approach. Critical exponents were calculated near the second-order phase transition point and the behavior of the first-order transition was evaluated near the tricritical point.     

Asymptotic theory of multidimensional chaos

A delay-differential equationu(t)+u(t)=f(u(t–1)), 0t < , and its generalization are investigated in the limit 0, when the attractor's dimension increases infinitely. It is shown that a number of statistical characteristics are asymptotically independent of. As for the attractor, it can be regarded as a direct product ofO(1/) equivalent subattractors, their statistical characteristics being asymptotically independent of . The results enable one to predict some characteristics of the attractor with fractal dimensionD 1 for the case 1, when they are inaccessible numerically. The approach developed seems to be applicable for a wide class of spatiotemporal systems.     

Resonant shielding of an inhomogeneous gyrotropic plasma slab

Conclusions The problem of the incidence of a plane TM electromagnetic wave on an isotropic, symmetric, resonance plasma slab (n=2, 4, 6, ...), discussed in [1], was solved by an iteration method in a recent paper [6]. The physical results found there are the same as those of [1]. Zhivulin and Makarov [6] then applied the iteration method to the analogous problem of a gyrotropic resonance plasma slab [7]. The analysis in these papers furnishes a clearer mathematical justification of the results of [1] and the present paper and thus of the method used there. The present method, which satisfies only a physical condition of rigor, is preferable to the mathematically more rigorous methods (in particular, the iteration method) because of its simplicity, its graphic nature, and its clear physical meaning. It also answers many questions which cannot be answered in the more rigorous approach because of the serious difficulties which arise (and which have not yet been overcome).N. G. Denisov has called our attention to the fact that complete shielding was actually found previously by Rytov and Yudkevich [8], who treated the problem of the incidence of a plane TE electromagnetic wave on a slab with a dielectric constant (x)=₁ – A₁/(a – x)² for x<0. (x)=₂ – A₂/(b + x)² for x>0, and ₁ – A₁/(a² = ₂ – A₂/b² in the plane x=0. In the limita0, b0, they found results corresponding to a slab with a dielectric constant having a first-order pole; it is in this case that complete shielding is achieved. This method for obtaining the corresponding results is analogous to the method used in [1] and the present paper. We also note that the distribution of the effective dielectric constant (6) in the immediate vicinity of the pole—where the contribution of the last term. (1–u)x², can be neglected—is the same as the distribution adopted in [8] if we seta-b-0, ₁ = ₂, A₁=A₂=u.Scientific-Research Institute of Radiophysics. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 19, No. 8, pp. 1130–1141, August, 1976.     

Kinetic limits of the HPP cellular automaton

We study the Boltzmann-Grad limit in various versions of the two-dimensional HPP cellular automaton. In the completely deterministic case we prove convergence to an evolution that is not of kinetic type, a well-known phenomenon after Uchyiama's paper on the Broadwell gas, whereas the limiting equation becomes of kinetic type in the model with random collisions. The main part of the paper concerns the case where the collisions are deterministic and the randomness comes from inserting, between any two successive HPP updatings, ^- stirring updatings, <1 being any fixed positive number and a parameter which tends to 0. The initial measure is a product measure with average occupation numbers of the order of (low-density limit) and varying on distances of the order of ^–1. The limit as 0 of the system evolved for times of the order of ^-1- corresponds to the Boltzmann-Grad limit. We prove propagation of chaos and that the renormalized average occupation numbers (i.e., divided by) converge to the solution of the Broadwell equation. Convergence is proven at all times for which the solution of the Broadwell equation is bounded.     

The Statistics of the Trajectory of a Certain Billiard in a Flat Two-Torus

We consider a billiard in the punctured torus obtained by removing a small disk of radius >0 from the flat torus ², with trajectory starting from the center of the puncture. In this case the phase space is given by the range of the velocity only. Let (), and respectively R(), denote the first exit time (length of the trajectory), and respectively the number of collisions with the side cushions when ² is being identified with [0,1)². We prove that the probability measures on [0, ) associated with the random variables and R are weakly convergent as 0⁺ and explicitly compute the densities of the limits. Research partially supported by ANSTI grant C6189/2000.     

One-dimensional harmonic lattice caricature of hydrodynamics

We derive the hydrodynamic (Euler) approximation for the harmonic time evolution of infinite classical oscillator system on one-dimensional lattice ¹ It is known that equilibrium (i.e., time-invariant attractive) states for this model are translationally invariant Gaussian ones, with the mean 0, which satisfy some linear relations involving the interaction quadratic form. The natural parameter characterizing equilibrium states is the spectral density matrix function (SDMF)F(), [– , ). Time evolution of a space profile of local equilibrium parameters is described by a space-time SDMFF(t;x, ) t, xR ¹. The hydrodynamic equation forF(t; x, ) which we derive in this paper means that the normal mode profiles indexed by are moving according to linear laws and are mutually independent. The procedure of deriving the hydrodynamic equation is the following: We fix an initial SDMF profileF(x, ) and a familyP ,>0 of mean 0 states which satisfy the two conditions imposed on the covariance of spins at various lattice points: (a) the covariance at points close to the value ^–1 x in the stateP is approximately described by the SDMFF(x, ); (b) The covariance (on large distances) decreases with distance quickly enough and uniformly in. Given nonzerotR ¹, we consider the states P _–1 ,>0, describing the system at the time moments ^–1 t during its harmonic time evolution. We check that the covariance at lattice points close to ^–1 x in the state P _–1 is approximately described by a SDMFF(t;x, ) and establish the connection betweenF(t; x, ) andF(x,).     

Correlations and spectra of an intermittent chaos near its onset point

A one-parameter family of piecewise-linear discontinuous maps, which bifurcates from a periodic state of periodm, (m=2, 3,...) to an intermittent chaos, is studied as a new model for the onset of turbulence via intermittency. The onset of chaos of this model is due to the excitation of an infinite number of unstable periodic orbits and hence differs from Pomeau-Manneville's mechanism, which is a collapse of a pair of stable and unstable periodic orbits. The invariant density, the time-correlation function, and the power spectrum are analytically calculated for an infinite sequence of values of the bifurcation parameter which accumulate to the onset point _c from the chaos side - _c > 0. The power spectrum near=0 is found to consist of a large number of Lorentzian lines with two dominant peaks. The highest peak lies around frequency=2/m with the power-law envelope l/¦-(2/m)¦⁴. The second-highest peak lies around o = 0 with the envelope l/¦¦². The width of each line decreases as, and the separation between lines decreases as/lg3^–1. It is also shown that the Liapunov exponent takes the form-/m and the mean lifetime of the periodic state in the intermittent chaos is given bym ^–1(ln ^–1+1).     

A limit theorem for stochastic acceleration

We consider the motion of a particle in a weak mean zero random force fieldF, which depends on the position,x(t), and the velocity,v(t)= (t). The equation of motion is (t)=F(x(t),v(t), ), wherex(·) andv(·) take values in ^d ,d3, and ranges over some probability space. We show, under suitable mixing and moment conditions onF, that as 0,v (t)v(t/²) converges weakly to a diffusion Markov processv(t), and ² x (t) converges weakly to , wherex=lim ² x (0).     

Simulation calculation of dielectric constants: Comparison of methods on an exactly solvable model

A mean spherical model of classical dipoles on a simple cubic lattice of sideM=2N+1 sites is considered. Exact results are obtained for finite systems using periodic boundary conditions with an external dielectric constant and using reaction field boundary conditions with a cutoff radiusR _c N and an external dielectric constant. The dielectric constant in the disordered phase is calculated using a variety of fluctuation formulas commonly implemented in Monte Carlo and molecular dynamics simulations of dipolar systems. The coupling in the system is measured by the parametery=4 ²/9kT, where ² is the fixed mean square value of the dipole moments on the lattice. The system undergoes a phase transition aty2.8, so that very high dielectric constants cannot be obtained in the disordered phase. The results show clearly the effects of system size, cutoff radius, external dielectric constant, and different measuring techniques on a dielectric constant estimate. It is concluded that with periodic boundary conditions, the rate of approach of the dielectric constant estimate to its thermodynamic limit is asN ^–2/3 and depends only weakly on. Methods of implementing reaction field boundary conditions to give rapid convergence to the thermodynamic limit are discussed.     

Natural boundaries for area-preserving twist maps

We consider KAM invariant curves for generalizations of the standard map of the form (x, y)=(x+y, y+f(x)), wheref(x) is an odd trigonometric polynomial. We study numerically their analytic properties by a Padé approximant method applied to the function which conjugates the dynamics to a rotation +. In the complex plane, natural boundaries of different shapes are found. In the complex plane the analyticity region appears to be a strip bounded by a natural boundary, whose width tends linearly to 0 as tends to the critical value.     

Accurate calculation of functional determinants

A dependence of the functional determinant of the operator from the family D() satisfying the condition D()=fD()+D()f on the parameter m² of infrared regularization is found in the regularization method using a generalized function.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 6, pp. 27–32, June, 1988.     

Spectral behavior of quasi periodic potentials

Spectral properties of Schrödinger operators of the typeH =–+V, where is the Laplacian,V a quasiperiodic potential and a coupling constant, are developed.V is taken to be finite sum of exponentials with generic frequencies. For small a strong stability is shown. On the other hand, examples (in the finite diffeence case) are given, for which a transition in the type of spectrum occurs, as is increased.Research supported in part by grant NSF MCS 7900813     

Effective Dynamics for Bloch Electrons: Peierls Substitution and Beyond

We consider an electron moving in a periodic potential and subject to an additional slowly varying external electrostatic potential, (x), and vector potential A(x), with x ^d and 1. We prove that associated to an isolated family of Bloch bands there exists an almost invariant subspace of L ² ( ^d ) and an effective Hamiltonian governing the evolution inside this subspace to all orders in . To leading order the effective Hamiltonian is given through the Peierls substitution. We explicitly compute the first order correction. From a semiclassical analysis of this effective quantum Hamiltonian we establish the first order correction to the standard semiclassical model of solid state physics.     

Retardation of electromagnetic waves by helices of large diameters

This paper is devoted to the study of the wave retardation by helices of large diameters, when the lengthL of one turn of the helix is larger than the vacuum wavelength, i.e.L/>1. The dispersion equation of the tape helix wound up on a dielectric cylinder was derived and the dependence of the phase velocity of slowed-down waves on the diameter of helix was calculated. The theory was verified experimentally at a frequencyf=2·385 GHz. Helices were wound up on polyfoam (=1·04) and plexiglass (=2·55) cylinders of various diameters. For the helix wound up on plexiglass cylinders it was found that the wave retardation depends on the form of conductor from which the helix is made. The retardation of waves is determined by an effective dielectric constant _ef which is equal either ( _i + _e)/2 for the tape helix or ( _{i e}) for the helix made from a wire of the circular cross-section; here _i is the dielectric constant of inner dielectric rod and _e is that of outer space.     

Critical (Φ4)3,ε

The Euclidean (⁴)_3, model in R³ corresponds to a perturbation by a ⁴ interaction of a Gaussian measure on scalar fields with a covariance depending on a real parameter in the range 01. For =1 one recovers the covariance of a massless scalar field in R³. For =0, ⁴ is a marginal interaction. For 0<1 the covariance continues to be Osterwalder-Schrader and pointwise positive. We consider the infinite volume critical theory with a fixed ultraviolet cutoff at the unit length scale and we prove that for >0, sufficiently small, there exists a non-gaussian fixed point (with one unstable direction) of the Renormalization Group iterations. We construct the stable critical manifold near this fixed point and prove that under Renormalization Group iterations the critical theories converge to the fixed point. Partially supported by NSERC of CanadaLaboratoire Associé au CNRS. UMR 5825Partially supported by CNR, G.N.F.M. and MURST     

Effect of quenching temperature on the components of the permeability tensor and the complex dielectric constant of microwave magnesium ferrites

We report an investigation of the effect of the quenching temperature (from 900 °C, 700 °C, and for self-cooling) on the components of the permeability tensor and on the complex dielectric constant * of magnesium-aluminum, magnesium-chromium and magnesium-manganese, ferrites of fixed composition. The measuring apparatus and measurement procedure are described and an estimate of the errors is given. It is shown that due to quenching the gyrotropic properties of the ferrites are increased ( falls and _a increases), while the dielectric constant is unchanged. Quenching leads to an increase in the magnetic and dielectric losses.Translated from Izvestiya VUZ. Fizika, Vol. 11, No. 11, pp. 41–47, November, 1968.     

Dielectric properties of titanium and gadolinium doped MgO single crystals

The dielectric properties of titanium doped magnesium oxide (Ti/MgO) and gadolinium doped magnesium oxide (Gd/MgO) single crystals have been measured at room temperature over the frequency range 500 Hz to 50 kHz. For both the crystals, the dielectric constant is found to be independent of frequency and the ac conductivity Re{_ae} agrees well with the relation Re{_ae} ⁿ , being the angular frequency with n=0.84±0.05 for Ti/MgO andn=0.81±0.03 for Gd/MgO. The data fits well with the relation ^n–1(n<1), being the dielectric loss factor. An explanation may be found on the basis of the hopping phenomenon.     

The time dependent amplitude equation for the Swift-Hohenberg problem

Precise estimates for the validity of the amplitude approximation for the swift-Hohenberg equation are given, in a fully time dependent framework. It is shown that small solutions of orderO() which are modulated like stationary solutions have an evolution which is well described in the amplitude approximation for a time of orderO(^-2). For the proofs, we use techniques for nonlinear semigroups and oscillatory integrals.Dedicated to Res Jost and Arthur Wightman