SPME-GC-MS快速分析炼油厂废水中痕量VOCs

采用固相微萃取-气相色谱-质谱联用(SPME-GC-MS)对炼油厂废水中痕量挥发性有机化合物(VOCs)进行了定性分析,简化了预处理过程,总分析时间为1h左右.对比处理前后的废水样品的MS定性结果,为废水处理工艺的评价以及有机物降解机理提供了依据.     

基于BDF的无约束优化方法的收敛性分析

1.介 绍 在上个世纪的七十年代末、八十年代初,基于常微分方程的优化方法或者说同伦方法是一类与拟牛顿法和共轭梯度法等我们所熟知的优化方法相竞争的重要方法[1-6,8,13,14,16].由于这类方法只是简单地利用现成的数值求解常微分方程的软件包,如CVODE[7]、LSODE[12],对同伦方程(一般是一个常微分方程的初值问题)进行计算,除了一些特殊的病态问题     

A New Cycloartane from Sphaerophysa salsula

A novel cycloartane,named sphaerophysone A,9,19-cycloart-7β,24β,25-triol-1-en-3-one,was isolated from the ethanol extract of Sphaerophysa salsula DC.The structure was elucidated on the basis of spectral evidences and confirmed by X-ray analysis,the stereochemistry of the compound was also defined by X-ray analysis.     

车前子中多糖含量的测定

采用蒽酮-硫酸法比色测定，用精制车前子多糖测得车前子多糖对葡萄糖的换算因子，对我国同属不同品种的车前子不同采集时间及炮制前后其多糖含量进行了比较研究。结果表明：此测定方法简便可行。供试液在8h内显色稳定，重现性较好，平均回收率为97．8％，RSD=1．41％(n=5)。江西吉安产大粒车前子生品多糖含量在9．15％～9．83％之间，炮制后其多糖含量在6．29％～6.81％之间；南昌新祺周车前GAP标准基地的大粒车前子生品多糖含量为7.85％～8．38％，炮制后其多糖含量为6．01％～6．64％；东北产的小粒车前子生品多糖含量为6．61％，炮制后其多糖含量为6．45％。     

Effect of ion impinging on the microstructure and field emission of carbon nanotubes

Effects of ion impinging on the microstructure and field electron emission properties of screen-printed carbon nanotube films were investigated. We observed that the plasma treatment modified the microstructure of CNTs along with the remarkable increase of emission site density. With the prolongation of ion impinging time, the emission current falls down first, and then rises up to higher than that of the untreated films. It is proposed that the change of emission characteristics is due to the different emission mechanisms. After the treatment, electrons are emitted predominantly from the nano-nodes on the tube wall instead from the nanotube tips.     

Absorbing boundary conditions for reaction-diffusion equations

We treat here of the question of absorbing boundary conditionsfor nonlinear diffusion equations. We use the conditions designedfor the linear equation, we prove them to be well posed forthe nonlinear problem, and through numerical experiments thatthey are well suited for reaction–diffusion equations.     

Mathematical modelling of the oxidation of nickel titanium alloys

A one-dimensional bulk reaction model for the oxidation of nickeltitanium is formulated, with preferential oxidation of titaniumbeing included. The modelling is directed at the better understandingof the dominant mechanisms involved in the oxidation processand their significance for the biocompatibility of the alloy.Two different regimes for the relative diffusivities of oxygenand the metals are investigated. By assuming fast bulk reactions,different asymptotic structures emerge in different parameterregimes and the resulting models take the form of moving boundaryproblems. Different profiles of nickel concentration are obtained:in particular a nickel-rich layer (observed in practice) ispresent below the oxide/metal interface for the case when oxygenand the metals diffuse at comparable rates.     

线性泛函方程解的振动性的新结果

本文研究高阶泛函方程x(g(t))=P(t)x(t)+Q1(t)x(g2(t))+…+Qk(t)x(gk+1(t))解的振动性,得到了一些新的振动条件.改进和推广了已有结果.     

修正的Shepard型算子的Lp-逼近

摘要:本文在L_[0.1]~p空间给出了 Durrmeyer型修正的shepard算子D_n(f,x),对 f∈L_[0.1]~p,(p≥1),得到了下列的Jackson型估计:││D)n(f)-f││_p≤ C_(pλω)(f,n~(-1))p,λ≥2, Cω(f,n~(-1)logn)p,λ=2, C_(pλω)(f,n~(-1))p,1<λ<2,