全文获取类型
收费全文 | 185534篇 |
免费 | 16783篇 |
国内免费 | 14063篇 |
专业分类
化学 | 69102篇 |
晶体学 | 2484篇 |
力学 | 14904篇 |
综合类 | 2175篇 |
数学 | 53880篇 |
物理学 | 73835篇 |
出版年
2023年 | 1181篇 |
2022年 | 1902篇 |
2021年 | 3768篇 |
2020年 | 3631篇 |
2019年 | 3698篇 |
2018年 | 3475篇 |
2017年 | 3765篇 |
2016年 | 4214篇 |
2015年 | 3418篇 |
2014年 | 5672篇 |
2013年 | 9945篇 |
2012年 | 6531篇 |
2011年 | 7659篇 |
2010年 | 7523篇 |
2009年 | 13157篇 |
2008年 | 14205篇 |
2007年 | 12912篇 |
2006年 | 11224篇 |
2005年 | 8762篇 |
2004年 | 8239篇 |
2003年 | 7833篇 |
2002年 | 10614篇 |
2001年 | 6792篇 |
2000年 | 6162篇 |
1999年 | 5717篇 |
1998年 | 4987篇 |
1997年 | 3819篇 |
1996年 | 3490篇 |
1995年 | 3702篇 |
1994年 | 3646篇 |
1993年 | 2891篇 |
1992年 | 2399篇 |
1991年 | 1798篇 |
1990年 | 1509篇 |
1989年 | 1238篇 |
1988年 | 1188篇 |
1987年 | 993篇 |
1986年 | 737篇 |
1985年 | 1560篇 |
1984年 | 1174篇 |
1983年 | 812篇 |
1982年 | 1117篇 |
1981年 | 1222篇 |
1980年 | 1066篇 |
1979年 | 965篇 |
1978年 | 851篇 |
1977年 | 739篇 |
1976年 | 670篇 |
1974年 | 401篇 |
1973年 | 561篇 |
排序方式: 共有10000条查询结果,搜索用时 217 毫秒
71.
语音通信系统中,语音通过信道传输将不可避免地引入码间串扰和信号畸变,同时受到噪声污染。本文在分析自适应盲均衡算法CMA(constant modulus algorithm)和改进盲均衡算法的基础上,考虑到自适应盲均衡技术在语音噪声控制方面能力有限,将自适应盲均衡技术与小波包掩蔽阈值降噪算法联合使用,形成一种基带语音增强新方法。仿真试验结果显示自适应盲均衡技术可以使星座图变得清晰而紧凑,有效减小误码率。研究证实该方法在语音信号ISI和畸变严重情况下,在白噪及有色噪声不同的噪声环境中都具有稳定的降噪能力,消噪同时可获得汉语普通话良好的听觉效果。 相似文献
72.
Leonor Contreras Ignacio Villarroel Camila Torres Roberto Rozas 《Molecules (Basel, Switzerland)》2021,26(6)
Doxorubicin (DOX), a recognized anticancer drug, forms stable associations with carbon nanotubes (CNTs). CNTs when properly functionalized have the ability to anchor directly in cancerous tumors where the release of the drug occurs thanks to the tumor slightly acidic pH. Herein, we study the armchair and zigzag CNTs with Stone–Wales (SW) defects to rank their ability to encapsulate DOX by determining the DOX-CNT binding free energies using the MM/PBSA and MM/GBSA methods implemented in AMBER16. We investigate also the chiral CNTs with haeckelite defects. Each haeckelite defect consists of a pair of square and octagonal rings. The armchair and zigzag CNT with SW defects and chiral nanotubes with haeckelite defects predict DOX-CNT interactions that depend on the length of the nanotube, the number of present defects and nitrogen doping. Chiral nanotubes having two haeckelite defects reveal a clear dependence on the nitrogen content with DOX-CNT interaction forces decreasing in the order 0N > 4N > 8N. These results contribute to a further understanding of drug-nanotube interactions and to the design of new drug delivery systems based on CNTs. 相似文献
73.
利用热丝化学气相沉积法(HFCVD)在碳化硅基底上制备金刚石薄膜,采用场发射扫描电子显微镜、拉曼光谱仪、原子力显微镜研究了在不同甲烷浓度条件下制备的金刚石薄膜表面形貌及物相组成,在干摩擦条件下通过往复式摩擦磨损实验测试并计算了已制备金刚石薄膜的摩擦系数和磨损率,结合物相分析及摩擦磨损实验结果分析了甲烷浓度的改变对金刚石薄膜摩擦磨损性能的影响。结果表明,由于甲烷气体含量的升高,金刚石薄膜结晶质量下降,薄膜由微米晶向纳米晶转变。摩擦磨损实验结果显示:3%甲烷浓度条件下制备的金刚石薄膜耐磨性较好,磨损率为2.2×10-7 mm3/mN;5%甲烷浓度条件下制备的金刚石薄膜摩擦系数最低(0.032),磨损率为5.7×10-7 mm3/mN,制备的金刚石薄膜的耐磨损性能相比于碳化硅基底(磨损率为9.89×10-5 mm3/mN)提升了两个数量级,显著提高了碳化硅基底的耐磨性。 相似文献
74.
Quinones are electroactive species that have shown great promise for redox flow batteries due to the ability to tune their properties and to act as both negative and positive electrolytes. The following review outlines highlights of work in the last couple of years working to provide materials with higher stability, solubility, and performance. Developments toward stable negolytes have provided opportunities for potential commercial opportunities when paired with alternate chemistries. However, the stability of quinones in high potential electrolytes is still not sufficient and the number of potential quinones limited. 相似文献
75.
Mourad Kainane Mezadek Mohamed Kainane Mezadek Michael Reissig 《Mathematical Methods in the Applied Sciences》2020,43(6):3117-3147
In this paper, we study the global (in time) existence of small data solutions to the Cauchy problem for the semilinear wave equation with friction, viscoelastic damping, and a power nonlinearity. We are interested in the connection between regularity assumptions for the data and the admissible range of exponents p in the power nonlinearity. 相似文献
76.
Comparative study on transport properties of N-, P-, and As-doped SiC nanowires: Calculated based on first principles 下载免费PDF全文
According to the one-dimensional quantum state distribution, carrier scattering, and fixed range hopping model, the structural stability and electron transport properties of N-, P-, and As-doped SiC nanowires(N-SiCNWs, P-SiCNWs, and As-SiCNWs) are simulated by using the first principles calculations. The results show that the lattice structure of NSiCNWs is the most stable in the lattice structures of the above three kinds of doped SiCNWs. At room temperature,for unpassivated SiCNWs, the doping effect of P and As are better than that of N. After passivation, the conductivities of all doped SiCNWs increase by approximately two orders of magnitude. The N-SiCNW has the lowest conductivity. In addition, the N-, P-, As-doped SiCNWs before and after passivation have the same conductivity–temperature characteristics,that is, above room temperature, the conductivity values of the doped SiCNWs all increase with temperature increasing.These results contribute to the electronic application of nanodevices. 相似文献
77.
Recent Progress in the $L_p$ Theory for Elliptic and Parabolic Equations with Discontinuous Coefficients 下载免费PDF全文
Hongjie Dong 《分析论及其应用》2020,36(2):161-199
In this paper, we review some results over the last 10-15 years on elliptic and parabolic equations with discontinuous coefficients. We begin with an approach given by N. V. Krylov to parabolic equations in the whole space with $\rm{VMO}_x$ coefficients. We then discuss some subsequent development including elliptic and parabolic equations with coefficients which are allowed to be merely measurable in one or two space directions, weighted $L_p$estimates with Muckenhoupt ($A_p$) weights, non-local elliptic and parabolic equations, as well as fully nonlinear elliptic and parabolic equations. 相似文献
78.
Nai-Heng Chang 《Applicable analysis》2018,97(10):1771-1796
In this paper, we study the Cauchy problem for magnetic fluid of spin-liquid type with Mermin-Ho relation in the three-dimensional space and prove global existence and uniqueness of solutions. The proof is based on the equivalence relation between smooth solutions of the spin-liquid model and the systems of Schrödinger equations with Abelian gauge field. The Sobolev spaces with fractional derivatives are also used in our estimates. 相似文献
79.
The stable phase equilibria of quaternary systems LiBr-NaBr-MgBr2-H2O and LiBr-KBr-MgBr2-H2O at 298.15 K were studied by both experimental measurement(isothermal solution saturation method) and theoretical prediction(Pitzer model). The solubilities of the saturated solution have been determined experimentally and two stable phase diagrams and relevant water diagrams of the two quaternary systems were obtained. Results show that quaternary system LiBr-NaBr-MgBr2-H2O is hydrate II type as NaBr and NaBr·2H2O coexistence. Its phase diagram consists of only one invariant point, four univariant curves, and five crystallization fields. The quaternary system LiBr-KBr-MgBr2-H2O is a complex type as the double salt KBr·MgBr2·6H2O formed. In addition to this double salt, the three single salts LiBr·2H2O, KBr and MgBr2·6H2O also crystallize. In this paper, the solubilities of phase equilibria in above quaternary systems were also calculated by the Pitzer's electrolyte solution model. All the needed parameters can be obtained from the literature or be fitted by experimental data. On the Basis of the experimental and calculated results, the phase diagram of the quaternary system was plotted for comparison. It shows that the calculation results are consistent with the experimental ones. 相似文献
80.