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91.
A new study of the enzymatic hydrolysis of carboxymethyl cellulose with a bulk acoustic wave sensor 总被引:4,自引:0,他引:4
A new bulk acoustic wave (BAW) cellulase sensing technique, which is based on the enzymatic hydrolysis process of sodium carboxymethylcellulose (CMC) by cellulase, was established. The frequency shift curves of BAW sensor indicated that the viscosity of the tested solutions decreased during the hydrolysis process. The hydrolysis rate of CMC by cellulase was calculated from the frequency shift curves. The hydrolysis rate of CMC under different pH conditions at 30°C showed that cellulase had high hydrolysis ability approximately at pH 5.0. Kinetic parameters (the Michaelis constant Km and the maximum rate Vmax) of the process were estimated by using a linear method of Lineweaver–Burk plot. Km is 1.95±0.25 mg ml−1 and Vmax is −(4.25±0.58)×10−3 g1/2 cm−3/2 cP1/2 min−1. Also the activation energy (Ea) of the enzymatic hydrolysis, with a value of 51.99±1.26 kJ mol−1, was estimated in this work. 相似文献
92.
Shemseddine Fessi Abdelhamid Ghorbel 《Journal of Sol-Gel Science and Technology》2003,26(1-3):837-841
In this work, the metal dispersion of the Pd/Al2O3 catalyst prepared by sol-gel method is improved by an adequate optimisation of the preparative variables. First, the gelation temperature and the ageing time are selected, in order to avoid the reduction of the metal precursor (palladium acetylacetonate, Pd(acac)2) by the solvent (sec-butanol, sB). The metal sintering effect on the catalysts treated in oxygen at 500°C is then minimized when the alumina pore size is controlled by the variation of the alumium alkoxide (AsB) concentration and the acetic acid amount ([AcA]/[AsB]). The appearance of new palladium particles on the alumina surface and the matching between the particle diameters and the pore sizes were also effective for the metallic surface area improvement on the samples treated in oxygen at 800°C. Compared to the reference catalysts, the higher metal dispersion obtained on the sol-gel ones was the determinant factor for their higher catalytic activity in methane combustion. 相似文献
93.
94.
This paper introduces a bi-virus model with time-varying susceptibility. The model describes the case that there coexist two viruses and the time-varying susceptibility due to repeated infections. For different parameters, we investigate the stability of various equilibriums. Under appropriate conditions the two viruses show competitive relationship, that is, one virus will eventually become a pandemic, and the other virus will eventually disappear. For this case, we further study the dynamical behavior of virus transmission. The model shows some new phenomena, that is, the outbreak of the virus will be delayed appropriately, giving people an illusion. Finally, we present a numerical example to illustrate the effectiveness of the theoretical results. 相似文献
95.
Cécile Huybrechts 《Journal of Algebraic Combinatorics》1996,5(4):329-335
Let be a rank three incidence geometry of points, lines and planes whose planes are linear spaces and whose point residues are dual linear spaces (notice that we do not require anything on the line residues). We assume that the residual linear spaces of belong to a natural class of finite linear spaces, namely those linear spaces whose full automorphism group acts flag-transitively and whose orders are polynomial functions of some prime number. This class consists of six families of linear spaces. In the amalgamation of two such linear spaces imposes an equality on their orders leading, in particular, to a series of diophantine equations, the solutions of which provide a reduction theorem on the possible amalgams of linear spaces that can occur in .We prove that one of the following holds (up to a permutation of the words point and plane):A) the planes of and the dual of the point residues belong to the same family and have the same orders,B) the diagram of is in one of six families,C) the diagram of belongs to a list of seven sporadic cases.Finally, we consider the particular case where the line residues of are generalized digons. 相似文献
96.
A model, based on inverse gas chromatography experiments, has been developed for intermolecular interaction and its temperature dependence. The model ascribes to each substance a four-component solubility parameter; the four components reflect the van der Waals, polar, electron donor, and electron acceptor interactive properties. Their values depend on temperature in the same manner as does the cohesive energy. The latter was found to depend only on the critical temperature, the acentric factor, and the reduced temperature. The model was used for evaluation of the solubility parameters from polymer-solvent interaction coefficients and their temperature dependence with high accuracy. For binary solventsolvent mixtures, the free energy of mixing and its temperature dependence, as well as enthalpy of mixing can be derived from this model with a good accuracy. 相似文献
97.
Vaishali Tiwari 《Thermochimica Acta》2006,443(2):206-211
Densities ρ and viscosities η of two hydroxamic acids, N-phenyl-2-chlorobenzo- and N-o-tolyl-4-chlorobenzo-, have been determined as a function of their concentration in aqueous acetone solution at temperatures 303.15 and 313.15 K. Apparent molar volumes, standard-state partial molar volumes and relative viscosities have been calculated. The viscosity data have been analyzed using Jones-Dole equation. The activation thermodynamic parameters of viscous flow have been evaluated using Feakins equation. These were obtained to throw light on the mechanism of viscous flow. Thermodynamic interactions in solutions have been studied in terms of a number of excess functions calculated from the experimental data. The effect of hydroxamic acid concentration and temperature on these parameters has been discussed. The results were interpreted in the light of solute-solvent interactions in aquo-organic media. 相似文献
98.
L. N. Ignatieva A. Yu. Beloliptsev S. G. Kozlova V. M. Buznik 《Journal of Structural Chemistry》2004,45(4):599-609
Quantum-chemical calculations of the geometrical structure and vibrational spectra of CnF2n+2 oligomers (n = 5–8) in the chain and branched conformations are reported. The lengthening of the chain of CnF2n+2 does not substantially affect the geometrical parameters of the oligomers. In all cases under study, the most optimal structure of the molecule is a zigzag chain with bond lengths R(C-C) = 1.53 –1.54 and R(C-F) = 1.36 –1.34 ; the chain is rolled into a helix, which makes an angle of 17° with the plane. The IR spectra are sensitive to the structural deficiency of oligomers CnF2n+2 associated with the lateral trifluoromethyl groups formed in the chain; the spectra can be used for revealing defects of this type in the structure of polytetrafluoroethylene (PTFE). The possibility of defects associated with the lateral CF3 groups in the structure of PTFE and its low-temperature modifications is explained based on the calculated total energies of CnF2
n+2.Original Russian Text Copyright © 2004 by L. N. Ignatieva, A. Yu. Beloliptsev, S. G. Kozlova, and V. M. BuznikTranslated from Zhurnal Strukturnoi Khimii, Vol. 45, No. 4, pp. 632–643, July–August, 2004.This revised version was published online in April 2005 with a corrected cover date. 相似文献
99.
100.
Traceability of the measurement of analytical parameters capable of evaluating the performance of methods is an important
concept for the assessment of quality for the routine control, especially for residue monitoring of non-authorized medicinal
substances in food from animal origin. The European Decision no. 657/2002/EC recommends to calculate two statistical limits,
CCα and CCβ, which allow to evaluate the critical concentrations above which the method reliably distinguish and quantify
a substance taking into account the variability of the method and the statistical risk to take a wrong decision. The calculation,
which can be derived from the ISO standard no. 11843 is applied on a routine basis. An example displays a very simple way
for evaluating the performance of an LC-MSMS method which has been validated a few years ago and is qualified onto a Micromass
Quattro LCZ tandem mass spectrometer to monitor and confirm the nitrofuran metabolite residues in food from animal origin.
Community Reference Laboratory for Antimicrobial Veterinary Drug Residue Control in Food from Animal Origin 相似文献