Thermal onset chemically reactive Oldroyd-B nanofluid with immersion of microorganism in three-dimensional accelerating frame

The current research effort focuses on the employment of nanoparticles for 3-D chemically reactive flow of an Oldroyd-B nanofluid caused by a bidirectional accelerating surface. The implication of thermal radiation is also taken into account. The main characteristics of nanofluids, such as Brownian motion and thermophoresis are investigated using classic Buongiorno nanofluid design. The suitable transformation has been used to decrease the relevant equation for the defined theoretical model, for which the exact method is determined using the method of homotopic. Following that, a comprehensive graphic assessment of dimensionless velocities, concentration, and temperature distribution, as well as their physical significance, is considered. Furthermore, interesting physical quantities such as local Nusselt and Sherwood numbers are calculated and determined mathematically. The study stresses that increasing relaxation time reduces variation in both components of velocities, but the effect of continuous retardation time is exactly the reverse. For a while, larger combined convection and floating proportion parameters, the velocity distribution is said to have a rising movement in the horizontal plane. Furthermore, increasing the thermophoresis parameter improves temperature and centration distributions.     

A mini review on synthesis,properties and applications of deep eutectic solvents

Organic solvents have been of great importance for many chemical synthesis, storage and separation processes. The industries and research laboratories are heavily dependent on organic solvents in bulk; are highly volatile, lipophilic, toxic and causes a number of issues to the human health and the environmental fitness. Neoteric solvents have been proposed as a better substitute to these harmful organic solvents, and scientists have come up with several neoteric solvents in the last three decades, to name a few: ionic liquids (ILs), switchable solvents, bio-based solvents and deep eutectic solvents (DESs). These neoteric solvents attract a great deal of interest from the scientific community due to plenty of possibilities, therefore, they have huge impact and novel studies are reported quite frequently on the same. In this review, we intend to focus to brief on deep eutectic solvents, about their properties, synthesis, promising applications, and how they gradually emerged from ILs and later stood out as a different class of neoteric solvent, which overcomes many shortcomings of ILs. DESs are possibly receptive synthetic compounds and their relationship based on the hydrogen bond donor or acceptor restricts their reactivity and allow to explore in different disciplines of science.     

An overview on covalent organic frameworks: synthetic reactions and miscellaneous applications

Covalent organic frameworks (COFs) are an emerging class of porous crystalline materials which are completely constructed from organic building blocks through robust covalent bonds. High surface areas, compositional and structural tunability, low density, and superior stability have rendered COF candidates in a variety of applications, such as adsorption and separation, catalysis, electronics, chemical sensing, optics, and so forth. To better understand the structures and properties of COFs as well as the design principles, it is of great significance to learn about the linkages formed during synthetic reactions that contribute to the high crystallinity and stability of COFs. In this review, we will first discuss various linkages that have been utilized for COF construction up to date, followed by an outline of their miscellaneous applications, providing a comprehensive and detailed overview in this file.     

Spallation neutron spectrum on a massive lead/paraffin target irradiated with 1 GeV protons

The gamma-ray spectra emitted by decaying of residual nuclei produced by spallation neutrons in (n, xn), (n, xnyp), (n, p), (n, ) reactions with activation threshold detectors, i.e. ²⁰⁹Bi, ¹⁹⁷Au, ⁵⁹Co, ¹¹⁵In, ²³²Th, were measured in the Laboratory of Nuclear Problems (LNP), JINR, Dubna, Russia. Spallation neutrons were generated by bombarding a 20 cm long cylindrical lead target with 8 cm diameter surrounded by a 6 cm thick layer of paraffin moderator with 1 GeV proton beam from the NUCLOTRON accelerator. Reaction rates and a spallation neutron spectrum were measured and compared with CASCADE code calculations.     

密度泛函理论下的电负性均衡及应用

以密度泛函理论为框架,综述电负性和电负性均衡理论的发展及其在探讨各种分子性质时的应用。     

新型主体分子——杯芳烃的研究进展

评述了杯芳烃的合成途径、结构以及在分子识别等应用方面的研究进展,能者文献２８篇。     

Plasmon‐Enhanced Fluorescence Resonance Energy Transfer

In this review, we firstly introduce physical mechanism of fluorescence resonance energy transfer (FRET), the methods to measure FRET efficiency, and the applications of FRET. Secondly, we introduce the principle and applications of plasmon‐enhanced fluorescence (PEF). Thirdly, we focused on the principle and applications of plasmon‐enhanced FRET. This review can promote further understanding of FRET and PE‐FRET.