全文获取类型
收费全文 | 3627篇 |
免费 | 317篇 |
国内免费 | 405篇 |
专业分类
化学 | 571篇 |
晶体学 | 6篇 |
力学 | 161篇 |
综合类 | 123篇 |
数学 | 2965篇 |
物理学 | 523篇 |
出版年
2024年 | 4篇 |
2023年 | 24篇 |
2022年 | 58篇 |
2021年 | 75篇 |
2020年 | 97篇 |
2019年 | 90篇 |
2018年 | 91篇 |
2017年 | 103篇 |
2016年 | 109篇 |
2015年 | 73篇 |
2014年 | 156篇 |
2013年 | 385篇 |
2012年 | 175篇 |
2011年 | 218篇 |
2010年 | 190篇 |
2009年 | 257篇 |
2008年 | 276篇 |
2007年 | 257篇 |
2006年 | 206篇 |
2005年 | 178篇 |
2004年 | 188篇 |
2003年 | 172篇 |
2002年 | 160篇 |
2001年 | 113篇 |
2000年 | 87篇 |
1999年 | 114篇 |
1998年 | 101篇 |
1997年 | 87篇 |
1996年 | 56篇 |
1995年 | 44篇 |
1994年 | 36篇 |
1993年 | 18篇 |
1992年 | 23篇 |
1991年 | 14篇 |
1990年 | 23篇 |
1989年 | 14篇 |
1988年 | 13篇 |
1987年 | 8篇 |
1986年 | 6篇 |
1985年 | 7篇 |
1984年 | 8篇 |
1983年 | 5篇 |
1982年 | 6篇 |
1981年 | 6篇 |
1980年 | 3篇 |
1979年 | 5篇 |
1977年 | 3篇 |
1974年 | 2篇 |
1959年 | 1篇 |
1936年 | 2篇 |
排序方式: 共有4349条查询结果,搜索用时 15 毫秒
71.
72.
73.
The Fermi and Coulomb holes of the 21
S state of the helium isoelectronic sequence are investigated. Several interesting differences between the results obtained and those which might be expected on the basis of the corresponding 23
S state are pointed out and discussed. 相似文献
74.
75.
Paul W. Chun 《International journal of quantum chemistry》2001,85(6):697-712
This communication will demonstrate the existence of a thermodynamic molecular switch in the pairwise, sequence‐specific hydrophobic interaction of Ile–Ile, Leu–Ile, Val–Leu, or Ala–Leu over the temperature range of 273–333 K reported by Nemethy and Scheraga in 1962. Based on Chun's development of the Planck–Benzinger methodology, the change in inherent chemical bond energy at 0 K, ΔH°(T0), is 3.0 kcal mol?1 for Ile–Ile, 2.4 for Leu–Ile, 1.8 for Val–Leu, and 1.2 kcal mol?1 for Ala–Leu. The value of ΔH°(T0) decreases as the length of the hydrophobic side chain decreases. It is clear that the strength and stability of the hydrophobic interaction is determined by the packing density of the side chains, with Ala–Leu being the most stable. At 〈Tm〉, the thermal agitation energy, $\int^{T}_{0}\Delta Cp^{\circ}(T)\,dT$, is about five times greater than ΔH°(T0) in each case. Additionally, the thermal agitation energy for the same series, evaluated at 〈Tm〉, decreases in the same order, that is, as the length of the side chain decreases. This pairwise, sequence‐specific hydrophobic interaction is highly similar in its thermodynamic behavior to that of other biological systems, except that the negative Gibbs free energy change minimum at 〈Ts〉 occurs at a considerably higher temperature, 355 K compared to about 300 K. The melting temperature, 〈Tm〉, is also high, 470 K compared to 343 K in a biological system. The implication is that the negative Gibbs free energy minimum at a well‐defined 〈Ts〉 has it origin in the hydrophobic interactions, which are highly dependent on details of molecular structure. In addition to the four specific dipeptide interactions described, we have shown in our unpublished work the existence of a thermodynamic molecular switch in the interactions of 32 dipeptides wherein a change of sign in ΔCp°(T)reaction leads to a true negative minimum in the Gibbs free energy of reaction, and hence, a maximum in the related Keq. Indeed, all interacting biological systems that we have thus far examined using the Planck–Benzinger approach point to the universality of thermodynamic molecular switches. © 2001 John Wiley & Sons, Inc. Int J Quantum Chem, 2001 相似文献
76.
茂锆载体催化剂下的乙烯/辛烯共聚及聚合物的^13C NMR研究 总被引:3,自引:0,他引:3
茂锆载体催化剂下的乙烯/辛烯共聚及聚合物的~(13)CNMR研究刘胜生,于广谦,黄葆同(中国科学院长春应用化学研究所长春130022)关键词茂锆载体催化剂,共聚,序列分布,~(13)CNMR由于茂锆催化剂具有高活性,单一活性中心等特点[1,2],并且能... 相似文献
77.
78.
79.
Two published procedures for glass capillary column production are applied to produce capillaries for chromatography of polar natural compounds. Soda lime glass capillaries, after leaching with aqueous HCL, are either treated with colloidal silicic acid or with barium carbonate and coated with either Silar 7CP or SE 52. A test mixture as well as polar carbohydrate and peptide mixtures are chromatographed on the different columns and their chromatographic properties are evaluated. Combined capillary gas chromatography-electron impact and chemical ionization mass spectrometry are used for identification of the peptide sequence. 相似文献
80.
Yong Deng Da Cheng Yang Yi Shen Yu Guo Zhong 《中国化学快报》2007,18(1):7-9
Based on the structure-activity relationships and antiangiogenic mechanism of RGD-containing peptides,a series of 5-amino- 1,3-dihydro-1,3-dioxo-2H-isoindole derivatives were synthesized.The structures were characterized by ~1H NMR,MS and elementary analysis.There ability to inhibit angiogenesis were evaluated by chick embryo chorioallantoic membrane assay at 10~(-5) mol/L.Compounds 7a and 7b displayed obvious antiangiogenic activity. 相似文献