首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   17874篇
  免费   3872篇
  国内免费   1859篇
化学   11255篇
晶体学   136篇
力学   1602篇
综合类   194篇
数学   3509篇
物理学   6909篇
  2024年   52篇
  2023年   249篇
  2022年   386篇
  2021年   555篇
  2020年   761篇
  2019年   684篇
  2018年   588篇
  2017年   669篇
  2016年   1031篇
  2015年   944篇
  2014年   1183篇
  2013年   1701篇
  2012年   1270篇
  2011年   1310篇
  2010年   1116篇
  2009年   1184篇
  2008年   1265篇
  2007年   1252篇
  2006年   1088篇
  2005年   1060篇
  2004年   862篇
  2003年   734篇
  2002年   521篇
  2001年   421篇
  2000年   405篇
  1999年   328篇
  1998年   299篇
  1997年   249篇
  1996年   179篇
  1995年   176篇
  1994年   156篇
  1993年   113篇
  1992年   102篇
  1991年   82篇
  1990年   75篇
  1989年   62篇
  1988年   72篇
  1987年   54篇
  1986年   56篇
  1985年   57篇
  1984年   46篇
  1983年   14篇
  1982年   38篇
  1981年   34篇
  1980年   23篇
  1979年   21篇
  1978年   18篇
  1977年   12篇
  1976年   9篇
  1974年   9篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
61.
讨论了顾客到达时间和服务时间与等待队列队长有关的排队系统模拟,顾客服务次数不止1次即出现循环的复杂排队系统,引入到达因子、服务台因子和循环因子,在串并联多服务台情形下建立了4类计算机模拟模型,给出该复杂循环排队系统在进程调度中的应用并进行了计算机模拟.  相似文献   
62.
乌桕类可可脂结晶过程中表现体积变化   总被引:1,自引:0,他引:1  
为了解乌桕类可可脂(CTCBE)缓冷结晶横向胀罐爆裂原因,研究CTCBE结晶过程中的膨胀特性,采用流体静力法测试了不同等温结晶条件下CTCBE结晶形成的表观密度和表观体积及其横纵向膨胀状况。结果表明,CTCBE缓冷结晶后形成外部和中部两个晶区。在5-25℃的各等温结晶范围内,当结晶温度增加时,外部结晶区域减小、表观密度变化不大;中部结晶区域增大、表观密度明显减小,CTCBE的表观体积、横向、纵向膨胀率均增大,膨胀横向大于纵向。进一步表明CTCBE在自然缓冷固化的表观体积根本上由其结晶温度决定。为有效防止横向胀罐,自然缓冷固化温度应低于10℃。  相似文献   
63.
阎世英  朱正和 《中国物理》2004,13(12):2053-2057
Density functional method (DFT) (B3p86) of Gaussian98 has been used to optimize the structure of the Tc_2 molecule. The result shows that the ground state for Tc_2 molecule is an 11-multiple state and its electronic configuration is {}^{11}Σ_g^-, which shows the spin polarization effect of Tc_2 molecule of a transition metal element for the first time. Meanwhile, we have not found any spin pollution because the wavefunction of the ground state does not mingle with wavefunctions of higher energy states. So, that the ground state for Tc_2 molecule is an 11-multiple state is indicative of the spin polarization effect of Tc_2 molecule of a transition metal element: that is, there exist 10 parallel spin electrons. The non-conjugated electron is greatest in number. These electrons occupy different spacious tracks, so that the energy of Tc_2 molecule is minimized. It can be concluded that the effect of parallel spin of the Tc_2 molecule is larger than the effect of the conjugated molecule, which is obviously related to the effect of electron d delocalization. In addition, the Murrell--Sorbie potential functions with the parameters for the ground state {}^{11}Σ_g^- and other states of Tc_2 molecule are derived. Dissociation energy D_e for the ground state of T_{c2} molecule is 2.266eV, equilibrium bond length R_e is 0.2841nm, vibration frequency ω_e is 178.52cm^{-1}. Its force constants f_2, f_3, and f_4 are 0.9200aJ·nm^{-2}, --3.5700aJ·nm^{-3}, 11.2748aJ·nm^{-4} respectively. The other spectroscopic data for the ground state of Tc_2 molecule ω_eχ_e, B_e, α_e are 0.5523cm^{-1}, 0.0426cm^{-1}, 1.6331×10^{-4}cm^{-1} respectively.  相似文献   
64.
The asymptotic behaviour of a Stokes flow with Tresca free boundary friction conditions when one dimension of the fluid domain tends to zero is studied. A specific Reynolds equation associated with variational inequalities is obtained and uniqueness is proved.  相似文献   
65.
Let {X_n, n≥1} be a strictly stationary sequence of random variables, whichare either associated or negatively associated, f(·) be their common density. In this paper,the author shows a central limit theorem for a kernel estimate of f(·) under certain regularconditions.  相似文献   
66.
变系数(2+1)维Broer-Kaup方程的精确解   总被引:19,自引:4,他引:15  
利用齐次平衡原则,导出了变系数(2+1)维Broer-Kaup方程的B?cklund变换(BT),并由该BT,求出了(2+1)维Broer-Kaup方程的各种形式的精确解.  相似文献   
67.
风力发电机组变速恒频控制系统研究   总被引:2,自引:0,他引:2  
全面介绍了一种最新应用于风力发电中的新型电机—无刷双馈电机,并分析了这种新型电机作变速恒频运行的原理并对这种电机进行了动态特性仿真研究,给出了形式简洁的控制方程和易于实现的控制方案。  相似文献   
68.
The reversible nonlinear conduction (RNC) in of high‐density polyethylene/acetylene carbon black composites with different degrees of crosslinking was studied above room temperature and below the melting point of high‐density polyethylene (HDPE). The experimental current density‐electric field strength curves can be overlapped onto a master curve, suggesting that the microscopic mechanisms for the appearance of RNC exist regardless of the ambient temperature and the crosslinking degree of the HDPE matrix. The relationship between the crossover current density and the linear conductivity can be explained in the framework of the dynamic random‐resistor‐network model. According to these results, two electron‐tunneling models are suggested to interpret the microscopic conduction behavior. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 1212–1217, 2004  相似文献   
69.
The desorption behavior of a surfactant in a linear low‐density polyethylene (LLDPE) blend at elevated temperatures of 50, 70, and 80 °C was studied with Fourier transform infrared spectroscopy. The composition of the LLDPE blend was 70:30 LLDPE/low‐density polyethylene. Three different specimens (II, III, and IV) were prepared with various compositions of a small molecular penetrant, sorbitan palmitate (SPAN‐40), and a migration controller, poly(ethylene acrylic acid) (EAA), in the LLDPE blend. The calculated diffusion coefficient (D) of SPAN‐40 in specimens II, III, and IV, between 50 and 80 °C, varied from 1.74 × 10?11 to 6.79 × 10?11 cm2/s, from 1.10 × 10?11 to 5.75 × 10?11 cm2/s, and from 0.58 × 10?11 to 4.75 × 10?11 cm2/s, respectively. In addition, the calculated activation energies (ED) of specimens II, III, and IV, from the plotting of ln D versus 1/T between 50 and 80 °C, were 42.9, 52.7, and 65.6 kJ/mol, respectively. These values were different from those obtained between 25 and 50 °C and were believed to have been influenced by the interference of Tinuvin (a UV stabilizer) at elevated temperatures higher than 50 °C. Although the desorption rate of SPAN‐40 increased with the temperature and decreased with the EAA content, the observed spectral behavior did not depend on the temperature and time. For all specimens stored over 50 °C, the peak at 1739 cm?1 decreased in a few days and subsequently increased with a peak shift toward 1730 cm?1. This arose from the carbonyl stretching vibration of Tinuvin, possibly because of oxidation or degradation at elevated temperatures. In addition, the incorporation of EAA into the LLDPE blend suppressed the desorption rate of SPAN‐40 and retarded the appearance of the 1730 cm?1 peak. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 1114–1126, 2004  相似文献   
70.
The effect of the triblock copolymer poly[styrene‐b‐(ethylene‐co‐butylene)‐b‐styrene] (SEBS) on the formation of the space charge of immiscible low‐density polyethylene (LDPE)/polystyrene (PS) blends was investigated. Blends of 70/30 (wt %) LDPE/PS were prepared through melt blending in an internal mixer at a blend temperature of 220 °C. The amount of charge that accumulated in the 70% LDPE/30% PS blends decreased when the SEBS content increased up to 10 wt %. For compatibilized and uncompatibilized blends, no significant change in the degree of crystallinity of LDPE in the blends was observed, and so the effect of crystallization on the space charge distribution could be excluded. Morphological observations showed that the addition of SEBS resulted in a domain size reduction of the dispersed PS phase and better interfacial adhesion between the LDPE and PS phases. The location of SEBS at a domain interface enabled charges to migrate from one phase to the other via the domain interface and, therefore, resulted in a significant decrease in the amount of space charge for the LDPE/PS blends with SEBS. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 2813–2820, 2004  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号