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61.
The photophysical characteristics and photochemical conversions of 5,10,15,20-tetrakis-(4-N-methylpyridyl)porphyrin in a highly polar solvent, formamide, are investigated. It has been established that no photochemical reactions occur on excitation in the visible spectral region, while UV excitation ( = 347 nm) causes photoreduction of porphyrin molecules followed by the formation of protonated products. The solvent molecules serve as a reducing agent. Photoreduction occurs in both air-saturated and deoxygenated solutions, but the nature of the products formed is different: chlorin molecules are formed in the air-saturated solutions and the successive photoconversion porphyrinphlorinporphometheneporphyrinogene occurs in the deoxygenated solutions. 相似文献
62.
Four kinds of surfactants, sodium laurate, sodium myristate, sodium palmitate and sodium oleate were used to study the effects of surfactant coatings on the lifetime and attenuation of microbubbles. The changes in the size distribution of microbubbles prepared with these surfactants in saline were measured with a Coulter Multisizer (Coulter Electronics Ltd., Luton, UK). Frequency characteristics of ultrasonic attenuation of the microbubble suspensions were measured between 400 kHz and 6 MHz. From the changes in attenuation in the microbubble suspensions over time, it was found that the lifetime of microbubbles in a suspension also depends on the frequency of the irradiating ultrasound. The effect of surfactants on the frequency characteristics of attenuation was also studied, and characteristics of the surfactant coating, including shell elasticity and shell friction parameters were calculated from the measurement results. Microbubbles produced with sodium palmitate had the longest lifetime and the smallest average size. The shell had very little effect on the ultrasonic properties of microbubbles produced with sodium palmitate, suggesting that the sodium palmitate microbubbles behaved ultrasonically as free microbubbles. 相似文献
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利用渗流技术制备出了以石墨颗粒为阻尼增强相、以Cu-11.9Al-2.5Mn(wt%)形状记忆合金为基体的复合材料,对该合金的内耗行为进行了研究. 在淬火态样品的内耗-温度曲线上观察到两个内耗峰,分别位于240 ℃和370 ℃附近. 对其中低温峰的变化规律和机理进行了研究. 实验发现,低温峰仅在复合材料中出现,峰位与频率无关,峰高随频率升高而上升;随升温速率增加,峰高增加,峰位移向高温;随石墨颗粒体积分数增加,峰高增加;经多次热循环后该内耗峰消失. 由以上特征和微观观察,可以证明该峰起因于外加交变应力与位错的相互作用. 相似文献
66.
We consider the dissipative nonlinear dynamics of a model of interacting atoms driven over a substrate potential. The substrate parameters can be suitably tuned in order to introduce disorder effects starting from two geometrically opposed ideal cases: commensurate and incommensurate interfaces. The role of temperature is also investigated through the inclusion of a stochastic force via a Langevin molecular dynamics approach. Here, we focus on the most interesting tribological case of underdamped sliding dynamics. For different values of the chain stiffness, we evaluate the static friction threshold and consider the depinning transition mechanisms as a function of the applied driving force. As experimentally observed in QCM frictional measurements of adsorbed layers, we find that disorder operates differently depending on the starting geometrical configuration. For commensurate interfaces, randomness lowers considerably the chain depinning threshold. On the contrary, for incommensurate mating contacts, disorder favors static pinning destroying the possible frictionless (superlubric) sliding states. Interestingly, thermal and disorder effects strongly influence also the occurrence of parametric resonances inside the chain, capable of converting the kinetic energy of the center-of-mass motion into internal vibrational excitations. We comment on the nature of the different dynamical states and hysteresis (due to system bi-stability) observed at different increasing and decreasing strengths of the external force. 相似文献
67.
Jet impingement onto a hole with elevated wall temperature can be associated with the high‐temperature thermal drilling, where the gas jet is used for shielding the hole wall from the high‐temperature oxidation reactions as observed in the case of laser drilling. In laser processing, the molten flow from the hole wall occurs; and in the model study, the hole wall velocity resembling the molten flow should be accounted for. In the present study, gas jet impingement onto tapered hole with elevated temperature is considered and the heat transfer rates as well as skin friction at the hole wall surface are predicted. The velocity of molten flow from the hole wall determined from the previous study is adopted in the simulations and the effect of hole wall velocity on the heat transfer rates and skin friction is also examined. It is found that the Nusselt number and skin friction at the hole wall in the regions of hole inlet and exit attain high values. The influence of hole wall velocity on the Nusselt number and skin friction is found not to be very significant. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
68.
测量和减小纳米凹凸面摩擦力的分子新技术 总被引:1,自引:1,他引:0
报道了美国用原子力显微镜可直接检测超微型设备内发动机转子与外表表面上凸点之间摩擦力的大小的研究成果,介绍了降低了时机的摩擦力的方法。 相似文献
69.
Ioan R. Ionescu Darko Volkov 《Journal of Computational and Applied Mathematics》2008,220(1-2):143-162
We study in this paper an eigenvalue problem (of Steklov type), modeling slow slip events (such as silent earthquakes, or earthquake nucleation phases) occurring on geological faults. We focus here on a half space formulation with traction free boundary condition: this simulates the earth surface where displacements take place and can be picked up by GPS measurements. We construct an appropriate functional framework attached to a formulation suitable for the half space setting. We perform an asymptotic analysis of the solution with respect to the depth of the fault. Starting from an integral representation for the displacement field, we prove that the differences between the eigenvalues and eigenfunctions attached to the half space problem and those attached to the free space problem, is of the order of d-2, where d is a depth parameter: intuitively, this was expected as this is also the order of decay of the derivative of the Green's function for our problem. We actually prove faster decay in case of symmetric faults. For all faults, we rigorously obtain a very useful asymptotic formula for the surface displacement, whose dominant part involves a so called seismic moment. We also provide results pertaining to the analysis of the multiplicity of the first eigenvalue in the line segment fault case. Finally we explain how we derived our numerical method for solving for dislocations on faults in the half plane. It involves integral equations combining regular and Hadamard's hypersingular integration kernels. 相似文献
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