增韧环氧树脂的动态裂纹扩展研究

本文主要进行了环氧及增韧环氧树脂的断裂韧性及裂纹快速扩展的试验研究。试验过程中采用了ＧＬＣ－１型高速裂纹扩展测试仪来测试裂纹的扩展速度,得到在裂纹扩展过程中裂纹扩展速度曲线。本文结合不同的计算公式及有限元分析方法,讨论了各个确定断裂韧性公式的准确程度,发现传统的静态断裂韧性的分析方法所得到的结果偏大,有一定的危险性,建议使用试验与数值计算相结合的方法;同时还发现增韧不仅可以提高材料的静态和动态断裂性能,而且在裂纹扩展过程中可以起到减缓裂纹扩展的作用     

法向载荷和滑动速度对GCr15钢干滑动摩擦的影响

本文研究了在干滑动摩擦情况下,GCr15钢与YG8硬质合金对磨时的摩擦系数与法向载荷及滑动速度的关系。结果表明,摩擦系数是随着法向载荷和滑动速度的增加而降低。根据磨损表面发生的变化和磨损表面温度计算,作者认为法向载荷和滑动速度的增加使闪温增高,从而导致了摩擦磨损表面的局部熔化,即形成了边界润滑,故此摩擦系数降低,而且在较高的载荷和滑动速度条件下,不同显微组织材料的摩擦系数之差减小。     

Rotating bunsen flames as solutions of the Kuramoto-Sivashinsky equation

Steadily rotating solutions of the Kuramoto-Sivashinsky equationu _t + ² u++¦u¦ ² =c ² are studied. These solutions bifurcate from the steady radial solution of the above equation. For large values ofc and angular velocities such thatN¦¦<2c<(N+1)¦¦, we show that there exists a 2N-1 family of bifurcating solutions. The proof is based on a certain generic transversality assumption. A computer-assisted proof of this assumption is given for 1N10.     

Enzymatic transformation of platycosides and one‐step separation of platycodin D by high‐speed countercurrent chromatography

Platycosides, the saponins found in the roots of Platycodon grandiflorum (Platycodi Radix), are typically composed of oleanane triterpenes with two side chains. In platycosides, platycodin D, a glucose unit at C‐3, is a major component, which has several pharmacological activities. Because of the high demand for this compound, we attempted to enzymatically convert platycodin D₃ and platycoside E, having two and three glucose units at C‐3, respectively, into platycodin D. In this study, we tested the ability of several glycosidases to transform platycosides, or more specifically, the ability to transform platycoside E and platycodin D₃ into platycodin D. To obtain pure platycodin D on a preparative scale, high‐speed countercurrent chromatography with a solvent system of ethyl acetate/n‐butanol/water (1.2:1:2, v/v/v) was used for the separation of the enzymatically transformed product. Approximately 39.4 mg of platycodin D (99.8% purity) was obtained from 200 mg of the product in a one‐step separation. The results strongly support the advantage of enzymatic transformation of the platycosides for the efficient enrichment of platycodin D in the complicated extract of the medicinal plant.     

Efficient isolation and purification of five products from microbial biotransformation of cinobufagin by high‐speed counter‐current chromatography

An efficient separation method of using high‐speed counter‐current chromatography was successfully established to directly purify cytotoxic transformed products of cinobufagin by Cordyceps militaris. The two‐phase solvent system composed of n‐hexane–ethyl acetate–methanol–water (4:6:3:4, v/v) was used in high‐speed counter‐current chromatography. A total of 9 mg of 4β,12α‐dihydroxyl‐cinobufagin ( 1 ), 15 mg of 12β‐hydroxyl‐cinobufagin ( 2 ), 8 mg of 5β‐hydroxyl‐cinobufagin ( 3 ), 12 mg of deacetylcinobufagin ( 4 ) and 6 mg of 3‐keto‐cinobufagin ( 5 ) were obtained in a one‐step separation from 400 mg of the crude extract with purity of 98.7, 97.2, 90.6, 99.1 and 99.4%, respectively, as determined by HPLC. Their chemical structures were identified on the basis of ¹H‐NMR and ¹³C‐NMR technology. All products ( 1 – 5 ) showed the potent activities against human carcinoma cervicis (Hela) and malignant melanoma (A375) cells in vitro.     

Preparation of Ga-doped ZnO films by pulsed dc magnetron sputtering with cylindrical rotating target for thin film solar cell applications

Applicability of Ga-doped ZnO (GZO) films for thin film solar cells (TFSCs) was investigated by preparing GZO films via pulsed dc magnetron sputtering (PDMS) with rotating target. The GZO films showed improved crystallinity and increasing degree of Ga doping with increasing thickness to a limit of 1000 nm. The films also fulfilled requirements for the transparent electrodes of TFSCs in terms of electrical and optical properties. Moreover, the films exhibited good texturing potential based on etching studies with diluted HCl, which yielded an improved light trapping capability without significant degradation in electrical propreties. It is therefore suggested that the surface-textured GZO films prepared via PDMS and etching are promising candidates for indium-free transparent electrodes for TFSCs.     

对冲火焰流场的二维分布对层流火焰传播速度测量的影响

在φ=0.6～0.75的条件下,利用PⅣ测得对冲火焰的二维速度场,分析使用偏移中心线一定距离提取的轴线速度分布曲线所得到的层流火焰传播速度SOL与沿中心线提取的速度分布曲线得到的SOL之间的误差大小.实验结果表明,在弱火焰时对冲火焰速度场具有明显的二维效应.φ=0.6,偏离中心轴线5 mm时,相对误差达到33%;而φ=...     

风场影响下直接空冷系统热风回流率的空间分布特性

环境风场影响下,电站直接空冷系统热风回流加剧,传热性能恶化。掌握风场作用下直接空冷系统热风回流率的空间分布特性,可为空冷系统的设计和运行提供理论依据。以典型2×600 MW直接空冷电站为例,通过数值模拟获得了冷却空气流场和温度场,分别计算了空冷岛和各个空冷单元的热风回流率。计算结果表明,随环境风速增加,空冷岛热风回流率升高,并随风向发生显著变化,炉后来风时空冷岛热风回流最为严重。空冷单元热风回流率呈现空间分布特性,风场不同区域空冷单元热风回流存在显著差异,处于风场上游空冷单元通常具有更大的热风回流率。     

用脉冲光声法测量固体介质中声速

提出了一种利用脉冲光声技术测量固体介质中声速的方法,建立了由YAG激光器和超声探测器组成的实验系统,脉冲激光在固体表面产生脉冲超声波,通过测量脉冲声波在固体内多次反射后的出射信号及固体的厚度,即可算出固体介质中的声速.对黄铜及铝的测量结果表明,这是一种准确性较高的固体介质中声速测量方法.该测量方法可作为综合设计性物理实...