一种简易的光纤光栅涂覆装置

阐述了对裸光纤光栅进行涂覆的原理和必要性。设计了一种简易可行的光纤光栅涂覆装置。该装置简单灵活,成本较低,尤其适合于长度较长的光纤光栅的一次性涂覆,涂层厚度灵活可调。以啁啾光纤光栅为例进行了涂覆实验,涂层光滑均匀,涂覆后的光栅强度得到了增强,抵抗机械应力的能力得到了提高,使用起来更方便。对光栅在涂覆前后分别作了特性参数测试。结果表明,光栅特性基本上不发生变化,性能未劣化,光纤光栅的涂覆简单易行。     

Electrochemical Sensing Platform Integrated with Solid-state Reference Electrode Based on Indium Tin Oxide Interdigitated Array Electrodes

We present a new strategy for the fabrication of a fully integrated electrochemical platform. The three-electrode system consists of an indium tin oxide interdigitated array as working electrode, a solid-state reference electrode, and an electrodeposited Pt counter electrode that are placed in microfluidic channel. By controlling the electrodeposition conditions, such as the applied potential and time, the stability and uniformity of the films can be optimized. A solid-state reference electrode was fabricated on the nanoporous Pt via electropolymerization of poly-1,3-phenylenediamine. This system provides a simple method for the fabrication of three-electrode system and opens the possibility for an electroanalytical platform.     

Organocatalytic Upgrading of Biomass Derived Building Blocks

The depletion of finite primary fossil fuels we are facing makes necessary a deep metamorphosis in fundamental parts of the chemical industry. A progressive transition from petro-based starting materials toward renewable biomass-derived sources will have to take place in the synthesis of added-value chemicals, important for our everyday life, such as pharmaceuticals, polymers, agrochemicals etc. Moreover, greener processes, carried out under friendlier reaction conditions, must be designed to address current concerns about the climate change and the resulting pressing need to reduce the environmental footprint of chemical processes. To this end, organocatalysis could offer a valuable opportunity for upgrading biomass-derived platform molecules in line with the principles of Green Chemistry. This review presents some of recent and remarkable advancements in this emerging area. Organocatalysis has proven to be an efficient tool to transform low value bio-based renewable platform building blocks into new high value bio-based chemicals, with potential applications as synthetic intermediates, innovative materials and pharmaceutically active compounds.