复杂应力状态镍基单晶合金低周疲劳损伤模型

根据连续介质损伤力学理论,采用应变能释放率作为热力学广义力描述正交异性材料的疲劳损伤过程,引入取向函数考虑镍基单晶合金晶体取向对疲劳损伤的非线性影响,提出了一个各向异性疲劳损伤模型。应用多元线性回归分析方法,拟合疲劳试验数据可确定模型参数。从应变能释放率的应变空间表达式出发,导出了含有3个弹性常数的单晶合金应变三轴性因子,它既反映了材料性能的晶体取向相关性,又反映了正应力和剪应力的相互作用,并可退化为各向同性材料的应变三轴性因子。利用该模型对CMSX-2镍基单晶合金在应力控制对称循环拉-扭载荷作用下的低周疲劳寿命进行预测,预测值与试验值吻合的相当好,试验所得数据均落在2.2倍偏差的分布带内。     

电感耦合等离子体发射光谱(ICP-OES)法测定镍基/钴基高温合金中硼磷硅

采用一定比例的混合酸溶解样品,利用基体匹配配制一系列标准溶液消除基体的影响,以及轴向观测喷嘴吹扫技术来提高待测元素的灵敏度,使用电感耦合等离子体发射光谱(ICP-OES)法测定镍基/钴基高温合金中硼磷硅。各元素选的分析线依次为B 182.577 nm、P 178.222 nm、Si 185.005 nm。检测范围分别是:B 0.001%~3.0%,P 0.003%~0.20%,Si 0.005%~3.0%,检出限范围为0.00005%~0.0004%,线性相关系数>0.9995。加标回收率为90.0%~105%,精密度RSD<2.0%。方法操作简单快速,结果令人满意。     

乙酸自热重整制氢用类水滑石衍生Zn-Ni-Al-Fe-O催化剂研究

采用共沉淀法制备了Zn_(2.4)Ni_(0.6)Al_xFe_(1-x)O_(4.5±δ)(x=1/0.5/0)系列类水滑石型镍基催化剂,用于乙酸自热重整制氢,并利用XRD、H_2-TPR、BET、XPS等表征手段对催化剂进行了表征。结果表明,Zn_(2.4)Ni_(0.6)Al_(0.5)Fe_(0.5)O_(4.5±δ)催化剂在乙酸自热重整中乙酸转化率维持在100%,氢气产率为2.39 mol-H_2/mol-HAc。Zn-Al水滑石前驱体经焙烧后形成了ZnO为骨架的复合氧化物,铁的适量添加增大了催化剂的比表面积,经还原后形成Fe NiZn合金,Fe以及Zn的给电子作用提高了Ni的抗氧化能力,催化剂的抗氧化烧结和抗积炭能力得到提高。     

电感耦合等离子体发射光谱法检测镍基/钴基高温合金中硼磷硅

采用一定比例的混合酸溶解样品,利用基体匹配配制一系列标液消除基体的影响,以及轴向观测喷嘴吹扫技术来提高待测元素的灵敏度,使用电感耦合等离子体发射光谱(ICP-OES)测定镍基/钴基高温合金中硼磷硅。各元素选的分析线依次为B 182.577 nm、P 178.222 nm、Si 185.005 nm。检测范围分别是：B：0.001%-3.0%,P：0.003%-0.20%,Si：0.005%-3.0%,检出限范围是0.00005%-0.0004%,线性相关系数>0.9995。加标回收率为90.0%-105.0%,精密度RSD<2.0%。该方法操作简单快速,结果令人满意。     

TEMPERATURE EFFECT ON LOW-CYCLE FATIGUE BEHAVIOR OF NICKEL-BASED SINGLE CRYSTALLINE SUPERALLOY

The low-cycle fatigue （LCF） behavior of a nickel-based single crystal superalloy with [001] orientation was studied at an intermediate temperature of T0℃ and a higher temperature of To ＋ 250℃ under a constant low strain rate of 10^-3 s^-1 in ambient atmosphere. The superalloy exhibited cyclic tension-compression asymmetry which is dependent on the temperature and applied strain amplitude. Analysis on the fracture surfaces showed that the surface and subsurface casting micropores were the major crack initiation sites. Interior Ta-rich carbides were frequently observed in all specimens. Two distinct types of fracture were suggested by fractogaphy. One type was characterized by Mode-I cracking with a microscopically rough surface at To ＋ 250℃. Whereas the other type at lower temperature T0℃ favored either one or several of the octahedral {111} planes, in contrast to the normal Mode-I growth mode typically observed at low loading frequencies （several Hz）. The failure mechanisms for two cracking modes are shearing of γ＇ precipitates together with the matrix at T0℃ and cracking confined in the matrix and the γ/γ＇interface at To - 250℃.     

热、机械载荷作用下夹杂对应力强度因子的影响

推导了远场应力、热应力耦合作用下含夹杂裂纹体的应力强度因子求解公式,改进了体积力法中的裂纹面合力平衡条件,将应力强度因子的求解归结为解一组积分方程,再将积分方程转化为线性方程组进行数值求解。算例分析结果表明方法正确、有效。将该算法应用于含Al2O3夹杂的FGH95材料应力强度因子分析中,计算结果表明热应力对应力强度因子影响很小。     

INFLUENCE OF SOL-GEL METHOD ON CATALYTIC PERFORMANCE OF PARTIAL OXIDATION OF METHANE TO SYNCES OAR NiO/|?-Al2O3 CATALYSTS

NiO/r-A12O3 catalysts were prepared by impregnation and sol-gel method. Comparative study of the POM catalytic performance for 80 h life-test over them was performed to investigate the effects of the preparation methods. The carbon deposition, surface composition, total nickel content, specific surface area, pore volume and crystal phase of catalysts were investigated with TG, XPS, AAS, TPR, BET, and XRD. The results indicated that the thermal stability of support during the redox reaction at high temperature could not be improved only by sol-gel method.     

一种镍基单晶超合金高温低周疲劳的晶体取向相关性模型

在950℃t对[001]、[012]、[112]、[011]和[114]晶体取向的镍基单晶超合金DD3试样进行了对称循环低周疲劳(ICF)试验。应变率取1.0×10-2,1.33×10-3,0.33×10-3s-1.试验结果表明,LCF特性显着地取决于晶体取向和应变率。试样断口细观分析表明,除了[001]取向试样外,其余所有试样断口上均有明显的等间距疲劳纹。这些疲劳纹由微裂纹组成,其间距取决于试样的晶体取向和总应变范围。基于晶体滑移理论,建立了疲劳纹间距和总分切应变范围及取向和应变率函数的一个简单关系。对Lall-Chin-Pope(LCP)模型进行修正并推广应用于循环塑性和疲劳寿命研究,提出了一个晶体取向和应变率参数,该参数可以很好地描述镍基单晶超合金高温低周疲劳循环塑性和疲劳寿命的晶体取向和应变率相关性。     

镍基定向结晶合金蠕变损伤的细观模型

针对镍基定向结晶合金的蠕变变形和损伤,本文建立了有限元和自洽两种晶体滑移细观模型。在这两种模型中同时考虑了晶粒滑移损伤和晶界损伤。通过一组镍基单晶合金和一组特殊结晶取向的定向结晶合金标定了模型参数。数值分析结果表明,这两种模型都可以比较准确地描述定向结晶合金的蠕变损伤变形和失效规律,尤其是定向结晶合金蠕变性能的结晶取向相关性。     

甲烷部分氧化制合成气NiO/γ-Al2O3催化剂的失活研究:溶胶-凝胶法对催化性能的影响

The nickel-based catalyst used in partial oxidation of methane(POM)to syngas emerged as the most practical one because of the high turnover rate and inexpensive cost.However,nickel-based catalyst supported on γ-Al2O3 is usually unstable at high temperature owing either to carbon deposition[1],the loss and sintering of nickel[2] or to phase transformation.