首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   37501篇
  免费   3535篇
  国内免费   3946篇
化学   26768篇
晶体学   496篇
力学   4889篇
综合类   246篇
数学   3562篇
物理学   9021篇
  2024年   44篇
  2023年   354篇
  2022年   648篇
  2021年   953篇
  2020年   1172篇
  2019年   1162篇
  2018年   998篇
  2017年   1262篇
  2016年   1520篇
  2015年   1392篇
  2014年   1607篇
  2013年   2513篇
  2012年   1980篇
  2011年   2356篇
  2010年   1862篇
  2009年   2455篇
  2008年   2224篇
  2007年   2291篇
  2006年   2095篇
  2005年   1954篇
  2004年   1980篇
  2003年   1591篇
  2002年   1805篇
  2001年   1095篇
  2000年   918篇
  1999年   734篇
  1998年   711篇
  1997年   599篇
  1996年   595篇
  1995年   605篇
  1994年   543篇
  1993年   395篇
  1992年   381篇
  1991年   239篇
  1990年   185篇
  1989年   198篇
  1988年   194篇
  1987年   154篇
  1986年   113篇
  1985年   96篇
  1984年   95篇
  1983年   37篇
  1982年   91篇
  1981年   114篇
  1980年   121篇
  1979年   137篇
  1978年   102篇
  1977年   82篇
  1976年   72篇
  1973年   40篇
排序方式: 共有10000条查询结果,搜索用时 46 毫秒
111.
We report on a new type of Fano effect, named as Andreev-Fano effect, in a hybrid normal-metal/supeeconductor (N/S) interferometer embedded with a quantum dot. Compared with the conventional Fano effect, AndreevFano effect has some new features related to the characteristics of Andreev reflection. In the Iinear response regime, the line shape is the square of the conventional Fano shape, while in the nonlinear transport, a sharp resonant structure is superposed on an expanded interference pattern, which is qualitatively different from the conventional Fano effect. The phase dependence of the hybrid N/S interferometer is also distinguished from those of all-N or all-S interferometers.  相似文献   
112.
A tin(IV) porphyrin was combined with two axial NCN‐pincer platinum(II) fragments by utilizing the oxophilicity of the apical positions on the tin atom and the acidic nature of the NCN‐pincer platinum derived benzoic acid. The solid‐state structure determined by X‐ray crystallography revealed some close contacts between the pincer complexes and the mesop‐tolyl subsitutents of the porphyrin. It was shown by 1H NMR spectroscopy that these close contacts were not present in solution and that this compound can potentially act as a novel building block for supramolecular architectures.  相似文献   
113.
We consider the isothermal flow through a cylindrical flat chamber, a model of some particular heat exchanger, for which LDV measurements and a numerical simulation have been performed. Experimental results show the establishment of an important vortex zone, the secondary flow extending all along the chamber radius. This observation leads to an expected significant increase of the fluid mixing. Results issued from the numerical simulation appear to be in close agreement with experimental data. Nevertheless, the kε model used here must be improved to obtain a better approach near the vortex centre. To cite this article: S. Petitot et al., C. R. Mecanique 330 (2002) 593–599.  相似文献   
114.
Pentacyclic isoxazolines were obtained by the cycloaddition of benzonitrile oxide to norbornene-azetidinone-fused 3,1-oxazines. The constitutions of two of the isomers obtained, and the configurations and conformations of all products, were determined by means of 1H and 13C NMR spectroscopy and DNOE experiments.  相似文献   
115.
116.
Morphological and chemical properties of both the surface and interface of poly(vinylidene fluoride)/poly(methyl methacrylate)-co-poly(ethyl acrylate) (PVDF/PMMA-co-PEA) blend films have been investigated before and after the samples were exposed to ultraviolet (UV) irradiation using a xenon arc lamp at 50 °C and 9% relative humidity (RH) for 7 months. Surface and interfacial morphologies were studied by atomic force microscopy (AFM). Chemical composition information was obtained by confocal Raman microscopy, attenuated total reflection-FTIR spectroscopy (ATR-FTIR), X-ray photoelectron spectroscopy (XPS), and contact angle measurements. Results show an enrichment of the PVDF material at the air surface, while the acrylic copolymer enriches the interface. Blends having greater than 50% mass fraction of PVDF show little change in the surface morphology after UV exposure for 7 months. However, for a lower PVDF content, blends exhibit significant degradation of PMMA-co-PEA copolymer and a much rougher surface after UV exposure. Microstructural changes in the PVDF spherulites are also observed after UV degradation. It is found that the surface and interfacial morphologies are correlated with the chemical properties.  相似文献   
117.
Rüffer  R. 《Hyperfine Interactions》2002,141(1-4):83-97
Hyperfine Interactions - The technique of nuclear resonant scattering has spread out in various fields during the previous years. Those fields, which have rapidly developed and attracted the...  相似文献   
118.
刘喆  唐喆  崔得良  徐现刚 《物理》2002,31(5):306-309
异质结晶体三极管(HBT)的性能与其材料体系密不可分,利用能带工程可以大大优化器件的结构,提高器件性能,文章从分析HBT的能带结构及设计要求入手,介绍了一种利用能带工程设计的基于GaAsSb/InP材料体系的新型HBT器件的结构及其性能,分析了该器件与其它材料体系器件相比所具有的优异特性,说明了对HBT的各区材料,其带边的相对位置所起的重要作用,最后,文章还报道了近期的实验情况,说明了GaAsSb/InP体系HBT的实际性能与理论预言一致。  相似文献   
119.
1 Introduction  Inrecentyears,boththetheoreticalandexperimentalinvestigationsonlasercoolingandtrappinghavebecomeoneofthemajorfieldsinatomic,molecularandoptical physics[1~ 8] .Thedevelopmentoflasercoolingandtrappingtechnologyisimportantfortheapplicationssu…  相似文献   
120.
The effect of SiO2 in SiCp and the following processing parameters on the microstructure and impact strength of Al/SiCp composites fabricated by pressureless infiltration was investigated: Mg content in the aluminum alloy, SiC particle size, and holding time. Preforms of SiCp in the form of rectangular bars (10 × 1 × 1 cm) were infiltrated at 1150°C in an argon→nitrogen atmosphere for 45 and 60 min by utilizing two aluminum alloys (Al-6 Mg-11 Si and Al-9 Mg-11 Si, wt.%). The results obtained show that the presence of SiO2 in SiC affects the microstructure and impact strength of the composites significantly. When Al4C3 is formed, the impact strength decreases. However, a high proportion of SiC to SiO2 limits the formation of the unwanted Al4C3 phase in the composites. Also, a higher content of Mg in the Al alloy lowers the residual porosity and, consequently, increases the composite strength. The impact strength grows with decrease in SiC particle size and increases considerably when the residual porosity is less than 1%. Russian translation published in Mekhanika Kompozitnykh Materialov, Vol. 42, No. 3, pp. 401–418, May–June, 2006.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号