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941.
Two Cd(Ⅱ) complexes, Cd2L2Cl2 (1) and Cd2L2(NCS)2 (2) (HL = N-(3-methoxylsalicylidene)-3-dimethylaminopropylamine) were synthesized and determined by EA, IR, TG and single-crystal X-ray diffraction. The crystallographic data are as follows: monoclinic, space group P21/n, a = 9.2710(9), b = 18.0069(18), c = 18.5562(19) A^°, β= 99.741(4)°, V = 3053.1(5), Z = 4,μ = 1.605, F(000) = 1536, R = 0.0264 and wR = 0.0699 for 1; orthorhombic, space group Pca21, a = 16.196(3), b = 11.506(2), c = 36.126(7) A^°, V = 6732(2), Z = 8,μ = 1.428, F(000) = 3264, R = 0.0376 and wR = 0.0877 for 2. There are two geometrically different octahedral Cd(Ⅱ) atoms, with N4O2 and O4Cl2 donor sets for 1 while N4O2 and N2O4 for 2. In the dinuclear Cd(Ⅱ) centers, the Cd(Ⅱ) atoms are held together by two deprotonted phenolate oxygen atoms from tetradentate L^- ligands. The thermal gravity data show two step decompositions with the residues of CdO for two complexes. 相似文献
942.
基于灰色关联分析的财产保险公司偿付能力的模糊综合评判 总被引:2,自引:0,他引:2
为解决财产保险公司的偿付能力的评价问题,建立了基于灰色关联分析的模糊综合评判模型.选取了2003-2005年我国8家财产保险公司的相关数据,用灰色关联分析中的点关联系数求解隶属度得出评判矩阵,用范数灰关联度法确定因素集中各因素的权重,从而对其偿付能力进行模糊综合评判,得出各公司的偿付能力所属的类别.并对评语集中各评语赋予适当的权重,对所研究的8家财产保险公司依据其偿付能力的情况进行了排序. 相似文献
943.
Wenbo Li Yubo Cao Hui Cao Miki Kashima Lingjie Kong Huai Yang 《Journal of Polymer Science.Polymer Physics》2008,46(13):1369-1375
Polymer dispersed liquid crystal (PDLC) films were prepared by photopolymerization of liquid crystal (LC)/polymerizable monomers/photoinitiator composites. The effects of the structures of the polymerizable monomers on the electro‐optical properties of PDLC films were investigated. It was found that the length of the molecular chain and the rigidity and flexibility of molecules influenced the structure of the polymer network in the PDLC films somewhat, and then affected the electro‐optical properties of the composites accordingly. © 2008 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 46: 1369–1375, 2008 相似文献
944.
945.
二阶非线性泛函微分方程的振动性质 总被引:1,自引:0,他引:1
研究了一类二阶非线性泛函微分方程解的振动性质.在一定条件下,应用分类讨论和分析的方法,建立了一个新的振动性定理,推广和改进了已知的结果. 相似文献
946.
The physical picture of coexistence of both hadronic and QGP phases is given by Friedberg and T.D. Lee‘s nontopology soliton model. The transport properties of quark in color space and spin space in a system of two-phase coexistence are investigated from both quantum and classical theories. 相似文献
947.
948.
Nathan Ravi Arpita Mitra Paul Hamilton Ferenc Horkay 《Journal of Polymer Science.Polymer Physics》2002,40(23):2677-2684
The characteristics of poly(ethylene glycol) (PEG)–acrylate hydrogel networks were investigated as a function of the ethanol–water solvent composition during free‐radical crosslinking copolymerization. Macromonomer (88% ω‐methoxy‐PEG–acrylate and 10% ω‐phenoxy‐PEG–acrylate) and crosslinker (2% PEG–diacrylate) concentrations were kept constant. As the copolymerization progressed, the polymer solution in 100% ethanol became increasingly turbid, indicating the development of a heterogeneous network structure. In 100% water, however, the initially turbid polymer solution became increasingly transparent as the crosslinking copolymerization progressed. All the gels were optically clear upon equilibration in water. Kinetic studies, with attenuated total reflectance‐infrared, showed a long induction period, along with a lowered reaction rate, in 100% ethanol, and a decrease in conversion with an increase in ethanol content. These results agree with the UV analysis of the sol fractions, which indicated an increase in the amounts of unreacted PEG–acrylates with an increase in the ethanol content. The gels which were formed with a high ethanol concentration exhibited lower Young's modulus and higher swelling ability, suggesting that the network structure was significantly affected by the solvent composition during free‐radical crosslinking copolymerization. From the stress–strain and swelling experiments, the Flory–Huggins interaction parameter was evaluated. The creep characteristics of the hydrogels were modeled with two Kelvin elements. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 40: 2677–2684, 2002 相似文献
949.
A model relating the translational and rotational transport of orientation distribution function (ODF) of fibers to the gradient of mean ODF and the dispersion coefficients is proposed to derive the mean equation for the ODE Then the ODF of fibers is predicted by numerically solving the mean equation for the ODF together with the equations of turbulent boundary layer flow. Finally the shear stress and first normal stress difference of fiber suspensions are obtained. The results, some of which agree with the available relevant experimental data, show that the most fibers tend to orient to the flow direction. The fiber aspect ratio and Reynolds number have significant and negligible effects on the orientation dis- tribution of fibers, respectively. The additional normal stress due to the presence of fibers is anisotropic. The shear stress of fiber suspension is larger than that of Newtonian solvent, and the first normal stress difference is much less than the shear stress. Both the additional shear stress and the first normal stress difference increase with increasing the fiber concentration and decreasing fiber aspect ratio. 相似文献
950.
Li Hong Xiao Cheng Liu Xi Gao Jian 《中国化学快报》2008,19(2):227-229
A novel series of poly(aryl ether sulfone ketone)s (PPESKs) containing phthalazinone and biphenyl moieties were prepared by two-step nucleophilic polycondensation reaction. The ^-Mw values of these copolymers were between 38,330 and 67,900. The glass transition temperatures (Tg) and 5% decomposition temperatures were ranged in 253-269 ℃ and 488-500 ℃, respectively, The structures of these copolymers were confirmed by FT-IR and ^1H NMR. Moreover, all the resultant copolymers were amorphous determined by wide angle X-ray diffraction (WAXD). 相似文献