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991.
Hongjie Xu Kangcheng Chen Xiaoxia Guo Jianhua Fang Jie Yin 《Journal of polymer science. Part A, Polymer chemistry》2007,45(6):1150-1158
Hyperbranched polybenzimidazoles (HBPBIs) were successfully synthesized by condensation polymerization of 1,3,5‐benzenetricarboxylic acid (BTA) and 3,3′‐diaminobenzidine (DAB) in polyphosphoric acid (PPA) at 190 °C. Different monomer addition manners and molar ratios resulted in different polymers, that is, simultaneous addition of BTA and DAB with the molar ratio of 1:1 (manner 1) gave carboxyl‐terminated HBPBI (HBPBI‐1), whereas the addition of BTA portion‐wise to DAB solution in PPA with the molar ratio of DAB:BTA = 2:1 (manner 2) yielded amine‐terminated HBPBI (HBPBI‐2). The free carboxyl and amino groups of HBPBI‐1 and HBPBI‐2 could further react with o‐diaminobenzene and benzoic acid, respectively, to form the chemically modified polymers. Except HBPBI‐2, all the HBPBIs showed good solubility in some organic solvents (e.g., dimethyl sulfoxide and N,N‐dimethylacetamide). Thermogravimetric analysis measurement revealed that HBPBIs except HBPBI‐1 had high thermal stability (>450 °C). HBPBI membranes with good mechanical properties were obtained by crosslinking treatment of partially chemically modified HBPBIs with terephthaldehyde (TPA) during the film cast process. The HBPBI membranes had high phosphoric acid uptake and the phosphoric acid‐doped HBPBI‐6 (40% o‐diamino groups were reacted with benzoic acid) membrane showed higher tensile strength than the acid‐doped commercial PBI despite the higher doping level of the former. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1150–1158, 2007 相似文献
992.
Jong‐Beom Baek Frank W. Harris 《Journal of polymer science. Part A, Polymer chemistry》2004,42(24):6318-6330
A phenylquinoxaline (PQ) AB monomer mixture was treated with monofunctional and difunctional end‐capping agents and with and without a coupling agent to afford phenylethynyl‐terminated linear PQ oligomers. The resulting PQ oligomers were soluble in common organic solvents and had intrinsic viscosities (IVs) of 0.21–0.30 dL/g. The glass‐transition temperature (Tg) of the diphenylethynyl‐end‐capped PQ oligomer on both sides increased the most, from 215 °C (before curing) to 251 °C (after curing). The PQ AB2 monomer, which acted as both a coupling agent and a monomer for the hyperbranched polymer, was treated with an AB monomer and end‐capping agents to afford phenylethynyl‐terminated hyperbranched polyphenylquinoxalines (PPQs). They were also soluble in common organic solvents, had IVs of 1.00–1.65 dL/g and Tg's of 251–253 °C, and underwent exothermic cure with maxima around 412–442 °C. The Tg's of the cured hyperbranched PPQs ranged from 258 to 261 °C, depending on the number of phenylethynyl groups on the surface. After further curing, they displayed a Tg of 316 °C in one sample and turned into a fully crosslinked network. The dynamic melt viscosities of a linear oligomer (IV = 0.21 dL/g), a hyperbranched sample (IV = 1.00 dL/g), and a linear reference PPQ (IV = 1.29 dL/g) were compared with respect to the processing temperature. The PQ oligomer and hyperbranched PPQ had low melt viscosities. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 6318–6330, 2004 相似文献
993.
The paper outlines an approach to constructing a mathematical model of moving mechanical systems under uncertainty. Generalized
fuzzy differential equations are used to prove that the model is mathematically correct. The motion of a control oscillator
under uncertainty is considered as an example
__________
Translated from Prikladnaya Mekhanika, Vol. 43, No. 10, pp. 108–119, October 2007. 相似文献
994.
Thermoelastic stress analysis under nonadiabatic conditions 总被引:1,自引:0,他引:1
Thermoelastic stress analysis is a full-field stress measurement technique complementary to local techniques like strain gages.
Generally, the heat transfer inside the material is neglected with respect to the frequency of the cyclical loading. An adiabaticity
criterion is established to assert this simplification as a function of the thermal diffusion length and the spatial stress
gradients. Under nonadiabatic conditions, heat diffusion attenuates the spatial temperature gradients, which leads to an underestimation
of stress concentrations. Analytical and numerical considerations allow for the quantification of the spatial resolution.
Finally, several inverse techniques can restore the thermally attenuated contrasts. 相似文献
995.
996.
M. García J. I. Eguiazbal J. Nazbal 《Journal of Polymer Science.Polymer Physics》2003,41(10):1022-1032
Injection‐molded blends composed of two liquid‐crystalline polymers (LCPs) based on 60/40 p‐hydroxybenzoic acid/ethylene terephthalate (R3) and 73/27 p‐hydroxybenzoic acid/2,6‐hydroxynaphthoic acid (VA) copolymers, respectively, were obtained across the whole composition range. The two amorphous phases of the blends contained only slight amounts of the minority component, and the occurrence of some chemical reaction, mainly at high VA contents, was detected by Fourier transform infrared. Synergisms in the modulus of elasticity and in the tensile strength were seen in most of the blend compositions. The largest synergism was in the 50/50 R3/VA blend, which showed a modulus of elasticity 26% higher than that of either of the two components and a 17% positive deviation in the tensile strength with respect to the rule of mixtures. The different orientation of the LCPs in the blends explains the differences in the mechanical behavior. However, contrary to previous works on LCP blends and despite the almost complete immiscibility, the observed negative volume of mixing appears to be the main parameter that determines the synergistic mechanical behavior. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 1022–1032, 2003 相似文献
997.
D. M. Rein L. Shavit‐Hadar R. L. Khalfin Y. Cohen K. Shuster E. Zussman 《Journal of Polymer Science.Polymer Physics》2007,45(7):766-773
The electrospinning method has been employed to fabricate ultrafine nanofibers of ultrahigh‐molecular‐weight polyethylene for the first time with a mixture of solvents of different dielectric constants and conductivities. The possibility of producing highly oriented nanofibers from ultrahigh‐molecular‐weight polymers suggests new ways of fabricating ultrastrong, porous, and single‐component nanocomposite fibers with improved properties. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 766–773, 2007 相似文献
998.
基于多项式组主项解耦消元法 ,将几何定理的假设条件 (多项式组 PS)化为主项只含主变元的三角型多项式组 DTS,可得到定理命题成立的不含变元的非退化条件 ,即充分必要或更接近充分必要的非退化条件 .由于多项式主系数不含变元 ,已不存在 DTS多项式之间的约化问题 ,故方法有普遍意义 .文中例为西姆松定理的机器证明 . 相似文献
999.
1000.
模糊控制已在一类缓变的过程控制中得到成功的应用,本文将它引入到柴油机这一高速系统的性能控制,研究了相应的模糊控制器的设计方法,研制了以微计算机为核心的增压空气泄放控制系统,并在B6135-ZG20涡轮增压柴油机上实现了最大爆发压力的闭环控制。这一研究进一步改善了增压系统的性能,也为模糊控制开辟了一个新的应用领域。 相似文献