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51.
52.
L. Malherbe 《Accreditation and quality assurance》2002,7(5):189-194
Human health risk assessment is a site-based approach used to identify the potential health hazards which are induced by an
old site contamination. For a proper evaluation of the daily doses of contaminants to which people will be exposed given the
future occupation of the site, both a characterization and a quantification of soil pollution are needed. Such information
can be provided by soil sampling. Thus the choice of the location, the number, depth and type of soil samples is very important
and ought to follow a well-defined strategy. A review of contaminated site sampling practices in Europe and North America
could not identify any completely formalized sampling strategy for human health risk assessment. On the contrary there are
several approaches which can be roughly classified into two categories: a systematic sampling scheme over the whole site,
on the one hand, and a sampling design driven by an initial knowledge of the contamination sources and fitted to the suspected
pollution pattern, on the other. The first approach provides a complete coverage of the site but it may be rather expensive
and entail useless sampling. The performance of the second depends on the quality of prior information. Actually both methods
can be combined as explained hereafter. In view of the specificity of each site, the requirements of health risk assessment
and the time and cost constraints, it seems difficult to work out a typical soil sampling strategy suitable for all sites.
However, some recommendations can be made according to the site dimensions, the nature, degree and heterogeneity of contamination,
and the (future) use of the site. The scientist should thus rely on a thorough examination of all available information (site
history, geology and hydrogeology, soil properties, contaminants behaviour , etc.) to delimit contaminated areas as homogeneous
as possible and then distribute the sampling points (e.g.using a sampling grid). They should also take the potential exposure
paths into account in order to define the areas and soil strata to be sampled as a priority. Statistical and geostatistical
tools can be helpful for formulating a sampling strategy as well as for interpreting the collected data.
Received: 7 December 2001 Accepted: 24 February 2002 相似文献
53.
Carmen Luna Concepción Lloreda Juan F. Almagro Bello Jaime Botella Maria J. Orts Ana Gozalbo 《Mikrochimica acta》2004,145(1-4):121-127
Non-metallic inclusions in steel are formed due to interactions between liquid steel and its environment in the melting shop (refractories and slags). Particles not trapped in the slag remain in the cast steel, impairing steel properties in service. Inclusion composition varies and certified standards covering the whole compositional range are unavailable.The present study describes the preparation of a set of homogeneous, glassy and crystalline standards with a wide compositional range for use in analysing non-metallic steel inclusions. For this, materials were designed based on knowledge of the compositional range of interest in the Al2O3–SiO2–CaO–MgO–CaF2 system, which is the matrix of the most frequent steel inclusions. The composition and microstructural homogeneity of the reference materials was verified. 相似文献
54.
C. Skark N. Zullei-seibert 《International journal of environmental analytical chemistry》2013,93(1-4):387-396
Abstract A comparative review of pesticide survey endosing 16 waterworks in the FRG tries to increase the understanding about interferences of pesticide utilization and pesticide occurrence in ground- and drinkingwater, which includes characterization of sampling points, subsurface situation, land use and pesticide application. Between 1986 and 1991, 5772 samples were measured and led to 219094 data about the occurrence of various pesticides. 5% of these analyses showed pesticide or metabolite concentrations above the particular detection limits. This result does not vary in large extent considering groups of different characterized sampling points like groundwater dominated or surface water sampling points. As the herbicide atrazine and its metabolite desethylatrazine as well as the herbicide simazine were detected most often in all samples independent whether considering groundwater und surface water samples, this fact confirms the FRG-application ban for atrazine as well as the application restriction for simazine. 相似文献
55.
This article reports an investigation of 251 high school mathematics teachers’ meanings for slope, measurement, and rate of change. The data was collected with a validated written instrument designed to diagnose teachers' mathematical meanings. Most teachers conveyed primarily additive and formulaic meanings for slope and rate of change on written items. Few teachers conveyed that a rate of change compares the relative sizes of changes in two quantities. Teachers’ weak measurement schemes were associated with limited meanings for rate of change. Overall, the data suggests that rate of change should be a topic of targeted professional development. 相似文献
56.
Wei Zhou Xiangning Fang Qinglong Qiao Wenchao Jiang Yue Zhang Zhaochao Xu 《中国化学快报》2021,32(2):943-946
With the development of single-molecule detection and super-resolution fluorescence imaging, rhodamine dyes gain new life. Through the modification of the N-substituents and the replacement of the oxygen atom in xanthene, the wavelength and brightness can be effectively changed. However, the spectra of rhodamine, especially due to the balance between ring-closed non-fluorescent lactone and ring-opened fluorescent zwitterion/cation, are sensitive to interference from various environmental factors. In this way, the spectral data of various rhodamines reported by different research groups under different test conditions lacked comparability, sometimes even lacked accuracy. In order to meet the requirements for the accuracy and uniformity of spectral data in the research of single molecule imaging and dye structure-fluorescence relationship study, we have tested the spectra of fifteen rhodamine dyes that cover the visible and near-infrared regions under exactly the same conditions. By studying the dependence of the spectra on dye concentrations, it was confirmed that 1 μmol/L was ideal for detection less from the interference of dye molecule aggregation. We provide comprehensive and reliable spectral data of these fifteen dyes, which are expected to be used as references for future research. And the direct comparison of different rhodamine spectra would help to understand the structure-fluorescence relationship of rhodamines. 相似文献
57.
Fatigue damage behavior of a surface-mount electronic package under different cyclic applied loads 下载免费PDF全文
This paper studies and compares the effects of pull-pull and 3-point bending cyclic loadings on the mechanical fa- tigue damage behaviors of a solder joint in a surface-mount electronic package. The comparisons are based on experimental investigations using scanning electron microscopy (SEM) in-situ technology and nonlinear finite element modeling, respec- tively. The compared results indicate that there are different threshold levels of plastic strain for the initial damage of solder joints under two cyclic applied loads; meanwhile, fatigue crack initiation occurs at different locations, and the accumulation of equivalent plastic strain determines the trend and direction of fatigue crack propagation. In addition, simulation results of the fatigue damage process of solder joints considering a constitutive model of damage initiation criteria for ductile materials and damage evolution based on accumulating inelastic hysteresis energy are identical to the experimental results. The actual fatigue life of the solder joint is almost the same and demonstrates that the FE modeling used in this study can provide an accurate prediction of solder joint fatigue failure. 相似文献
58.
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60.
A. C. Lowe 《Molecular Crystals and Liquid Crystals》2013,570(1):295-308
An optimized configuration of the nematic guest-host effect is described in which a 90° twist cell is used. In order to assess the suitability of nematic guest-host systems for use in integrated displays in which a significant dc voltage may appear across the liquid crystal, several dye/host systems were tested with up to 1.5V dc superimposed on the normal 5V r.m.s. drive signal. Degradation was monitored by measurement of tilt, clearing point and absorbance. One system tested showed no significant degradation after 9 × 103 hr. Excellent correlation was observed between stability of a dye/host system in a driven display and the reversibility of the reduction of the dye in acetonitrile solution at a platinum electrode. 相似文献