淮南六方堤多层土堤基塑流稳定性计算

本文研究了台阶状六方堤堤体荷重的弗里哀级数展开式和堤基应力计算系数的计算原理,通过堤基应力计算和塑流判别,对六方堤多层土堤基塑流稳定性进行了评价。     

非线性子结构方法中实现对结构抗震措施阻尼器的数值模拟

应用子结构理论,对设置伸缩横缝的小湾高拱坝结构,分别就正常高水位常遇低水位两种水位工况,考虑坝体伸缩横缝在地震交变荷载作用下反复开合引起的缝面问滑移．接触等效应的影响,坝体一库水的相互作用而产生的动水压力的影响,对坝体的抗震性能进行了地震反应分析。对伸缩缝问设置阻尼器这一新的设计思想进行了可行性的研究,论证推导了阻尼器的计算模型,探讨了阻尼器对坝体结构抗震性能的影响。     

Suppressing charge recombination by incorporating 3,6‐carbazole into poly[9‐(heptadecan‐9‐yl)‐9H‐carbazole‐2,7‐diyl‐alt‐(5,6‐bis‐(octyloxy)‐4,7‐di(thiophen‐2‐yl)benzo[1,2,5]‐thiadiazole)‐5,5‐diyl]

A series of poly[9‐(heptadecan‐9‐yl)‐9H‐carbazole‐2,7‐diyl‐alt‐(5,6‐bis‐(octyloxy)‐4,7‐di(thiophen‐2‐yl)benzo‐[1,2,5]‐thia‐diazole)‐5,5‐diyl] compositions containing various ratios of 3,6‐carbazole was synthesized for testing in a polymer solar cell. An appropriate amount of 3,6‐carbazole units incorporated into the copolymer improved intermolecular charge transport, whereas excess amount of 3,6‐carbazole units temporarily seized on the partial negative charge generated in the conjugation breaks. We extensively studied the effects of the incorporated 3,6‐carbazole units on the intermolecular interactions, which can affect nongeminated recombination in bulk heterojunction‐polymer solar cells. These properties were investigated using photocurrent‐ and light intensity‐dependent measurements and electrochemical impedance spectroscopy. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 2047–2056     

A Godunov method for the computation of erosional shallow water transients

A Godunov method is proposed for the computation of open‐channel flows in conditions of rapid bed erosion and intense sediment transport. Generalized shallow water equations govern the evolution of three distinct interfaces: the water free‐surface, the boundary between pure water and a sediment transport layer, and the morphodynamic bottom profile. Based on the HLL scheme of Harten, Lax and Van Leer (1983), a finite volume numerical solver is constructed, then extended to second‐order accuracy using Strang splitting and MUSCL extrapolation. Lateralisation of the momentum flux is adopted to handle the non‐conservative product associated with bottom slope. Computational results for erosional dam‐break waves are compared with experimental measurements and semi‐analytical Riemann solutions. Copyright © 2003 John Wiley & Sons, Ltd.     

光学CT技术在大坝位移自动检测中的应用研究（二）

介绍采用光学ＣＴ及ＣＣＤ技术的大坝位移自动检测系统中结合采用数字信号的信息提取方法，对该方法在各种具有情况下处理信号的结果进行分析。     

Gamma-oxidation of linear low-density polyethylene: The dose–rate effect of irradiation on chemical and physical modifications

γ-Oxidation of linear low-density polyethylene based on hexene and butene was investigated. Irradiation was performed at different dose rates in air (from 2 rad/s to 100 rad/s). Degraded samples were analyzed with IR combined with NO and SF₄ derivatizations. Our results showed that the lower the dose rate, the higher the degree of oxidation in terms of γ-product formation. Ketone species appeared to be the dominant γ-products. The G values of γ-product formation were very dependent on the dose rate of initiation. Comparison of the G value ratio of different γ-products revealed stoechiometry differences. The complex appearance and disappearance of unsaturations was tentatively explained. The modifications of elongation at break induced by γ-irradiation were monitored by molecular changes in weight. This was not conclusive because changes in elongation at break are inconsistent with changes in M_w/M_n. © 1995 John Wiley & Sons, Inc.     

基于图像分割的尾矿坝干滩长度监测

干滩长度是反映影响尾矿库安全稳定的重要参数之一。为了测量尾矿坝干滩的长度,提出一种基于图像分割的干滩长度监测系统。根据尾矿库地形特点通过获取尾矿库水域边界图像,在Emgu CV环境下,使用OTSU阈值分割法、轮廓识别、分水岭法等算法过滤图片中尾矿库周围的植物、水面的波纹和倒影,自动清晰地识别干滩和水面的分界水线,并对水线像素坐标点进行分析与处理,实时得出最准确的干滩水线像素坐标。创新性地只通过一次标志物标定就能得出水线坐标与干滩长度的函数,从而得到尾矿坝干滩长度。经过浙江建德铜矿尾矿坝实地测量,该方法长度误差小于2.6%。     

Simulation of compressibility of entrapped air in an incompressible free surface flow using a pressure-based method for unified equations

A pressure-based method is developed to solve the unified conservation laws for incompressible and compressible fluids. A polytropic law is used to model the compressibility of a gas and decouple the energy equation. The pressure field is calculated by solving a single-pressure Poisson equation for the entire flow domain. The effects of the compressibility of the gas are reflected in the source term of the Poisson equation. The continuities of pressure and normal velocity across a material interface are achieved without any additional treatment along the interface. To validate the developed method, the oscillation of a water column in a closed tube due to the compression and expansion of air in the tube is simulated. The computed time history of the pressure at the end wall of the tube is in good agreement with other computational results. The free drop of a water column in a closed tank is simulated. The time history of the pressure at the center of the bottom of the tank shows good agreement with other reported results. The developed code is applied to simulate the air cushion effect of entrapped air in a dam break flow. The computed result is in good agreement with other experimental and computational results until the air is entrapped. As the entrapped air pocket undergoes rapid pulsation, the pressure field of water around the air pocket oscillates synchronously.     

Optimized incompressible smoothed particle hydrodynamics methods and validations

The solution of the Poisson's equation used by the incompressible smoothed particle hydrodynamics (ISPH) methods for estimating the pressure field is expensive in CPU time. The CPU time, consumed by the inversion of the operator ∇(1/ρ∇) and the estimation of the right hand side of the Poisson's equation, increases with the number N of particles used in a purely Lagrangian framework. In this work, this default of ISPH methods is overcome by solving the Poisson's equation on a Cartesian grid. This SPH-mesh coupling is equivalent to the particle in cell method. In a first step, in order to analyze its efficiency, the optimized version of two ISPH methods (divergence free and density invariant) is compared with the standard weakly compressible SPH method through two benchmarks of incompressible bidimensional flows characterized by the Reynolds number Re, Lamb-Oseen vortex (10 ≤Re≤ 100) and lid-driven cavity flow (100 ≤Re≤ 1000). In a second step, the numerical results obtained by the three SPH methods are compared to laboratory experimental data of a dam break flow in order to show the performance of the SPH-mesh coupling in a practical and complex flow problem. As in the configuration of the experimental setup, the numerical results are obtained for a Reynolds number Re = 3.8 10⁶.     

Parameters influencing the molecular weight of 3,6‐carbazole‐based D‐π‐A‐type copolymers

Condensation copolymerization reactions of carbazole 3,6‐diboronate with 4,7‐bis(5‐bromo‐2‐thienyl)‐2,1,3‐benzothiadiazole (DTBT) only produce low‐molecular‐weight donor (D)‐π‐acceptor (A) copolymers. High‐molecular‐weight copolymers for use in optoelectronic devices are necessary for achieving extended π‐conjugation and for controlling the copolymer processibility. To elucidate the cause of the persistently low molecular weight, we synthesized three 3,6‐carbazole‐based D‐A copolymers using copolymerizations of N‐9′‐heptadecanyl‐3,6‐carbazole with DTBT, N‐9′{2‐[2‐(2‐methoxy‐ethoxy)‐ethoxy]‐ethyl}‐3,‐6‐carbazole with DTBT, and N‐9′‐heptadecanyl‐3,6‐carbazole with alkyl‐substituted DTBT. We investigated several parameters for their influence on molecular copolymer weight, including the conformation of the chain during growth, the solubility of the monomers, and the dihedral angles between the donor and acceptor units. Size exclusion chromatography, UV–vis absorption spectroscopy, and computational studies revealed that the low molecular weights of 3,6‐carbazole‐based D‐A copolymers resulted from conjugation breaks and the resulting high coplanarity, which led to strong interactions between polymer chains. These interactions limited formation of high‐molecular‐weight‐copolymers during copolymerization. The strong intermolecular interactions of the 3,6‐carbazole moiety were exploited by incorporating 3,6‐carbazole units into poly[9′,9′‐dioctyl‐2,7‐flourene‐alt‐5,5‐(4′,7′‐di‐2‐thienyl‐2′,1′,3′‐benzothiadiazole)] prepared from 9′,9′‐dioctyl‐2,7‐flourene and DTBT. Interestingly, the number average molecular weight increased gradually with increasing 2,7‐fluorene monomer content but the number of conjugation breaks was a range of 6–7. The hole mobilities of the copolymers were studied for comparison purposes. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011