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111.
Numerous formulations describing the dynamics and morphology of corrugated flames, including the scenarios of flame acceleration, are based on a “geometrical consideration”, where the wrinkled-to-planar flame velocities ratio, Sw /SL , is evaluated as the scaled flame surface area, while the entire combustion chemistry is immersed into the planar flame speed SL , which is assumed to be constant. However, SL may experience noticeable spatial/temporal variations in practice, in particular, due to pressure/temperature variations as well as non-uniform distribution of the equivalence ratio and/or that of combustible or inert dust impurities. The present work initiates the systematic study of the impact of the local SL -variations on the global flame evolution scenario. The variations are assumed to be imposed externally, in a manner being a free functional of the formulation. Specifically, the linear, parabolic and hyperbolic spatial SL -distributions are incorporated into the formulations of finger flame acceleration in pipes, and they are compared to the case of constant SL . Both two-dimensional channels and cylindrical tubes are considered. The conditions promoting or moderating flame acceleration are identified, and the revisited equations for the flame shape, velocity and acceleration rate are obtained for various SL -distributions. The theoretical findings are validated by the computational simulations of the reacting flow equations, with agreement between the theory and modelling demonstrated. 相似文献
112.
113.
《International Journal of Solids and Structures》2014,51(19-20):3471-3479
Azobenzene-containing glassy nematic sheets deform in response to light in a complicated way depending on director distribution. To quantify the large-deflected deformation, a theoretical model is developed for the sheets with typical splay-bend and twist director distributions. A third-order in-plane displacement assumption is adopted to characterize the effect of transverse shear deformation, and the necessity is discussed through two examples for which analytical solutions are obtainable. Though this work is an extension of the third-order shear deformable theory for anisotropic laminates, it involves some new ingredients such as varying spontaneous strains and special material symmetries. The results are expected useful for analysis and design of the glassy nematic sheets in actuation applications. 相似文献
114.
This research is made to visualize the boundary layer flow by a curved stretching sheet embedded in porous medium. The geometry is bended(curved), therefore the curvilinear coordinates are used to model the present problem.Fluid is electrically conducting with the presence of uniform magnetic field. The governing non-linear partial differential equation reduces to non-linear ordinary differential equations by using the dimensionless suitable transformations. The numerical solutions are obtained by using the method bvp4c from MATLAB. The effects of curvature parameter, nondimensional magnetic parameter, and porosity parameter on the velocity field and skin friction coefficient are examined.The skin friction profile enhances with enhancing the values of porosity and magnetic parameter. Comparison of the present results with the existing results in the literature for the flat surface is also given. 相似文献
115.
116.
《International journal of quantum chemistry》2018,118(16)
The low‐temperature reduction of N2O plays a significant role for solving the growing environmental and health issues caused by emission of this greenhouse gas. The aim of this study is to investigate the possible reaction pathways for the reduction of N2O by CO or SO2 molecule over Si‐doped boron nitride nanosheet (Si‐BNNS). According to our results, a B or N‐vacancy defect in BN sheet could be able to greatly stabilize the single Si adatom. The relatively large diffusion barrier for the Si atom over the defective BN sheet also indicates Si‐BNNS is stable enough to be utilized in catalytic reduction of N2O. The large charge‐transfer from the surface to N2O leads to the spontaneous dissociation of this molecule into N2 molecule and an activated oxygen atom (Oads). The Oads moiety is then eliminated by CO or SO2 molecule. The calculated activation energies and reaction energies reveal that the Si atom located on top of the B‐vacancy site has a large catalytic activity toward the reduction of N2O by CO or SO2. 相似文献
117.
We prove limsup results for nonnegative functionals of convex sets determined by normalized Brownian paths in Banach spaces. This continues the interesting investigation of D. Khoshnevisan into this area, and relates to some classical unsolved isoperimetric problems for the convex hull of curves in d. Section 4 contains the solution of a problem similar to these classical problems. 相似文献
118.
A review on developments of liquid membranes (LMs) in the field of gas and vapor separation of the last 16 years is presented. Liquid membrane configurations employing supports, i.e. immobilized, supported and contained liquid membranes are focussed and detailed information on the respective materials, i.e. supports (supplier, type, thickness, pore width, porosity, tortuosity), liquids and carriers, are presented together with their specific separation tasks. Performance of different LMs in terms of permeability and selectivity as well as stability (duration of testing, applied differential pressures) are compared and discussed. Finally, different preparation methods of LMs are illustrated. 相似文献
119.
We studied the topographical effect of roughness displayed by a closely packed particle monolayer on formation of a cell monolayer (cell sheet). Particle monolayers were prepared by Langmuir-Blodgett deposition using particles, which were 527nm (SA053) and 1270nm (SA127) in diameter. Human umbilical vein endothelial cells (HUVECs) were seeded at a high density (2.0 x10(5)cells/cm(2)) onto particle monolayers. It was found that cells gradually became into contact with adjacent cells on the SA053 monolayer and the formed cell sheet could be readily detached from the particle monolayer by gentle pipetting. On the other hand, cells adhering onto the tissue culture polystyrene (TCPS) and the SA127 particle monolayer were difficult to peel off. At a low cell seeding density (5.0x10(4)cells/cm(2)), pre-coating with bovine plasma fibronectin (FN) allowed cell growth on an SA053 particle monolayer, and a confluent monolayer was able to be peeled as a cell sheet from the particle monolayer just by pipetting. By immunostaining of human fibronectin, we found that fibronectin was secreted and concentrated onto the substrate side of a cell sheet. The obtained cell sheet adhered and grew on the TCPS again within 20min. 相似文献
120.
New cage models (MeAlO)n(Me3Al)m (n=16, m=6 or 7) isomeric with previously reported sheet models for the principle activator found in hydrolytic MAO (h-MAO) are compared at M06-2X and MN15 levels of theory using density functional theory with respect to their thermodynamic stability. Reactivity of the neutrals or corresponding anions with formula [(MeAlO)16(Me3Al)6Me]− towards chlorination, and loss of Me3Al is explored while reactivity of the neutrals towards formation of contact- and outer-sphere ion pairs from Cp2ZrMe2 and Cp2ZrMeCl is examined. The results suggest on balance that a cage model for this activator is less consistent with experiment than an isomeric sheet model, although the latter are more stable based on free energy. 相似文献