La0．85Sr0．015MnO3—δ／Fe异质结构的瞬间光电导研究

采用磁控溅射的方法在Si基片上制备了La0.85Sr0.015MnO3-δ/Fe异质结构,对所制备结构中La0.85Sr0.015MnO3-δ薄膜的输运及光诱导特性进行了分析,表明薄膜在整个测量的温度区间内呈现金属一半导体相变,相变温度为130K.在低温金属相,磁场作用导致电阻减小,而高温半导体相则使电阻增大;激光辐照导致样品电阻减小,并产生瞬间光电导效应,即随着激光的关闭电阻瞬间恢复到原值,其相对变化值随着温度的降低而增大,并在温度为80K时达到极大值约1660%,分析认为该瞬态光电导效应可能与薄膜本身的氧缺陷有关.     

Photophysics of 9-aminoacridinium hydrochloride

The steady state and time domain spectroscopy of 9-aminoacridinium hydrochloride have been studied. 9-aminoacridine (I), 9-aminoacridinium (II) and the double protonated ion (III) follow Waterman’s principle with respect to their spectra and lifetimes. It is established that the excimer formation in (II) is from the ground state dimers which undergo either thermally-activated radiationless excimer conversion or a geometrical rearrangement in the excited state at room temperature. The quenching of monomer emission by dimers or foreign quenchers (KI) is found to be of transient nature as suggested by the continuum model. The authors felicitate Prof. D S Kothari on his eightieth birthday and dedicate this paper to him on this occasion.     

长链脂肪酸影响胆红素-人血清蛋白复合物的激发态分化

胆红素与人血清白蛋白结合后会发生光异构和光诱导环化反应,其中后一反应将最终形成一种名为光红素的产物,这些光诱导化学反应是临床上治疗新生儿黄疸的基本原理. 据前人研究报道,长链脂肪酸的加入有利于光红素的生成,但其背后的机理,特别是其激发态动力学尚不明确. 本文利用飞秒瞬态吸收和飞秒荧光转换技术,探究了棕榈酸对胆红素在血清蛋白中的光化学反应的影响. 研究表明,随着棕榈酸的加入,光激发后的胆红素更倾向于通过4 ps的衰减通道返回热基态,而不是通过固有的超快激发态衰减途径(小于1 ps). 这一效应促进了热基态的胆红素发生由Z-Z到E-Z构型的异构化,从而提高了光红素的产率. 这是首次利用飞秒时间分辨光谱技术对长链脂肪酸在光疗过程中的作用进行表征,其结果可为相关临床研究提供有利的信息.     

Image Encryption Scheme with Compressed Sensing Based on a New Six-Dimensional Non-Degenerate Discrete Hyperchaotic System and Plaintext-Related Scrambling

Digital images can be large in size and contain sensitive information that needs protection. Compression using compressed sensing performs well, but the measurement matrix directly affects the signal compression and reconstruction performance. The good cryptographic characteristics of chaotic systems mean that using one to construct the measurement matrix has obvious advantages. However, existing low-dimensional chaotic systems have low complexity and generate sequences with poor randomness. Hence, a new six-dimensional non-degenerate discrete hyperchaotic system with six positive Lyapunov exponents is proposed in this paper. Using this chaotic system to design the measurement matrix can improve the performance of image compression and reconstruction. Because image encryption using compressed sensing cannot resist known- and chosen-plaintext attacks, the chaotic system proposed in this paper is introduced into the compressed sensing encryption framework. A scrambling algorithm and two-way diffusion algorithm for the plaintext are used to encrypt the measured value matrix. The security of the encryption system is further improved by generating the SHA-256 value of the original image to calculate the initial conditions of the chaotic map. A simulation and performance analysis shows that the proposed image compression-encryption scheme has high compression and reconstruction performance and the ability to resist known- and chosen-plaintext attacks.     

Transient Dynamics in the Random Growth and Reset Model

A mean-field type model with random growth and reset terms is considered. The stationary distributions resulting from the corresponding master equation are relatively easy to obtain; however, for practical applications one also needs to know the convergence to stationarity. The present work contributes to this direction, studying the transient dynamics in the discrete version of the model by two different approaches. The first method is based on mathematical induction by the recursive integration of the coupled differential equations for the discrete states. The second method transforms the coupled ordinary differential equation system into a partial differential equation for the generating function. We derive analytical results for some important, practically interesting cases and discuss the obtained results for the transient dynamics.     

In-plane oriented CH_3NH_3PbI_3 nanowire suppression of the interface electron transfer to PCBM

One-dimensional nanowire is an important candidate for lead-halide perovskite-based photonic detectors and solar cells. Its surface population, diameter, and growth direction, etc., are critical for device performance. In this research,we carried out a detailed study on electron transfer process at the interface of nanowire CH_3 NH_3 PbI_3(N-MAPbI_3)/Phenyl C61 butyric acid methyl-ester synonym(PCBM), as well as the interface of compact CH_3 NH_3 PbI_3(C-MAPbI_3)/PCBM by transient absorption spectroscopy. By comparing the carrier recombination dynamics of N-MAPbI_3, N-MAPbI_3/PCBM,C-MAPbI_3, and C-MAPbI_3/PCBM from picosecond(ps) to hundred nanosecond(ns) time scale, it is demonstrated that electron transfer at N-MAPbI_3/PCBM interface is less efficient than that at C-MAPbI_3/PCBM interface. In addition, electron transfer efficiency at C-MAPbI_3/PCBM interface was found to be excitation density-dependent, and it reduces with photo-generation carrier concentration increasing in a range from 1.0 × 1018 cm~(-3)–4.0 × 1018 cm~(-3). Hot electron transfer,which leads to acceleration of electron transfer between the interfaces, was also visualized as carrier concentration increases from 1.0 × 10~(18) cm~(-3)–2.2 × 10~(18) cm~(-3).     

Adaptive synchronization of chaotic systems with less measurement and actuation

We investigate the synchronization problem between identical chaotic systems only when necessary measurement(output) and actuation(input) are needed to be implemented by the adaptive controllers. A sufficient condition is derived based on the Lyapunov stability theory and Schur complementary lemma. Moreover, the theoretic result is applied to the Rikitake system and the hyperchaotic Liu system to show its effectiveness and correctness. Numerical simulations are presented to verify the results.     

外部光注入的光泵浦自旋垂直腔表面发射激光器中的两个混沌偏振分量对两个复杂形状目标中的多区域精确测距

基于外部光注入的光泵浦自旋垂直腔表面发射激光器(vertical cavity surface-emitting laser,VCSEL)的两个混沌偏振分量,提出了对两个复杂形状目标中的多区域精确测距方案.这里,两个混沌偏振探测波具有飞秒量级快速动态并且被双极性sinc波形调制,使它们具有时空不相关特性.利用这些特性,通过计算多束延时反馈混沌偏振探测波形和与之相对应的参考波形的相关性,实现了对两个复杂形状目标多区域位置矢量精确测量.研究结果表明,对多区域小目标的测距具有非常低的相对误差(低于0.94%).当光电探测器的带宽足够大时,其测距的分辨率达到0.4 mm,并具有很强的抗噪声能力.本文的研究结果在复杂形状目标的精确测距方面具有潜在应用.     

Insight into influence of thermodynamic coefficients on transient negative capacitance in Zr-doped HfO2 ferroelectric capacitors

We study the influence of the thermodynamic coefficients on transient negative capacitance for the Zr-doped HfO₂ (HZO) ferroelectric capacitors by the theoretical simulation based on the Landau-Khalatnikov (L-K) theory and experimental measurement of electrical properties in the resistor-ferroelectric capacitor (R-FEC) circuit. Our results show that the thermodynamic coefficients α, β and γ also play a key role for the transient NC effect besides the viscosity coefficient and series resistor. Moreover, the smaller coefficients α and β, the more significant the transient NC effect. In addition, we also find that the thermodynamic process of transient NC does not obey the generally accepted viewpoint of Gibbs free energy minimization.     

Adaptive synchronization of a class of fractional-order complex-valued chaotic neural network with time-delay

This paper is concerned with the adaptive synchronization of fractional-order complex-valued chaotic neural networks (FOCVCNNs) with time-delay. The chaotic behaviors of a class of fractional-order complex-valued neural network are investigated. Meanwhile, based on the complex-valued inequalities of fractional-order derivatives and the stability theory of fractional-order complex-valued systems, a new adaptive controller and new complex-valued update laws are proposed to construct a synchronization control model for fractional-order complex-valued chaotic neural networks. Finally, the numerical simulation results are presented to illustrate the effectiveness of the developed synchronization scheme.