基于改善空间关联性的混沌控制

基于混沌信号的统计特性，提出了一种通过改善混沌信号的空间关联性实现混沌控制的方法.以Hénon离散混沌系统和四阶Chua's电路超混沌连续系统为例进行了数值研究，验证了这种控制方法的有效性.结果表明， 通过改善混沌信号之间的空间关联性， 混沌系统能以较快的速度收敛到它的平衡点或多种周期轨道. 关键词： 混沌控制 空间关联性 Hénon系统 四阶Chua's电路     

一个新的四维混沌系统理论分析与电路实现

分析了一个新的复杂的四维混沌系统的基本特性，该系统每个方程中包含一个三次交叉乘积项，共有9个平衡点，它们相对于原点和坐标轴具有完美的对称性，并且相对于线性特性和不变流形具有很好的相似性.描述了两个同时共存的对称双翼吸引子.最后，设计了一个模拟电路来实现这个新的四维混沌系统，表明数值仿真和电路实现具有很好的一致性，同时说明在应用上由于频率不同导致的仿真与物理实现之间的重要区别. 关键词： 四维混沌系统 Lyapunov 指数 共存双翼吸引子 电路实现     

F+H2→HF+H反应的全量子态分辨的散射动力学研究

利用高灵敏度的氢原子里德堡飞渡时间谱方法研究了 F H_2→HF H 反应碰撞能在5.02kJ/mol 下的交叉分子束反应态态散射动力学.所有在时间飞渡谱中被观测到的谱峰可以归属为 HF 产物的振转态结构.还观测到了明显的 HF(v’=3)前向散射,以及少许的 HF(v’=2)前向散射.     

Two-spin-majority cellular automaton as a model of 2D cluster and interface growth

A new probabilistic cellular automaton model is introduced to simulate cluster and interface growth in two dimensions. The dynamics of this model is an extension to higher dimensions of the compact directed percolation studied by Essam. Numerical results indicate that the two-dimensional cluster coarsening and growth can be described only approximately by the conventional cluster size scaling due to a crossover in the growth mode. The spreading of the initially flat interface follows a purely diffusional,t ^1/2, law.     

Atomistic packing models for experimentally investigated swelling states induced by CO2 in glassy polysulfone and poly(ether sulfone)

Atomistic packing models have been created, which help to better understand the experimentally observed swelling behavior of glassy polysulfone and poly (ether sulfone), under CO₂ gas pressures up to 50 bar at 308 K. The experimental characterization includes the measurement of the time‐dependent volume dilation of the polymer samples after a pressure step and the determination of the corresponding gas concentrations by gravimetric gas‐sorption measurements. The models obtained by force‐field‐based molecular mechanics and molecular dynamics methods allow a detailed atomistic analysis of representative swelling states of polymer/gas systems, with respect to the dilation of the matrix. Also, changes of free volume distribution and backbone mobility are accessible. The behavior of gas molecules in unswollen and swollen polymer matrices is characterized in terms of sorption, diffusion, and plasticization. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 1874–1897, 2006     

泊松类型方程边界元解法

本文采用高阶拉普拉斯算子基本解将泊松类型方程的区域积分全部变换成边界积分，使计算问题的维数减少一维．通过斯托克斯方程的算例，表明本文所用的方法是有效的方法。     

Winning controllers and regions in competitive nonlinear dynamic games with two qualitative objectives and uncertain information

The Liapunov technique has been introduced in differential games in a sequence of works over the last decade. We discuss application of this technique to the interface between two competitive semi-games, each with different qualitative objective. The feedback information for controllers is provided from designed, analytically integrable state predictors with reduced dynamics, which considerably shortens the computing time. The case is illustrated on the scenario of target reaching before being intercepted, and intercepting before target is reached.Deceased.     

A numerical study of an unsteady laminar flow in a doubly constricted 3D vessel

Unsteady flow dynamics in doubly constricted 3D vessels have been investigated under pulsatile flow conditions for a full cycle of period T. The coupled non‐linear partial differential equations governing the mass and momentum of a viscous incompressible fluid has been numerically analyzed by a time accurate Finite Volume Scheme in an implicit Euler time marching setting. Roe's flux difference splitting of non‐linear terms and the pseudo‐compressibility technique employed in the current numerical scheme makes it robust both in space and time. Computational experiments are carried out to assess the influence of Reynolds' number and the spacing between two mild constrictions on the pressure drop across the constrictions. The study reveals that the pressure drop across a series of mild constrictions can get physiologically critical and is also found to be sensitive both to the spacing between the constrictions and the oscillatory nature of the inflow profile. The flow separation zone on the downstream constriction is seen to detach from the diverging wall of the constriction leading to vortex shedding with 3D features earlier than that on the wall in the spacing between the two constrictions. Copyright © 2002 John Wiley & Sons, Ltd.     

系统动力学模型结构分析中表函数的改进方法

分析了非线性系统动力学(SD)模型中表函数环节的传统表示方法,指出该方法对于进行SD模型的结构分析所造成的障碍,并提出了用牛顿插值的承袭性算法来改进表函数环节的表示方法的思路.接着分别介绍了用差商和差分牛顿插值法改进表函数的过程.最后,通过一个实例说明了表函数改进的方法,并展示了以此为基础进行结构分析的思路.     

Chain length effect on dynamical structure of poly (vinyl pyrrolidone)-polar solvent mixtures in dilute solution of dioxane studied by microwave dielectric relaxation measurement

Dielectric relaxation study of the binary mixtures of poly(vinyl pyrrolidone) (PVP) (Mw=24000, 40000 and 360000 g mol⁻¹) with ethyl alcohol (EA) and poly(ethylene glycol)s (PEGs) (Mw=200 and 400 g mol⁻¹) in dilute solutions of dioxane were carried out at 10.1 GHz and 35°C. The relaxation time of PVP-EA mixtures was interpreted by the consideration of a wait-and-switch model in the local structure of self-associated ethyl alcohol molecules and also the PVP chain length as a geometric constraint for the reorientational motion of ethyl alcohol molecules. The formation of complexes and effect of PVP chain length on the molecular dynamics, chain flexibility and stretching of PEG molecules in PVP-PEG mixtures were explored from the comparative values of dielectric relaxation time. Further, relaxation time values in dioxane and benzene solvent confirm the viscosity independent molecular dynamics in PVP-EA mixtures but the values vary significantly with the non-polar solvent environment.