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31.
Hongyu Yang Xin Wang Lei Song Bin Yu Yao Yuan Yuan Hu Richard K. K. Yuen 《先进技术聚合物》2014,25(9):1034-1043
The main aim of this work was to investigate the synergistic effect of expandable graphite (EG) and aluminum hypophosphite (AHP) on the flame retardancy of rigid polyurethane foams (RPUFs). A series of flame retardant RPUF containing EG and AHP were prepared by one‐shot and free‐rise method. The flame retardant, thermal degradation, and combustion properties of RPUF hybrids were characterized through limiting oxygen index (LOI) test, vertical burning (UL‐94) test, thermogravimetric analysis and microscale combustion calorimeter. The LOI and UL‐94 results showed that the RPUF sample with 10 wt% EG and 5 wt% AHP passed UL‐94 V‐0 rating and reached a relatively high LOI value of 28.5%, which is superior over other EG/AHP ratios in RPUF at the equivalent filler loading. Microscale combustion calorimeter results revealed that the incorporation of EG and AHP into RPUF reduced the peak heat release rate and total heat release, thus decrease the fire risk of RPUF significantly. Incorporation of EG and AHP improved the thermal stability of RPUF as observed from the thermogravimetric analysis results and also enhanced the thermal resistance of char layer at high temperature from scanning electron microscopy and Raman spectroscopy. Moreover, it could be seen from thermogravimetric analysis/infrared spectrometry spectra that the addition of EG and AHP significantly decreased the combustible gaseous products such as hydrocarbons and ethers. Finally, the synergistic mechanism in flame retardancy was discussed and speculated. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
32.
以动态光散射为主要手段研究了盐对羧酸盐Gemini表面活性剂O,O′-双(2-月桂酸钠)-p-二苯氧(记为C12φ2C12)自组织的影响.结果表明盐的加入很容易使C12φ2C12的网状聚集体转变为小(流体力学半径Rh,app约几纳米)和大(Rh,app100 nm)两种尺寸共存的聚集体,1,6-二苯基-1,3,5-己三烯(DPH)探针增溶实验证实小尺寸聚集体为核-壳结构的似球胶束,流变学测量说明大尺寸聚集体可能已经是线型的核-壳胶束.这种行为被归结为初始的网状聚集体不稳定,添加的反离子与C12φ2C12头基结合破坏了网状结构的亲水亲油平衡,促使了它们的转变.盐效应规律表现为MgCl2NaCl、Bu4NBrMe4NBrEt4NBrPr4NBr,这里Bu4NBr不遵循上述静电力顺序的原因是它提供了携带的丁基与C12φ2C12烷烃链疏水相互作用的附加力. 相似文献
33.
Dr. Wei Bai Jingyu Gao Dr. Kun Li Gongrui Wang Dr. Tengfei Zhou Pengju Li Prof. Shengyong Qin Prof. Genqiang Zhang Prof. Zaiping Guo Prof. Chong Xiao Prof. Yi Xie 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(40):17647-17651
Volume expansion and poor conductivity are two major obstacles that hinder the pursuit of the lithium-ion batteries with long cycling life and high power density. Herein, we highlight a misfit compound PbNbS3 with a soft/rigid superlattice structure, confirmed by scanning tunneling microscopy and electrochemical characterization, as a promising anode material for high performance lithium-ion batteries with optimized capacity, stability, and conductivity. The soft PbS sublayers primarily react with lithium, endowing capacity and preventing decomposition of the superlattice structure, while the rigid NbS2 sublayers support the skeleton and enhance the migration of electrons and lithium ions, as a result leading to a specific capacity of 710 mAh g−1 at 100 mA g−1, which is 1.6 times of NbS2 and 3.9 times of PbS. Our finding reveals the competitive strategy of soft/rigid structure in lithium-ion batteries and broadens the horizons of single-phase anode material design. 相似文献
34.
Shao-Dong Li Feng Su Miao-Li Zhu Li-Ping Lu 《Acta Crystallographica. Section C, Structural Chemistry》2020,76(9):863-868
A new coordination polymer (CP), namely, poly[[diaquatris[μ2‐1,4‐bis(1H‐imidazol‐1‐yl)benzene]bis[μ6‐4‐(2,4‐dicarboxylatophenoxy)phthalato]tetracobalt(II)] hexahydrate], {[Co4(C16H6O9)2(C12H10N4)3(H2O)2]·6H2O}n, has been synthesized by solvothermal reaction. The CP was fully characterized by IR spectroscopy, elemental analysis, thermogravimetric analysis, and powder and single‐crystal X‐ray diffraction. It presents a three‐dimensional (3D) structure based on tetranuclear CoII secondary building units (SBUs) with a tfz‐d net and point symbol (43)2(46·618·84). The 4‐(2,4‐dicarboxyphenoxy)phthalic acid (H4dcppa) ligands are completely deprotonated and link {Co4(COO)4}4? SBUs into two‐dimensional (2D) layers. Furthermore, adjacent layers are connected by 1,4‐bis(1H‐imidazol‐1‐yl)benzene (bib) ligands, giving rise to a 3D supramolecular architecture. Interestingly, there are numerous elliptical cavities in the CP where isolated unique discrete hexameric water clusters have been observed. The results of thermogravimetric and magnetic analyses are described in detail. 相似文献
35.
36.
Xiaoye Ma Chuanqing Kang Wenhui Chen Rizhe Jin Haiquan Guo Xuepeng Qiu Lianxun Gao 《Journal of polymer science. Part A, Polymer chemistry》2016,54(4):570-581
To investigate the influence of hydrogen bonding on the properties of polyimides (PIs) containing rigid rod‐like groups, five symmetrical diamines containing benzimidazole, benzoxazole, and hydroxy group were synthesized, and then a series of PIs were prepared. Results showed that hydroxyl‐containing poly(benzoxazole imide)s possess higher glass transition temperature (Tg) and dimensional stabilities than their corresponding poly(benzoxazole imide)s. Moreover, the corresponding poly(benzimidazole imide)s presented the best performances, such as the highest Tg, the highest char yield and the highest dimensional stabilities. The influence of hydrogen bonding of benzimidazole on the properties of PIs was stronger than that of hydroxyl groups. Hydroxyl‐containing poly(benzoxazole imide)s were formed in crosslinking structures after heat treatment at 400 °C. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 570–581 相似文献
37.
《Physics and Chemistry of Liquids》2012,50(4):193-196
Abstract The molecular theory of dense fluids is progressing rapidly and its extension to mixtures is well underway. The purpose of this note is to call attention to a possibly serious difficulty in comparing experimental Henry's constants with those calculated from theory. The difficulty arises because whereas theorists choose temperature and density as independent variables, experimental equilibrium measurements on mixtures are often made along the saturation line where (at fixed composition) temperature and density are not both independent variables. Unless Henry's constants are defined with care, the effect of temperature on Henry's constants calculated from molecular theory may be qualitatively different from that observed. 相似文献
38.
Let be a lattice in a noncompact simple Lie Group G, where . Suppose acts analytically and ergodically on a compact manifold M preserving a unimodular rigid geometric structure (e.g. a connection and a volume). We show that either the action is isometric or there exists a "large image" linear representation of . Under an additional assumption on the dynamics of the action, we associate to a virtual arithmetic quotient of full entropy.
Received: December 14, 2000 相似文献
39.
40.
基于最小加速度原理的刚塑性动力问题 总被引:2,自引:0,他引:2
应用有限变形的最小加速度原理,推导出了小变形或有限变形构件受到刚性飞射物撞击时的刚塑性运动方程,指出该方法具有直接、简捷和可靠的特点。 相似文献