全文获取类型
收费全文 | 110篇 |
免费 | 4篇 |
国内免费 | 10篇 |
专业分类
化学 | 47篇 |
力学 | 45篇 |
综合类 | 5篇 |
数学 | 9篇 |
物理学 | 18篇 |
出版年
2024年 | 2篇 |
2022年 | 1篇 |
2021年 | 5篇 |
2020年 | 6篇 |
2019年 | 1篇 |
2018年 | 7篇 |
2017年 | 7篇 |
2016年 | 6篇 |
2015年 | 4篇 |
2014年 | 6篇 |
2013年 | 8篇 |
2012年 | 7篇 |
2011年 | 4篇 |
2010年 | 5篇 |
2009年 | 10篇 |
2008年 | 7篇 |
2007年 | 3篇 |
2006年 | 4篇 |
2005年 | 2篇 |
2004年 | 5篇 |
2003年 | 3篇 |
2002年 | 3篇 |
2001年 | 1篇 |
2000年 | 2篇 |
1999年 | 1篇 |
1997年 | 4篇 |
1994年 | 3篇 |
1993年 | 2篇 |
1992年 | 1篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1982年 | 1篇 |
1981年 | 1篇 |
排序方式: 共有124条查询结果,搜索用时 31 毫秒
1.
The glass transition temperature (Tg), measured by Modulated Differential Scanning Calorimetry (MDSC), is related to the flow characteristics of asphalt at low temperatures as is the rate of change of the creep stiffnessm. This study compared the glass transition temperature of different asphalts (neat, chemically modified, and crumb rubber modified asphalts) with the creep stiffness, the rate of change of creep stiffness, and the low specification temperature of the continuous PG grading of those asphalts.From the rheological data (BBR) and the thermal data (MDSC) for the virgin and the modified asphalts, the modified products had the same variations of values ofm, S, and Tg at lower temperatures as those of their corresponding virgin asphalts. A correlation between the Tg andm value was observed for both the modified and unmodified asphalts. Since DSC measurements for asphalt low temperature properties use less operator time, less sample, and have less measurement and operator error than rheological methods, Tg has promise to be considered as a fast and easy laboratory method to obtain the low temperature useful range of asphalts in pavements.The authors would like to acknowledge Susan P. Needham for her work in conducting rheological testing for the modified and unmodified asphalts. 相似文献
2.
Experimental results on the extrapolated ultimate enhancement factors of o-, m-, and p-xylene protons at 1.53 mT are obtained for MC800 asphalt solutions. The ultimate enhancement factors are found such as ?26.9, ?25.7, and ?11.7 for o-, m-, and p-xylene, respectively. These results show that the solvent proton Overhauser effect cannot reach the extrapolated enhancement of ?330 in the extreme narrowing case because of occurrence of small scalar interactions in addition to the dipole–dipole interactions between solvent protons and asphalt electrons. The ortho, meta, and para positions of the –CH3 group change the nature of the interactions. The nuclear magnetic resonance (NMR) signal enhancements exhibit a sensitive behavior depending on the chemical environment differing from isomer to isomer. The solvation or association of asphalt in xylene isomers at room temperature is revealed. Quantum chemical calculations for the xylene isomers with the electronic and optical properties; absorption wavelengths, excitation energy, atomic charges, dipole moment and frontier molecular orbital energies, molecular electrostatic potential; are carried out using the density functional theory (DFT) method (B3LYP) with the 6-311G(d,p) basis set by the standard Gaussian 09 software package program. The relative importance of scalar and translational dipolar interaction parameters determined in dynamic nuclear polarization experiments is explained by the electronic structure of HOMO–LUMO of the xylene isomers. 相似文献
3.
D.G. Pavlou 《Mechanics Research Communications》2011,38(8):546-552
An analytic solution of a thin layer bonded on a visco-elastic medium under the action of in-plane and lateral pulse loads is presented. The analysis is based on double integral transforms with respect to space and time. Representative examples are studied and discussed to determine the influence of the (a) damping and elastic coefficients of visco-elastic medium, and (b) in-plane compression and stretching of the thin layer on wave propagation. 相似文献
4.
5.
Asphalt binder was modified by low-density polyethylene (LDPE) and ethyl vinyl acetate (EVA) polymers to investigate the structure–property relationships of polymer-modified asphalt (PMA). The PMA was prepared in a high-shear blender at 160 °C. The optimum blending time (OBT) for each polymer was determined following a separate investigation. OBT was influenced by Mw, MWD, and polymer structure. The influence of Mw of LDPE and vinyl acetate (VA) content of EVA on PMAs was studied by rheological tools. Polymer modification improved the rheological properties of base asphalt. EVA–PMAs were found to be less temperature sensitive than LDPE-modified asphalts. LDPE modification increased flow activation energy (Ea) but EVA modification decreased Ea. Both VA content and Mw of LDPE have influenced the storage stability of PMAs. The low-temperature properties of PMAs and short ageing tests were not influenced by polymer type. On the other hand, the high-temperature properties of PMAs were strongly influenced by Mw of LDPE and VA content of EVA. Overall, EVA with low VA content showed the best temperature resistance to high- temperature deformations, the highest upper service temperature as well as the best storage stability. 相似文献
6.
7.
《中国化学》2017,35(11):1701-1705
The development of asphalt‐based UV blocking materials is important to extend the alphalt lifespan in road construction. In this work, we put forward that the fabrication of host‐guest system can be an effective way to obtain UV blocking materials. Firstly, a new anionic Schiff base, N ,N' ‐bis(salicylidine)‐4,4'‐diaminostilbene‐2,2'‐disulfonic acid (SDSD ), has been synthesized, which was intercalated into Zn‐Al‐LDH by anion‐exchange method. FT‐IR and XRD illustrate the layered organic–inorganic composite, Zn‐Al‐SDSD‐LDH , has been successfully synthesized with high crystallinity. Laser particle size analyzer, SEM and TEM show that particle size distributions of Zn‐Al‐SDSD‐LDH is in the range 100–500 nm. UV –vis absorption spectra show that Zn‐Al‐SDSD‐LDH has better UV absorption than the pristine Zn‐Al‐LDH and SDSD . Furthermore, the mixture of asphalt and 3 wt% Zn‐Al‐SDSD‐LDH presents enhanced UV blocking property relative to the pristine asphalt after irradiating by UV spray accelerated weathering test. Therefore, this work not only develops a new type of host‐guest Zn‐Al‐SDSD‐ LDH , but also confirms it can be an effective asphalt UV blocking material for practical application. 相似文献
8.
本文将飞机-道面-土基作为一个相互作用的动力系统,对飞机滑行情况下,弹性半空间地基上刚性道面板的动响应,采用有限元法进行了计算分析。结果表明,本文计算结果与现场实测值吻合很好。由于考虑了飞机和道面之间的耦合作用,避免了实测飞机对道面作用荷载的繁琐工作,因此本文方法具有明显的实用意义。 相似文献
9.
我国北方地区的土石坝和水池的防渗沥青混凝土面板,常出现低温裂缝。因此,对沥青混凝土在低温条件下的温度应力疲劳进行实验研究很有必要.本项研究研制了适用于沥青混凝土低温低周大变形的弯曲疲劳试验机,进行了沥青混凝土在不同低温下的疲劳破坏性能试验。对试验结果用粘弹性理论和推广的应变区分法(SRP)和应变能区分法(SEP)进行了分析,首次得出了沥青混凝土的疲劳寿命与弯曲应力、应变和应变能的关系,并试用于实际工程的予测. 相似文献
10.
将沥青混合料看作由粗骨料和沥青砂组成的两相复合材料,根据给定的级配生成凸多面体骨料,然后利用随机投放算法建立沥青混合料试样的三维随机模型.采用广义Maxwell模型刻画沥青砂的本构行为,其参数通过单轴蠕变实验获得.在对三维随机模型的有效性进行验证之后,采用参数化建模方法建立包含不同骨料分布、含量和级配的沥青混合料有限元模型,通过数值模拟研究骨料分布、含量和级配对沥青混合料蠕变行为的影响.结果表明:骨料分布对沥青混合料力学性质的影响较小;沥青混合料瞬时弹性模量随骨料含量的增加呈近似线性增大,而且弹性模量与骨料含量之间的关系曲线处于Paul上下边界内;在计算考虑的粒径范围内,骨料平均粒径越小,沥青混合料抵抗变形的能力越强. 相似文献