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81.
Venkatesh Vasudevan David F. Davidson Ronald K. Hanson Craig T. Bowman David M. Golden 《Proceedings of the Combustion Institute》2007,31(1):175-183
The two-channel thermal decomposition of formaldehyde [CH2O], (1a) CH2O + Ar → HCO + H + Ar, and (1b) CH2O + Ar → H2 + CO + Ar, was studied in shock tube experiments in the 2258-2687 K temperature range, at an average total pressure of 1.6 atm. OH radicals, generated on shock heating trioxane-O2-Ar mixtures, were monitored behind the reflected shock front using narrow-linewidth laser absorption. 1,3,5 trioxane [C3H6O3] was used as the CH2O precursor in the current experiments. H-atoms formed upon CH2O and HCO decomposition rapidly react with O2 to produce OH via H + O2 → O + OH. The recorded OH time-histories show dominant sensitivity to the formaldehyde decomposition pathways. The second-order reaction rate coefficients were inferred by matching measured and modeled OH profiles behind the reflected shock. Two-parameter fits for k1a and k1b, applicable in this temperature range, are:
82.
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84.
Li Yong-Feng Zhang Jie-Qiu Qu Shao-Bo Wang Jia-Fu Zheng Lin Zhou Hang Xu Zhuo Zhang An-Xue 《中国物理 B》2015,24(1):14202-014202
In this paper,we show that circular polarization-keeping reflection can be achieved using reflective metasurfaces.The underlying physical mechanism of the polarization-keeping reflection is analyzed using a reflection matrix.A wideband circular polarization-keeping reflector is demonstrated using N-shaped resonators.Both the simulation and experiment results show that the polarization-keeping reflection can be achieved with a high efficiency larger than 98%over the frequency range from 9.2 GHz to 17.7 GHz for both incident left-and right-handed circularly polarized waves.Under oblique incidence,the bandwidth increases as the incident angle varies from 0°to 80°. Moreover,the co-polarization reflection is independent of the incident azimuth angles. 相似文献
85.
Dr. Yannian Li Mengfei Wang Hao Wang Dr. Augustine Urbas Prof. Quan Li 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(49):16286-16292
Three rationally designed axially chiral diarylethene switches were synthesized and their application as chiral dopants for phototunable cholesteric liquid crystal devices was investigated. Design of these molecules was based on the combination of photochromic dithienylcyclopentene core with bridged binaphthyl units as chiral precursors. Aromatic groups were introduced to the molecules at 6,6′‐positions of binaphthyls through a Suzuki–Miyaura coupling reaction. Their helical twisting powers (HTPs) are significantly higher than those of the known chiral diarylethenes reported as chiral dopants so far. Photocyclization of these molecules upon light irradiation brought out dramatic variation in HTPs between different states. The primary colors, red, green, and blue, were obtained in reflection on light irradiation and with thermal stability. Moreover, a multi‐switchable photodisplay was demonstrated using one of these chiral molecular switches. 相似文献
86.
应用衰减全反射傅里叶变换红外光谱法测定橙子油中柠檬烯的含量。柠檬烯的特征峰(1 645.1±1)cm-1为定量测量峰,测定样品在15min内完成。柠檬烯的体积分数在9.60%~76.8%范围内与测量峰峰高呈线性关系。以橙子油样品为基体进行加标回收试验,所得回收率在99.7%~101%之间,测定值的相对标准偏差(n=5)为1.1%。 相似文献
87.
讨论了两种新型纤维素纳米晶体(Cellulose nanocrystal,CNC)薄膜的制备方法:浸没法和旋涂法,并利用红外反射吸收光谱(Infrared reflection absorption spectroscopy,IRRAS)和原子力显微镜(Atomic force microscopy,AFM)对其进行表征。AFM高度图显示两种工艺制备的CNC薄膜均由棒状的CNC纳米颗粒交错叠加而成。实验结果显示,旋涂法制备的薄膜更加光滑,粗糙度RMS约为2.7 nm。由于带电颗粒间斥力的存在,浸没法制备的CNC膜厚度最大约为15 nm,而旋涂法可以得到更厚的CNC薄膜,其厚度可达50 nm以上。研究CNC悬浮液浓度与旋涂法CNC膜厚之间的关系后发现,可以通过改变CNC溶液的浓度对薄膜厚度进行控制。IRRAS结果也证实随着CNC悬浮液浓度的增加,旋涂薄膜的厚度随之增加。 相似文献
88.
ABSTRACTTwo series of novel side-chain liquid crystal (LC) polysiloxanes grafted with chiral liquid crystalline dimers containing cholesteryl mesogens were synthesised. The chemical structure and LC properties of comonomers and polymers were characterised by FTIR, 1H-NMR, DSC, TGA, POM and XRD. M1 and M2 were chiral nematic (N*) dimers, and M3 was an achiral LC monomer displaying nematic mesophase in a narrow mesomorphic temperature range, while the copolymers exhibited N* mesophase whose mesomorphic temperature ranges were much wider than those of the comonomers. Moreover, the glass transition temperatures and isotropization temperatures of the polymers all decreased with decreasing the dimer components. Reflection spectra showed that Pa series tend to attain wide-band selective reflection at long wavelengths, while Pb series were more potential at short wavelengths with narrow bandwidths. Decreasing the dimer components led the wavelength of the selective reflection to blue shift, which was an abnormal phenomenon in chiral mixture system. 相似文献
89.
A novel uncertainty propagation method for problems characterized by highly non-linear or discontinuous system responses is presented. The approach is based on a Padé–Legendre (PL) formalism which does not require modifications to existing computational tools (non-intrusive approach) and it is a global method. The paper presents a novel PL method for problems in multiple dimensions, which is non-trivial in the Padé literature. In addition, a filtering procedure is developed in order to minimize the errors introduced in the approximation close to the discontinuities. The numerical examples include fluid dynamic problems characterized by shock waves: a simple dual throat nozzle problem with uncertain initial state, and the turbulent transonic flow over a transonic airfoil where the flight conditions are assumed to be uncertain. Results are presented in terms of statistics of both shock position and strength and are compared to Monte Carlo simulations. 相似文献
90.
Y. Benmimoun A. Bouhemadou R. Khenata A. H. Reshak B. Amrani M. Ameri H. Baltache 《The European Physical Journal B - Condensed Matter and Complex Systems》2008,61(2):165-171
The results of first-principles theoretical study of the structural,
electronic and optical properties of SrCl2 in its cubic structure, have
been performed using the full-potential linear augmented plane-wave method
plus local orbitals (FP-APW+lo) as implemented in the WIEN2k code. In this
approach both the local density approximation (LDA) and the generalized
gradient approximation (GGA) are used for the exchange-correlation (XC)
potential. Also we have used the Engel-Vosko GGA formalism, which optimizes
the corresponding potential for band structure calculations. We performed
these calculations with and without spin-orbit interactions. Including
spin-orbit coupling cause to lifts the triple degeneracy at Γ point
and a double degeneracy at X point. Results are given for structural
properties. The pressure dependence of elastic constants and band gaps are
investigated. The dielectric function, reflectivity spectra and refractive
index are calculated up to 30 eV. Also we calculated the pressure and volume
dependence of the static optical dielectric constant. 相似文献