二维金属有机框架材料的合成及电催化应用

二维金属有机框架材料(MOFs)由于具备高比表面积、 多孔性以及丰富的活性位点等优异特性而受到广泛关注, 并且在电催化领域展现出巨大的应用潜力. 研究者们已在二维MOFs的可控制备与电催化性能调控方面取得许多突破性进展, 显示出相关研究对开发高性能电催化剂的关键作用. 本文总结了二维MOFs的自上而下和自下而上合成策略以及二维MOFs衍生物的典型合成方法, 概述了二维MOFs在各尺度下的电催化性能调控策略, 并介绍了各种合成方法和调控策略在电催化中的应用. 最后讨论了该领域面临的挑战, 并对未来的发展方向进行了展望.     

SOFC/GT/ST三重复合动力系统特性研究

本文研究SOFC/GT/ST三重复合动力系统.首先基于Aspen Plus建立了SOFC/GT/ST的性能分析模型,分析了各主要参数对SOFC/GT/ST复合动力系统性能的影响规律.研究结果表明:复合动力系统尽量在高的压力,温度在900℃左右的条件下,有较高系统效率;较高的燃料利用率(Ut)有利于提高系统效率.本文研究...     

不同类型石油卟啉标志物的光谱、质谱及色谱特征

本文利用紫外－可见光谱、质谱及色谱对ETIO、DPEP及Rhodo型石油卟啉标志物的特征性和相关性进行了研究，结果指出，在可见光谱带四个特征峰的吸收强度ETIO型为Ⅳ＞Ⅲ＞Ⅱ＞Ⅰ，DPEP型为Ⅳ＞Ⅱ＞Ⅲ＞ⅠRhodo型为Ⅲ＞Ⅱ＞Ⅳ＞Ⅰ，在反相高效液相色谱的体系中流出顺序为，先流出的是Rhodo型卟啉，其次是ETIO和DPEP型。不同类型卟啉的质谱特征是，各卟啉化合物基本以分子离子峰出现，极少碎片峰，同类卟啉化合物按正态分布。     

碳纳米纤维吸附储氢性能分析

文中综合碳纳米纤维微观结构的表征结果以及氢吸脱附等温线的实验测量结果,对碳纳米纤维的吸附储氢性能进行了综合分析,分析发现:比表面积和中孔容积均与氢吸附量成线性关系;微孔容积对材料吸附性能影响较大,微孔容积与氢吸附量成抛物线关系;氢在常温左右以及77K下的吸附等温线呈现超临界气体的吸附特征,氢在273K和353K下的吸脱附等温线也基本重合,呈现的是物理吸附的特征。实验结果还说明:常温左右,甚至是77K下,碳纳米纤维均不适合于氢的吸附储存。     

The Design and Analysis of Benchmark Experiments

The assessment of the performance of learners by means of benchmark experiments is an established exercise. In practice, benchmark studies are a tool to compare the performance of several competing algorithms for a certain learning problem. Cross-validation or resampling techniques are commonly used to derive point estimates of the performances which are compared to identify algorithms with good properties. For several benchmarking problems, test procedures taking the variability of those point estimates into account have been suggested. Most of the recently proposed inference procedures are based on special variance estimators for the cross-validated performance. We introduce a theoretical framework for inference problems in benchmark experiments and show that standard statistical test procedures can be used to test for differences in the performances. The theory is based on well-defined distributions of performance measures which can be compared with established tests. To demonstrate the usefulness in practice, the theoretical results are applied to regression and classification benchmark studies based on artificial and real world data.     

Evaluating the performance of Swedish savings banks according to service efficiency

This article develops principles for an evaluation of the efficiency of a savings bank. It starts out from the observation that such a bank is less profit oriented than a commercial bank. The customer is a vital stakeholder to the savings bank implying a greater emphasis on customer service provision. We are using data envelopment analysis (DEA) as a method to consider the service orientation of savings banks. We thereby demonstrate how an evaluation of the performance of savings banks according to “service efficiency” differs from an evaluation based on the traditional “profit” or shareholder concept. We determine the number of Swedish savings banks being “service efficient” as well as the average degree of service efficiency in this industry.     

On the Analysis of the Virtual Waiting Time in Open Queueing Networks

The model of an open queueing network in heavy traffic has been developed. These models are mathematical models of computer networks in heavy traffic. A limit theorem has been presented for the virtual waiting time of a customer in heavy traffic in open queueing networks. Finally, we present an application of the theorem—a reliability model from computer network practice.     

Analytic study of multiserver buffers with two-state Markovian arrivals and constant service times of multiple slots

In this paper, we study the behavior of a discrete-time multiserver buffer system with infinite buffer size. Packets arrive at the system according to a two-state Markovian arrival process. The service times of the packets are assumed to be constant, equal to multiple slots. The behavior of the system is analyzed by means of an analytical technique based on probability generating functions (PGF’s). Explicit expressions are obtained for the PGF’s of the system contents and the packet delay. From these, the mean values, the variances and the tail distributions of the system contents and the packet delay are calculated. Numerical examples are given to show the influence of various model parameters on the system behavior.     

磁场电源在 HL-2M 装置初始等离子体放电中的应用

磁场电源是 HL-2M 装置初始等离子体放电的重要组成部分,它关系到 HL-2M 装置零场的建立,等 离子体的击穿和维持及位形控制。为实现初始等离子体放电所需的供电电压和电流,对磁场电源从主回路、控制、 测量和保护分别作了相应的调整。在此基础上进行了大量的工程调试,确保了磁场电源的控制和保护等性能达到 初始等离子体放电的需求。在磁场电源运行中,电源控制性能和输出参数的一致性、纹波质量等都有显著提高。 介绍了磁场电源在调试及 HL-2M 装置初始放电中的应用。     

Modification of membrane surface for anti-biofouling performance: Effect of anti-adhesion and anti-bacteria approaches

Membrane biofouling refers to the undesirable accumulation (attachment and growth) of microorganisms on a membrane surface, and has been a major problem in the application of membrane technology in water and wastewater treatment. In this study, the surface of a base membrane made of chitosan/cellulose acetate blend was modified by reacting with heparin, quaternary ammonium or being immobilized with silver ions. The purpose of the modifications was to increase the surface hydrophilicity, alter the surface charge property or endue the surface with anti-bacteria function. The modified membranes were then examined for their anti-biofouling performance in terms of the anti-adhesion and anti-bacteria effects, with Escherichia coli pure culture and mixed culture bacteria in a bioreactor that simulated the activated sludge wastewater treatment process. The results clearly show that the hydrophilicity of a membrane, although important, is not an effective indicator for the tendency of membrane biofouling but the nature of the surface charges of the membrane also plays a very important role. It was found that the anti-adhesion approach that prevents the initial attachment of bacteria on a membrane surface is a more effective method than the anti-bacteria approach that aims at killing bacteria already attached on the membrane surface. The best performance for minimizing membrane biofouling has, however, been realized through a modified membrane surface that has effective anti-adhesion property plus additional anti-bacteria function, with the latter as a safe guard in case some bacteria do attach to the surface of a membrane.