Foam Self-Clarification Phenomenon: An Experimental Investigation

This paper is focused on the capabilities of gas–liquid foams to attenuate acoustic waves. It is postulated that the sound attenuation phenomenon in foams is largely governed by the hydrodynamic resistance of the Plateau-Gibbs channels (PGC) to the flow of liquid through them. It is shown that the addition of solid particles to gas–liquid foams has opposite effects depending on the concentration of the added solid particles. As long as the concentration of the added solid particles is smaller than a certain critical value the sound attenuation coefficient increases and as a result in the sound velocity decreases. However, if the concentration of the added solid particles becomes larger than this critical value the attenuation coefficient decreases and the sound velocity increases. When the concentration of the solid particles reaches some critical value, the particles block the Plateau-Gibbs channels and stop the filtration. As a result the attenuation coefficient of the sound wave decreases while the sound velocity, in such three-phase foams, increases. The point at which the sound wave stops attenuating and its velocity starts to increase is known as the point of self-clarification. Based on this postulate and on the results of our preliminary tests the present study provides a plausible explanation to the above-mentioned contradicting effect, and the self- clarification phenomenon.     

大动脉中血液流动的中性扰动

本文在长波假定下用流体力学线性稳定性理论对大动脉中血液流动求出了一种中性扰动。结果表明，心室或瓣引起的扰动在一定条件下有可能量一种中性扰动，它可以沿着动脉管无变形地传播到动脉远端。这说明也许有可能提供一种通过在远离心脏的某些浅表动脉部位检测这种中性成动以了解心脏的某些功能的新方法。     

有限元离散模型中的出平面波动

采用分离变量技术,将二维出平面(Anti-Plane)波动问题的有限元运动方程化为两个联立的一维方程,获得了这一离散模型中波动的解析解,由此对有限元离散模型中出平面波动问题进行了深入的研究。分析了出平面弹性波的频散、截止频率、寄生振荡和有限元离散化引起的波传播的附加的各向异性性质等,同时讨论了时域离散化对出平面波动规律的影响。     

Numerical simulation of a fluid-saturated soil under a dynamically loaded pile

The behaviour of the soil under a dynamically loaded pile toe is studied. The soil is modelled as a fluid saturated porous continuum. The constitutive behaviour of the solid skeleton is described by the elasto-plastic model of Drücker-Prager. The wave propagation is simulated with a dynamical finite-element program.A two-phase model of soil gives useful information about effective stress and pore pressure in the soil. In saturated soil the main wave under the pile toe propagates more downards than in dry soil, due to the higher compressional stiffness in saturated soil. The plastic zone under the pile toe propagates with the velocity of the fast compressional wave. The pore fluid influences the plasticity strongly and can be expected to affect pile driving too.The distribution of effective stress and pore pressure under the pile toe depends on the permeability of the soil and cannot be calculated uniquely from a single-phase calculation. Therefore, a nonlinear soil cannot be modelled correctly as a conventional single-phase material.     

A Nitrite Electrochemical Sensor Based on Boron‐Doped Diamond Planar Electrochemical Microcells Modified with a Monolacunary Silicotungstate Polyoxoanion

A new boron doped diamond microcells (BDD) was modified, for rapid, selective and highly sensitive determination of nitrite, using a coating film of polyoxometalates (POMs), formed by cyclic voltammetry on the molecular p‐phenylenediamine (PPD) functionalized BDD. The scanning electron microscopy (SEM) technique was used to examine the morphology of (PPD/SiW₁₁) modified (BDD) electrode. It was found that (SiW₁₁) layer was uniformly formed on the electrode surface. It was observed that (BDD/PPD/SiW₁₁) showed excellent electrocatalytic activities towards nitrite ion. Under the selected conditions, the anodic peak maximum at ?0.6 V was linear versus nitrite concentration in the 40 µM–4 mM range, and the detection limit obtained was 20 µM. The newly developed electrode has been successfully applied to the determination of nitrite content in real river water samples.     

Square‐Wave Voltammetry of Electroinactive Surfactants

Under the influence of previously published and some new theoretical results, potential‐ dependent adsorption and desorption of model electroinactive surfactants Triton X‐100 (T‐X‐100 or polyethylene glycol p‐(1,1,3,3‐tetramethylbutyl)‐phenyl ether) and sodium dodecyl sulfate (SDS) on the static mercury drop electrode (SMDE) were studied by square‐wave voltammetry (SWV). Although (according to the theory) the resulting current – potential curve should consist of two highly separated peaks, only desorption signal could be seen on each experimentally obtained voltammogram, most probably because of the limitations concerning the available potential range. Different properties of the recorded peak are in good agreement with the theory indicating that square‐wave voltammetry could be treated as a potential tool for tensammetric studies of electroinactive surface active substances.     

Non‐Invasive Salivary Electrochemical Quantification of Paraquat Poisoning Using Boron Doped Diamond Electrode

The present work describes the first electrochemical method for quantifying paraquat herbicide poisoning in human saliva samples. Paraquat shows two couples of well‐defined peaks in aqueous solution using a boron doped diamond (BDD) electrode. By using square wave voltammetry (SWV) technique under optimum experimental conditions, a linear analytical curve was obtained for paraquat concentrations ranging from 0.800 to 167 µmol L^?1, with a detection limit of 70 nmol L^?1. This method was applied to quantify paraquat spikes in human saliva samples and in two different water samples (tap and river). The recovery values obtained ranged from 83.0 to 104 % and 99.1 to 105 %, respectively, which highlight the accuracy of the proposed method.     

Unraveling the electronic structure of transition metal dimers using resonant four‐wave mixing

The potential of two‐color resonant and degenerate four‐wave mixing spectroscopy for investigations of the complex spectra of transition metal dimers is explored. Two‐color resonant and degenerate four‐wave mixing spectroscopy scans of the well‐known A‐X and B‐X transitions in Cu₂ are reported and compared with previous experimental data obtained from standard single‐resonance techniques. The selectivity of the method is shown to enable the measurement of isotopologue pure spectra without the need for isotopically enriched metal targets. Specific subsets of the rovibronic structure are separated in a congested spectral region of overlapping transitions. The sensitivity of the method compares satisfactorily with linear spectroscopic methods such as laser‐induced fluorescence and cavity ring‐down. A new laser vaporization source for the production of transition metal dimers and clusters has been constructed. The new design aims for a high number density and maximum possible shot‐to‐shot stability. The possibilities of further applications of non‐linear four‐wave mixing spectroscopy to Cu₂ and other transition metal dimers are discussed. Copyright © 2015 John Wiley & Sons, Ltd.     

Dynamic polarizability of two‐electron ions under Debye screening

The effect of plasma screening on the dynamic dipole polarizability (DPP) of two‐electron ions Be²⁺, B³⁺, and C⁴⁺ has been investigated using highly correlated exponential wave functions within the framework of pseudostate summation technique and Debye screening concept. Plasma‐screening effect on the oscillator strengths (OS) of the ultraviolet and visible series has also been investigated for the systems Li⁺, Be²⁺, B³⁺, C⁴⁺. The DPP are reported as functions of screening parameters. The OS for S‐P transitions are also reported for various screening parameters. The OS and dynamic polarizability show interesting behavior with increasing screening strength and nuclear charge. © 2015 Wiley Periodicals, Inc.     

Two‐dimensional reactive scattering with transmitted quantum trajectories

A simple and easy‐to‐implement method is presented for the study of time‐dependent reaction dynamics by propagating an ensemble of transmitted quantum trajectories. During the trajectory evolution, reflected trajectories are gradually removed and all the remaining trajectories represent the transmitted subensemble. The removal process of reflected trajectories avoids numerical instabilities arising from node formation in the reactant region, and allows stable long‐time propagation of transmitted trajectories. This method is applied to a two‐dimensional model chemical reaction. Excellent computational results are obtained for the time‐dependent reaction probabilities evaluated by the time integration of the probability flux. © 2014 Wiley Periodicals, Inc.