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71.
Chenguang Liu Wenchen Zheng Ruoxiao Xie Yupeng Liu Zhe Liang Guoan Luo Mingyu Ding Qionglin Liang 《中国化学快报》2019,30(2):457-460
By combining microfiber spinning techniques with aqueous two phase system (ATPS), a rapid and simple strategy to fabricate water-in-water (w/w) droplets encapsulated in microfibers was proposed for the first time. Hydrophilic environment in hydrogel and the fiber format facilitates higher biocompatibility, convenient manipulation of the droplets and recycling of the contents inside droplets, which would have promising development in biological, pharmacological and environmental fields. 相似文献
72.
现代复合材料层合板具有高强和轻型的突出优点,从而在军工和民用等诸多领域发挥着重要作用。这种板结构的特点是随着纤维走向的不同,层间材料的物理-力学特性发生剧烈变化。沿板厚方向变形的梯度比较陡峭,并在层间结合面处发生强不连续,呈现zig-zag (锯齿状)现象。这导致横向剪应变在板的静态和动态响应中发生重要作用,不计横向变形的经典组合板计算模型CLPT难以适应现代多层板计算分析的需要。考虑横向剪切变形影响的板的计算模型得到重视和发展。需要指出,现有各种考虑剪切变形影响的计算模型虽然有了很大的发展,但在全面和准确性上仍然存在一定的不足,难以适应现代多层组合板横向力和物理性能多变的情况。模型预测的沿板厚方向位移和应力的变化规律难以通过严格的检验。本文提出的以比例边界有限元为基础的正交各向异性板的数值计算模型,同时可适用于各种薄板与厚板的分析,对现代复合材料层合板的分析具有特殊的优越性。所得到的板的位移、正应力和剪应力沿板厚方向的变化,与三维弹性理论的标准解高度吻合。数值算例进一步表明,随着层间纤维走向的变化,板内位移场和应力场沿板厚方向剧烈变化所呈现的锯齿现象均可以精准地进行模拟。据此,本文建议方法对现代板分析的广泛适应性和高度准确性得到了充分论证。 相似文献
73.
《Journal of computational chemistry》2017,38(13):981-997
A novel approach for calculating deformation densities is presented, which enables to calculate the deformation density resulting from a change between two chemical states, typically conformers, without the need for radical fragments. The Fragment, Atom, Localized, Delocalized, and Interatomic (FALDI) charge density decomposition scheme is introduced, which is applicable to static electron densities (FALDI‐ED), conformational deformation densities (FALDI‐DD) as well as orthodox fragment‐based deformation densities. The formation of an intramolecular NH⋅⋅⋅N interaction in protonated ethylene diamine is used as a case study where the FALDI‐based conformational deformation densities (with atomic or fragment resolution) are compared with an orthodox EDA‐based approach. Atomic and fragment deformation densities revealed in real‐space details that (i) pointed at the origin of density changes associated with the intramolecular H‐bond formation and (ii) fully support the IUPAC H‐bond representation. The FALDI scheme is equally applicable to intra‐ and intermolecular interactions. © 2017 Wiley Periodicals, Inc. 相似文献
74.
The dynamic analysis of a generalized linear elastic body undergoing large rigid rotations is investigated. The generalized linear elastic body is described in kine-matics through translational and rot... 相似文献
75.
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77.
Sergio Conti Matteo Focardi Flaviana Iurlano 《Annales de l'Institut Henri Poincaré (C) Analyse Non Linéaire》2019,36(2):455-474
We consider the Griffith fracture model in two spatial dimensions, and prove existence of strong minimizers, with closed jump set and continuously differentiable deformation fields. One key ingredient, which is the object of the present paper, is a generalization to the vectorial situation of the decay estimate by De Giorgi, Carriero, and Leaci. This is based on replacing the coarea formula by a method to approximate functions with small jump set by Sobolev functions, and is restricted to two dimensions. The other two ingredients will appear in companion papers and consist respectively in regularity results for vectorial elliptic problems of the elasticity type and in a method to approximate in energy functions by ones. 相似文献
78.
We develop a variational optimization method for crystal analysis in atomic resolution images, which uses information from a 2D synchrosqueezed transform (SST) as input. The synchrosqueezed transform is applied to extract initial information from atomic crystal images: crystal defects, rotations and the gradient of elastic deformation. The deformation gradient estimate is then improved outside the identified defect region via a variational approach, to obtain more robust results agreeing better with the physical constraints. The variational model is optimized by a nonlinear projected conjugate gradient method. Both examples of images from computer simulations and imaging experiments are analyzed, with results demonstrating the effectiveness of the proposed method. 相似文献
79.
The heat capacity of a solid polymer is governed by the manner in which the internal energy is distributed over the various degrees of freedom. If the internal energy manifests itself in harmonic oscillatory motions, the heat capacity is the sum of contributions of the normal modes of motion. In practice, full frequency data are not generally available for polymers. This paper proposes an empirical method for determining the heat capacities of linear high polymers by the addition of contributions from different chain segments. A survey of heat capacity data for 30 linear high polymers and several copolymer systems has revealed that additivity is usually valid for a temperature range from about 60°K to the glass-transition temperature. A table of heat capacity contributions of a number of polymer constituents is derived which permits the calculation of unknown heat capacities to an accuracy of ±5% or better. In addition, δCp data for the increase of the heat capacity at the glass-transition temperature were found to agree with the rule of constant heat capacity increase per mole of “bead” proposed 8 years ago. 相似文献
80.
In this paper we are interested in developing constitutive equations for fiber-reinforced nonlinearly viscoelastic solids. It has been shown that constitutive equations for such bodies can be expressed in terms of a complete minimal set of 18 classical invariants associated with deformation and fiber orientation. In this paper, we give an alternative formulation using a set of spectral invariants. It is shown via the use of spectral invariants that only 11 of the 18 classical invariants are independent. We analyze the spectral invariants for two illustrative deformation gradients: (i) simple tension, and (ii) simple shear. 相似文献